用二氧化氯降解废水中的苯胺类化合物（2）──降解机理的探讨

本文在上文（１）的基础上，进一步研究了经二氧化氯处理前后ＢＯＤ＿５／ＣＯＤ的变化规律，其比值大于或接近０．３．其降解产物有醌及醌的氧化产物和ＮＨＩ．对苯胺及二氧化氯来说其．反应级数为１，整个反应为二级反应．     

石油降解菌XD-1产表面活性剂的性能

从含油废水中筛选分离到1株原油降解菌XD-1,鉴定为假单胞菌（Pseuomonas sp.）.初步实验表明菌XD-1具有较强的产表面活性剂乳化原油的作用,对该菌的产表面活性剂性能进行了研究.实验证明,菌XD-1所产表面活性剂为脂肽类物质,菌在生长对数期产表面活性剂,表面活性剂的产生为生长相关型;充足的碳源是产表面活性剂的必需条件,菌利用原油为碳源时能持续大量地产表面活性剂;原油和尿素为产表面活性剂的最适碳源和氮源,菌XD-1产表面活性剂的最佳营养培养基组成为葡萄糖10 g,尿素4 g,磷酸二氢钾1 g,微量元素液4 mL,水1 L,pH 8.0.     

绍兴茶园小流域的3种农药生态风险评价

虫螨腈、联苯菊酯和溴氰菊酯是茶叶生产中较为常见的3种杀虫剂,但其对茶园小流域内生态环境影响的相关研究较少。为评价其生态风险,选取我国浙江绍兴茶园小流域内主要溪流及湖库采集水体样品,采用气相色谱-质谱法对样品中3种农药进行残留检测;基于美国生态毒理数据库(ECOTOX)收集了3种农药对我国常见水生生物的毒性数据,利用BITSSD软件平台构建了物种敏感度分布(species sensitivity distribution, SSD)曲线,结合研究区实测数据开展3种农药对绍兴茶园小流域的生态风险评价研究。结果表明：(1)无脊椎动物和节肢动物对3种农药的敏感度高于鱼类,营养级越高其敏感度越低;(2)根据SSD模拟结果,为保护该流域95%的物种,联苯菊酯和溴氰菊酯浓度需<0.001μg·L^(-1),虫螨腈为0.4μg·L(-1),虫螨腈为0.4μg·L^(-1);(3)农药喷施后,虫螨腈、溴氰菊酯和联苯菊酯在茶园溪流中的残留浓度最高分别影响22%、50%和66%的物种,联苯菊酯是生态风险的主要贡献者,但在喷施1个月后,茶园流域水溪及河湖水环境中的农药残留基本均未检出。这说明3种农药施用对茶园小流域物种的影响较小,所带来的生态风险尚在可控范围之内。     

High performance of multi-layered alternating Ni–Fe–P and Co–P films for hydrogen evolution

Judiciously engineering the electrocatalysts is attractive and challenging to exploit materials with high electrocatalytic performance for hydrogen evolution reaction. Herein, we successfully perform the interface engineering by alternately depositing Co–P and Ni–Fe–P films on nickel foam, via facile electroless plating and de-alloying process. This work shows that there is a significant effect of de-alloying process on alloy growth. The electronic structure of layered alloys is improved by interface engineering. The multilayer strategy significantly promotes the charge transfer. Importantly, the Co–P/Ni–Fe–P/NF electrode fabricated by interface engineering exhibits excellent electrocatalytic hydrogen evolution activity with an overpotential of 43.4 mV at 10 mA cm-2 and long-term durability for 72 h in alkaline medium (1 mol L-1 KOH). The innovative strategy of this work may aid further development of commercial electrocatalysts.     

Accumulation of potentially toxic trace elements (PTEs) by native plant species growing in a typical gold mining area located in the northeast of Qinghai-Tibet Plateau

Environmental Science and Pollution Research - Though gold mines provide significant economic benefits to local governments, mining causes soil pollution by potentially toxic trace elements (PTEs)...     

Assessing economic sustainability and ecological efficiency with genuine progress indicator: a case study of the Yangtze River Delta from 2000 to 2018

To achieve urban sustainability, it is critical to enhance the environment, economy, and society simultaneously. This study adopted the revised genuine progress indicator (GPI) and ecological footprint (EF) to evaluate the ecological efficiency and economic sustainability of the Yangtze River Delta from 2000 to 2018. Spatial analysis was utilized to identify spatial autocorrelation. A total of 27 cities were then partitioned through k-means cluster analysis. The results showed that GPI and ecological efficiency improved rapidly, but economic sustainability showed a downward trend. GPI and GDP had a high degree of spatial correlation, especially in Suzhou-Wuxi-Changzhou Metropolitan Area. However, no spatial correlation existed between GPI and EF. The city with high GEE can reach 3000 $/gha, indicating the city consumed 1 global hectare to create $3000 of genuine economic growth. Shanghai, Hangzhou, and Taizhou were cities with the highest level of economic sustainability and ecological efficiency. The spatiotemporal characteristics of economic sustainability and ecological efficiency revealed in this study will provide theoretical guidance for alleviating ecological pressure and promoting economic sustainable development.

     

Exploring the embodied carbon flow interactive relationships in China from an ecological network perspective: a model framework and application at provincial level

Environmental Science and Pollution Research - Energy-related carbon emissions take a large proportion in China, and the interregional trade caused by provincial disparities has led to significant...     

基于GIS的地震构造信息系统

本文讨论了地震构造信息系统的建造和信息管理。系统是以GIS工具软件ARC/INFO为开发平台建造的,原始资料复盖华北地区的大部,约北纬35～41度,东经109～120度。系统包括活动断裂、破坏性地震、仪器记录地震等信息。本文深入研究了GIS做为信息管理工具的能力,探讨了GIS在地震区划图编制中可能起到的作用。系统能使地震危险分析中信息管理方式、信息管理效率和利用率有质的改进,在某种程度上减小资料利用不充分和人为任意性引起的不确定性。作为一种探索,本文进行了一系列的空间操作和分析,以研究空间特征之间的相关性,并产生新的数据集合。     

重庆市生态足迹时间序列动态特征及其驱动因子分析

生态足迹是近年来广泛用于评价区域发展可持续性的重要方法.基于生态足迹计算模型,利用自然资源和能源消费的统计数据,对重庆市1997-2005年的人均生态足迹序列进行了计算;在此基础上,根据区域社会经济发展与生态足迹变化的作用机理选择了6个社会经济发展相关指标作为自变量,运用主成分回归方法,建立了人均生态足迹的驱动因子分析模型,揭示了驱动生态足迹序列变化的主要因素.计算结果显示,直辖以来,重庆市人均生态足迹总体呈上升趋势,由1997年的1.1244hm2增加到2005年的1.490 3 hm2,而由于耕地占用等原因,人均生态承载力却在逐年减少,从1997年的0.507 5 hm2减少到2005年的0.465 2 hm2,导致该地区人均生态赤字逐年扩大,呈相对不可持续发展状态.驱动力分析模型表明:重庆市社会经济发展对人均生态足迹增长具有强烈的驱动作用.直辖以来,一方面随着工业化、城镇化进程的加快以及消费水平的提升,人均生态足迹也相应同步增长;而另一方面,由于目前的产业和工业结构调整力度有限,因此它们尚未有效发挥降低区域生态足迹的作用.