The acute effects of fine particles on respiratory mortality and morbidity in Beijing, 2004–2009

Recent epidemiological and toxicological studies have shown associations between particulate matter and human health. However, the estimates of adverse health effects are inconsistent across many countries and areas. The stratification and interaction models were employed within the context of the generalized additive Poisson regression equation to examine the acute effects of fine particles on respiratory health and to explore the possible joint modification of temperature, humidity, and season in Beijing, China, for the period 2004–2009. The results revealed that the respiratory health damage threshold of the PM_2.5 concentration was mainly within the range of 20–60 μg/m³, and the adverse effect of excessively high PM_2.5 concentration maintained a stable level. In the most serious case, an increase of 10 μg/m³ PM_2.5 results in an elevation of 4.60 % (95 % CI 3.84–4.60 %) and 4.48 % (95 % CI 3.53–5.41 %) with a lag of 3 days, values far higher than the average level of 0.69 % (95 % CI 0.54–0.85 %) and 1.32 % (95 % CI 1.02–1.61 %) for respiratory mortality and morbidity, respectively. There were strong seasonal patterns of adverse effects with the seasonal variation of temperature and humidity. The growth rates of respiratory mortality and morbidity were highest in winter. And, they increased 1.4 and 1.8 times in winter, greater than in the full year as PM_2.5 increased 10 μg/m³.     

生物填料地下渗滤系统对生活污水的脱氮

将草甸棕壤、炉渣和活性污泥等基质按体积比13∶6∶1配制生物填料,研究了生物填料地下渗滤系统（subsurface wastewater infiltration system,SWIS）在不同的水力负荷和污染负荷条件下对校园生活污水的脱氮效果。场地实验结果表明,当BOD5负荷为12.0 g BOD5/（m2·d）,表面水力负荷为0.04-0.10 m3/（m2·d）时,SWIS对NH＋4-N和TN的平均去除率分别为92.4%和82.0%。当水力负荷为0.08 m3/（m2·d）,BOD5负荷9.3-16.8 g BOD5/（m2·d）时,SWIS对NH＋4-N和TN的平均去除率为92.7%和81.2%。SWIS中氧化还原电位（oxygen reduction potential,ORP）随进水水力负荷和BOD5负荷的增加而降低,脱氮效率下降。综合出水水质和处理效率,适宜的水力负荷和污染负荷分别为0.065 m3/（m2·d）和12.0 g BOD5/（m2·d）。在此条件下,SWIS的启动周期为25-30 d。出水水质均优于《城市污水再生利用-景观环境用水水质》（GB/T18921-2002）标准,且处理效果稳定,抗负荷冲击能力强。     

离子交换法选择性回收污泥厌氧消化液中的磷

为探讨高效选择性回收污泥厌氧消化液中磷的离子交换方法,采用静态实验和动态实验研究了4种阴离子交换树脂（D213、D202、D301和DSQ）的磷回收性能,筛选了适合富磷污泥厌氧消化液选择性磷回收的高交换容量树脂。实验结果表明,D213、D202、D301和DSQ 4种树脂对正磷浓度为70 mg/L的厌氧消化液进行动态处理时,其最大穿透体积分别为3、7、17和90 BV;DSQ树脂磷交换容量远高于其他3种树脂,达到6 860 mg P/L湿树脂,是目前报道的高磷交换容量树脂的3~4倍;DSQ树脂能有效地抵抗厌氧消化液中有机质和硫酸根等阴离子的干扰;用NaOH溶液再生DSQ树脂并回收磷,磷洗脱率超过96%,洗脱液是高浓度含磷液,可作为磷矿石的优质替代品。研究表明,DSQ树脂是一种高效选择性分离磷的树脂,适用于污泥厌氧消化液的磷回收。     

基于AERMOD模式的固定源对不同楼层大气污染预测研究

环境影响评价中,大气污染预测通常考虑地面的浓度影响,对高层住宅楼不同楼层影响的考虑较少.通过案例设计,模拟4种不同的污染排放情景,采用预测推荐模式AERMOD分别计算各情景下5个代表高度共20种组合情况的预测受体结果,并基于三维可视仪软件VOXLER直观显示各情景污染物浓度的空间连续分布情况,对小时最大浓度的分布规律利用分析工具CANOCO进行了分析.结果表明:(1)污染源高为15～80 m时,不同楼层间小时浓度分布差异性较大;污染源高为120～240 m时,楼层间差异性较小.(2)污染源高为15m时,小时最大浓度以50 m为分界线随楼层高度的增加先增后降;污染源高为80～240 m时,小时最大浓度随楼层高度的增加而增加.     

微米Cu／Fe对污染土壤洗脱液中有机氯农药的降解

以表面活性剂TritonX-100（TX-100）为洗脱剂,某有机氯农药（organochlorinepesticides,OCPs）污染场地土壤为对象,七氯、氯丹和灭蚁灵为目标污染物,研究微米Cu／Fe双金属对污染土壤洗脱液中OCPs的降解效果。考察了洗脱液中OCPs初始浓度、洗脱液pH值、微米零价铁加入量和cu负载量对Cu／Fe去除OCPs效果的影响。结果表明,微米Cu／Fe可以有效的去除土壤洗脱液中目标污染物。当微米零价铁加入量为1．0g（25g／L）,cu负载量为1．0％,洗脱液pH值为6．89时,Cu／Fe对2号土壤洗脱液中七氯、γ-氯丹、α-氯丹和灭蚁灵的去除效果最好,去除率分别为100．0％、99．3％、80．8％和71．1％。洗脱液中OCPs初始浓度越低,微米零价铁加入量越大,Cu／Fe对OCPs去除率越高;偏酸性条件有利于Cu／Fe对γ-氯丹和灭蚁灵的去除,而α-氯丹在中性条件下去除效果最好;1号土壤和2号土壤洗脱液的最佳铜负载量分别为2．O％和1．0％。     

发光细菌法在水质综合毒性在线检测中的应用

以海洋发光细菌费氏弧菌（Vibriofischeri）作为检测生物,采用冻干菌粉快速复苏技术,研究费氏弧菌在水质检测中的最佳测试温度和有效性测试条件,并对硫酸锌等多种毒物和几种实际水样进行发光抑制作用分析。研究表明,费氏弧菌冻干粉复苏菌液保存在2～5℃条件下能有效测试7d,最佳测试温度为15℃,最佳测试时间为15min。氯化汞、硫酸锌、硫酸镉等重金属和苯胺、多菌灵、甲醛等有机毒物对费氏弧菌均具有较强的光抑制作用,也即费氏弧菌对以上毒物较为敏感,并能够连续7d保持对同一浓度硫酸锌的敏感性较为一致。对几种实际水样的测试和分析表明,以费氏弧菌为指示生物的发光细菌法能够应用于水质环境安全的综合毒性在线监测预警中。     

砂尘环境试验风洞稳定段和收缩段的数值模拟研究

采用计算流体动力学软件FLUENT,对砂尘环境试验风洞中稳定段和收缩段的气固两相流流场进行数值模拟.给出了计算采用的湍流模型及计算区域的网格划分技术.通过分析稳定段和收缩段的两相流流场的速度梯度分布,得到了反向加砂方式优于正向加砂方式的计算结果.     

Aging activity of DDE in dissimilar rice soils in a greenhouse experiment

A green-house study was conducted in late 2005 to investigate the aging behavior of p,p'-DDE in two types of soil, Hydragric Anthrosols (An) and Hydragric Acrisols (Ac), according to the World Reference Base (WRB) [FAO/ISRIC/ISSS. 1998. World reference base for soil resources. World soil resources reports, Rome. p. 87]. Paddy rice and dry rice were grown in submerged paddy soils and non-submerged upland soils, respectively. The concentration of extractable p,p'-DDE in fresh DDE-spiked soils was 746.2ngg(-1). During the first few weeks of the experiment, the extractability of p,p'-DDE became increasingly low as the aging period prolonged. However, certain amount of p,p'-DDE that had been captured by soil minerals and organic matter (OM) could be released and became extractable in the later period. The extractability of p,p'-DDE in submerged soils was significantly lower than that in non-submerged soil, because flooding could increase the binding of pollutants to soil particles. The plantation of both dry rice and paddy rice slowed down the aging process of p,p'-DDE. After one month's growth of rice, p,p'-DDE bound to soil particles was released and became extractable. The OM and silt content of An are higher than that of Ac, resulting in more bound residues and relative lower extractability of p,p'-DDE in An. In addition, the extractability of p,p'-DDE could be reduced by the addition of rice straw to soils.     

人群疏散行为仿真技术研究

提出并建立了一种人群疏散仿真模型。针对疏散空间中障碍物的动态布局,采用网格法获得各障碍物包围盒坐标,依据最短路径原则采用几何法确定每个个体起始疏散路径,解决了人群疏散的空间连续性问题。针对人群疏散时个体之间的差异性,依据个体与个体之间的作用力、摩擦力动态改变个体的行进方向,以及依据人群密度采用人群疏散速度模型实时确定每个个体的运动速度,解决了个体之间的动态避碰、绕行和超越等问题。针对人群疏散时多个出口的选择问题,提出了把出口拥挤状态与个体心理慌乱状态相结合的出口选择方法。最后采用粒子系统实现了上述人群疏散行为的二维仿真并取得了较好的效果。     

煤矿瓦斯爆炸事故演化的突变模型

煤矿瓦斯爆炸事故,从微观上看,是在瓦斯积聚、引火源和氧气浓度3个条件同时具备的情况下发生的,从宏观上看,是在生产活动中存在人的不安全行为和物的不安全状态导致了微观3条件的同时具备。笔者介绍了突变理论的基本原理;在轨迹交叉事故致因理论基础上,分析了瓦斯爆炸事故演化的非线性特征;建立了事故演化的尖点突变模型。并指出:事故演化是一个流变-突变过程,其突变的程度反映了事故的严重度;人的不安全行为是事故发生的主要因素;物的因素决定事故的严重度;安全生产必须建立本质安全型矿井,避免人和物的运动轨迹越过分歧点集。