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111.
Pd-MnO_2/TiO_2 nanotube arrays(NTAs) photo-electrodes were successfully fabricated via anodization and electro deposition subsequently; the obtained Pd-MnO_2/TiO_2 NTAs photo electrodes were analyzed by scanning electron microscopy(SEM), X-ray diffraction(XRD) and characterized accordingly. Moreover, the light harvesting and absorption properties were investigated via ultraviolet–visible diffuse reflectance spectrum(DRS); photo degradation efficiency was investigated via analyzing the photo catalytic degradation of Rhodamine B under visible illumination(xenon light). The performed analyses illustrated that Pd-MnO_2 codoped particles were successfully deposited onto the surface of the TiO_2 nanotube arrays;DRS results showed significant improvement in visible light absorption which was between400 and 700 nm. Finally, the photo catalytic degradation efficiency results of the designated organic pollutant(Rhodamine B) illustrated a superior photocatalytic(PC) efficiency of approximately 95% compared to the bare TiO_2 NTAs, which only exhibited a photo catalytic degradation efficiency of approximately 61%, thus it indicated the significant enhancement of the light absorption properties of fabricated photo electrodes and their yield of UOH radicals. 相似文献
112.
Yunan Chen Yi Yang Bolong Xu Shunhao Wang Bin Li Juan M Jie Gao Yi Y. Zuo Sijin Liu 《环境科学学报(英文版)》2017,29(12):100-114
Environmental exposure and health risk upon engineered nanomaterials are increasingly concerned. The family of mesoporous carbon nanomaterials(MCNs) is a rising star in nanotechnology for multidisciplinary research with versatile applications in electronics,energy and gas storage, and biomedicine. Meanwhile, there is mounting concern on their environmental health risks due to the growing production and usage of MCNs. The lung is the primary site for particle invasion under environmental exposure to nanomaterials. Here, we studied the comprehensive toxicological profile of MCNs in the lung under the scenario of moderate environmental exposure. It was found that at a low concentration of 10 μg/mL MCNs induced biophysical inhibition of natural pulmonary surfactant. Moreover, MCNs at similar concentrations reduced viability of J774 A.1 macrophages and lung epithelial A549 cells.Incubating with nature pulmonary surfactant effectively reduced the cytotoxicity of MCNs.Regarding the pro-inflammatory responses, MCNs activated macrophages in vitro, and stimulated lung inflammation in mice after inhalation exposure, associated with lung fibrosis.Moreover, we found that the size of MCNs played a significant role in regulating cytotoxicity and pro-inflammatory potential of this nanomaterial. In general, larger MCNs induced more pronounced cytotoxic and pro-inflammatory effects than their smaller counterparts. Our results provided valuable information on the toxicological profile and environmental health risks of MCNs, and suggested that fine-tuning the size of MCNs could be a practical precautionary design strategy to increase safety and biocompatibility of this nanomaterial. 相似文献
113.
简要介绍了挥发性有机物(VOCs)的定义及危害,分析了炼化企业的VOCs排放现状,并简要介绍了VOCs有组织和无组织排放的种类。介绍了中国石化济南分公司延迟焦化装置和柴油加氢装置针对有组织排放和无组织排放开展的各种治理措施及LDAR检测开展情况。 相似文献
114.
介绍了装卸过程中油品静电产生机理,并对储罐内油品静电积聚造成的静电放电危险性进行了分析,总结了常用的油品静电安全控制措施。通过探讨管输油品静电量检测技术原理,设计了油品电荷量监测设备(油品电荷密度表),并应用于乙醇汽油装车过程中对油品静电的监测。为强化成品油输运、装卸过程中油品静电安全防护措施提供参考。 相似文献
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117.
Jinzhao Huang Song Liu Lei Kuang Yongdan Zhao Tao Jiang Shiyou Liu Xijin Xu 《环境科学学报(英文版)》2013,25(12):2487-2491
An efficient photocatalyst was fabricated by assembling quantum dots (QDs) onto one-dimensionally-ordered ZnO nanorods, and the photocatalytic properties for Methyl Orange degradation were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, UV-Vis-NIR absorption spectroscopy and photoluminescence. The results indicate that the catalyst with assembled QDs is more favorable for the degradation than the pristine ZnO nanorods. The QDs with core-shell structure lower the photocatalytic ability due to the higher carder transport barrier of the ZnS shell layer. Besides its degradation efficiency, the photocatalyst has several advantages given that the one-dimensionally-ordered ZnO nanorods have been grown directly on indium tin oxide substrates. The article provides a new method to design an effective and easily recyclable photocatalyst. 相似文献
118.
Xiangyun Zhong Shiyong Wu Yang Liu Zhenning Zhao Yaru Zhang Jinfeng Bai Jun Xu Bai Xi 《环境科学学报(英文版)》2013
The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising. 相似文献
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120.
结合胜利油田电力生产实际,提出了基于HSE作业指导卡的风险精细管控模式,介绍了HSE作业指导卡的格式内容、工作流程和实施效果。 相似文献