全文获取类型
收费全文 | 1434篇 |
免费 | 96篇 |
国内免费 | 535篇 |
专业分类
安全科学 | 98篇 |
废物处理 | 71篇 |
环保管理 | 103篇 |
综合类 | 901篇 |
基础理论 | 223篇 |
污染及防治 | 408篇 |
评价与监测 | 76篇 |
社会与环境 | 117篇 |
灾害及防治 | 68篇 |
出版年
2024年 | 2篇 |
2023年 | 22篇 |
2022年 | 88篇 |
2021年 | 75篇 |
2020年 | 65篇 |
2019年 | 64篇 |
2018年 | 72篇 |
2017年 | 56篇 |
2016年 | 74篇 |
2015年 | 94篇 |
2014年 | 100篇 |
2013年 | 142篇 |
2012年 | 115篇 |
2011年 | 154篇 |
2010年 | 111篇 |
2009年 | 92篇 |
2008年 | 90篇 |
2007年 | 93篇 |
2006年 | 78篇 |
2005年 | 52篇 |
2004年 | 38篇 |
2003年 | 45篇 |
2002年 | 55篇 |
2001年 | 41篇 |
2000年 | 36篇 |
1999年 | 35篇 |
1998年 | 24篇 |
1997年 | 30篇 |
1996年 | 23篇 |
1995年 | 26篇 |
1994年 | 23篇 |
1993年 | 16篇 |
1992年 | 13篇 |
1991年 | 8篇 |
1990年 | 1篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1982年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有2065条查询结果,搜索用时 46 毫秒
251.
252.
城市灰尘是分散于城市不同区域的表面固体颗粒物。城市灰尘对城市环境造成的污染越来越多地受到人们的关注,尤其是城市灰尘重金属对城市生存环境造成的危害。本文利用R软件中的Gstat包,对金华市城市地表灰尘中的Pb元素含量进行500次条件高斯模拟,并从中随机抽出3次模拟对其模拟结果进行分析,从模拟结果可以看出研究区Pb元素总体上显示出相似的空间变化趋势,但在细部空间变化上是有差别的。条件高斯模拟法对未知点的模拟值具有不确定性,克服了普通克里格法的平滑效应,能够更好地反映研究区的随机性和结构性。 相似文献
253.
污染河流悬沙与铜、锌污染相关性研究 总被引:1,自引:1,他引:0
通过对矿区选矿废水污染的河流水样和悬沙进行采样,分析悬沙、铜、锌质量浓度,探讨河流悬沙与铜、锌之间的相关关系,是有重要现实意义的.研究结果表明:河流水质铜超标严重,丧失了作为农业用水的使用功能.水中铜污染物量与悬沙量相关关系,锌污染物量与悬沙量相关关系都是极显著的.经过曲线回归方程拟合,锌污染物量与悬沙量之间的回归关系比铜污染物量与悬沙量之间的回归关系显著,有3个曲线方程较优,即:对数方程、二次多项式方程、三次多项式方程.据此,通过测定污染河流悬沙量可以粗略地估算水中锌污染物量. 相似文献
254.
选取滇池福保湾表层沉积物,以聚合氯化铝为钝化剂,研究了扰动强度对钝化剂抑制沉积物中磷释放的影响.结果表明,当扰动强度低于一定范围时,聚合氯化铝对沉积物中的磷有抑制作用,当转速为0,60,120r/min时,对应的水中磷浓度分别为初始值的62.5%,71.7%和83.4%;当转速达到240r/min时,沉积物会向水中释放大量磷,钝化作用完全被破坏,水中磷浓度为初始值的3.3倍.此外,在转速低于120r/min时,磷形态主要是以无机磷(DIP)为主的溶解性磷(DTP),而转速达到240r/min时,水中DTP/TP30%,DIP/DTP40%,即磷形态主要为不溶性磷,溶解性磷中以有机磷(DOP)为主. 相似文献
255.
Degradation and detoxification of microcystin-LR in drinking water by
sequential use of UV and ozone
Microcystins (MCs) produced by cyanobacteria are strong hepatotoxins and classified as possible carcinogens.MCs pose a considerable threat to human health through tainted drinking and surface waters.Herein filtrated water from a waterworks in Harbin,China,was spiked with microcystin-LR (MC-LR) extracted from a toxic scum of microcystis aeruginosa,and the spiked sample waters were treated using UV irradiation with consequent ozonation process (UV/O3),compared with ozonation at a dose range commonly applied in water treatment plants,UV irradiation at 254 nm and UV irradiation combined with ozonation (UV+O3),respectively.The remaining of toxins were analyzed using high-performance liquid chromatography and also determined using a protein phosphatase type 2A inhibition assay,which was utilized to evaluate the reduction in toxicity.Results indicated that in comparison to other three processes (O3,UV,and UV+O3),UV/O 3 process could effectively decrease both the concentration and toxicity of MC-LR at 100 μg/L level after 5 min UV irradiation with consequent 5 min ozonation at 0.2 mg/L (below 1 μg/L),while 0.5 mg/L ozone dose was required for the level below 0.1 μg/L.The addition of an UV treatment step to the existing treatment train may induce significant transformation of micropollutants and breaks down the natural organic matters into moieties unfavorable for ozone decomposition,stabilizing the ozone residual.These findings suggested that sequential use of UV and ozone may be a suitable method for the removal of these potentially hazardous microcystins from drinking water. 相似文献
256.
Heavy metal (Pb,Zn) uptake and chemical changes in rhizosphere soils of four wetland plants with different radial oxygen loss 总被引:4,自引:0,他引:4
Lead and Zn uptake and chemical changes in rhizosphere soils of four emergent-rooted wetland plants; Aneilema bracteatum,
Cyperus alternifolius, Ludwigia hyssopifolia and Veronica serpyllifolia were investigated by two experiments: (1) rhizobag filled with
“clean” or metal-contaminated soil for analysis of Pb and Zn in plants and rhizosphere soils; and (2) applied deoxygenated solution for
analyzing their rates of radial oxygen loss (ROL). The results showed that the wetland plants with di erent ROL rates had significant
e ects on the mobility and chemical forms of Pb and Zn in rhizosphere under flooded conditions. These e ects were varied with
di erent metal elements and metal concentrations in the soils. Lead mobility in rhizosphere of the four plants both in the “clean”
and contaminated soils was decreased, while Zn mobility was increased in the rhizosphere of the “clean” soil, but decreased in the
contaminated soil. Among the four plants, V. serpyllifolia, with the highest ROL, formed the highest degree of Fe plaque on the root
surface, immobilized more Zn in Fe plaque, and has the highest e ects on the changes of Zn form (EXC-Zn) in rhizosphere under both
“clean” and contaminated soil conditions. These results suggested that ROL of wetland plants could play an important role in Fe plaque
formation and mobility and chemical changes of metals in rhizosphere soil under flood conditions. 相似文献
257.
Lilai Xu Tao Lin Ying Xu Lishan Xiao Zhilong Ye Shenghui Cui 《Journal of Material Cycles and Waste Management》2016,18(2):377-384
Comprehensive study of the factors influencing household solid waste (HSW) generation is crucial and fundamental for exploring the generation mechanism and forecasting future dynamics of HSW. A case study of Xiamen Island, China was employed to reveal the direct and indirect effects of demographic/socioeconomic factors on solid waste generation at the urban household scale. Based on a face-to-face questionnaire and two-stage survey of solid waste generation, a path analysis model was built. Results showed that the proposed path model exhibited good fit indices. Family size and dinning-at-home rate (DR), whose coefficients were ?0.40 and 0.43, respectively, were the two major factors influencing HSW directly. Moreover, family size, education level, employment rate and age structure played different degrees of indirect effects on HSW generation through respective paths, which should not be ignored. In terms of total effects, coefficients of family size, DR and employment rate were ?0.46, 0.43 and ?0.37, respectively, which were three most dominant factors influencing HSW generation. As for waste composition, organic waste was the most representative of HSW dynamics, and was the most sensitive to impact by the factors studied. Quantitative results of this study have important policy implications for sustainable municipal solid waste management. 相似文献
258.
Ye Sun Yuan Meng Xiaoyan Guo Tianle Zhu Hongju Liu Wenpei Li 《Journal of Material Cycles and Waste Management》2016,18(4):618-624
Experiments were conducted using a bubbling reactor to investigate nitrogen oxide absorption in the calcium sulfite slurry. The effects of CaSO3 concentration, NO2/NO mole ratio and O2 concentrations on NO2 and SO2 absorption efficiencies were investigated. Five types of additives, including MgSO4, Na2SO4, FeSO4, MgSO4/Na2SO4 and FeSO4/Na2SO4, had been evaluated for enhancing NO2 absorption in CaSO3 slurry. Results showed that CaSO3 concentration had significant impact on NO2 and SO2 absorption efficiencies, and the highest absorption efficiencies of SO2 and NO2 could reach about 99.5 and 75.0 %, respectively. Furthermore, the NO2 absorption was closely related to the NO2/NO mole ratio, and the existence of NO2 in flue gas may promote NO absorption. The presence of O2 in simulated flue gas was disadvantage for NO x removal because it can oxidize sulfite to sulfate. It was worth pointing out that FeSO4/Na2SO4 was the best additive among those investigated additives, as the NO2 removal efficiency was significantly increased from 74.8 to 95.0 %. IC and in situ FTIR results suggest that the main products were NO3 ? and NO2 ? in liquid phase and N2O, N2O5 and HNO3 in gas phase during the CaSO3 absorption process. 相似文献
259.
260.
粉煤灰-铝土矿改性制备铝铁复合混凝剂的除磷性能及混凝机理研究 总被引:4,自引:1,他引:3
化学混凝法是城市污水处理深度除磷的有效方法,目前常用混凝剂主要存在成本高、除磷效率低且用量大等缺点.本研究采用常压酸浸法,以低成本的铝土矿和粉煤灰为主要原料制备无机复合混凝剂,并对其进行除磷应用及机理研究,结果表明:1自制混凝剂对生活污水中TP去除率达99.58%,出水TP含量为0.012 mg·L-1,优于GB18918—2002一级A标准.2 X-射线衍射和红外光谱结果显示,混凝剂中的Fe—OH、Al—OH、H—OH等基团能与水中的磷酸根作用生成沉淀达到除磷目的,该沉淀在沉降过程中还能吸附不易沉淀的含磷悬浮物,发挥网捕卷扫作用.3采用Ferron逐时络合比色法分析铝铁形态结果显示,混凝剂含有64.14%低聚态铝铁,能中和水中胶体的表面电荷致使胶体脱稳;11.27%中聚态铝铁可吸附在胶体表面,降低其表面电荷,同时以较高的分子量发挥吸附架桥作用;24.59%高聚态铝铁在沉淀过程中可包夹部分胶体粒子,以较大表面积发挥卷扫作用.4分形维数研究结果显示,絮体分形维数在1.2~2.8之间,分形特征较好,能有效发挥絮体的吸附架桥作用.5 Zeta电位分析结果显示,混凝剂本身带正电荷,能与水中带负电荷的胶体物质发生中和,从而压缩双电子层,使胶体粒子脱稳而从水中去除.混凝剂除磷过程是压缩双电层、电中和、吸附架桥和网捕卷扫多种机制共同作用的动态变化过程. 相似文献