全文获取类型
收费全文 | 629篇 |
免费 | 32篇 |
国内免费 | 262篇 |
专业分类
安全科学 | 39篇 |
废物处理 | 34篇 |
环保管理 | 59篇 |
综合类 | 348篇 |
基础理论 | 130篇 |
污染及防治 | 197篇 |
评价与监测 | 41篇 |
社会与环境 | 41篇 |
灾害及防治 | 34篇 |
出版年
2023年 | 10篇 |
2022年 | 33篇 |
2021年 | 27篇 |
2020年 | 21篇 |
2019年 | 25篇 |
2018年 | 32篇 |
2017年 | 36篇 |
2016年 | 33篇 |
2015年 | 39篇 |
2014年 | 32篇 |
2013年 | 54篇 |
2012年 | 50篇 |
2011年 | 56篇 |
2010年 | 53篇 |
2009年 | 37篇 |
2008年 | 42篇 |
2007年 | 46篇 |
2006年 | 41篇 |
2005年 | 23篇 |
2004年 | 23篇 |
2003年 | 22篇 |
2002年 | 32篇 |
2001年 | 29篇 |
2000年 | 31篇 |
1999年 | 11篇 |
1998年 | 16篇 |
1997年 | 9篇 |
1996年 | 10篇 |
1995年 | 9篇 |
1994年 | 13篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 9篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有923条查询结果,搜索用时 0 毫秒
901.
902.
903.
904.
905.
全氟辛酸(PFOA)广泛应用于工业生产中,具有高度的生物毒性及生物蓄积性,然而PFOA对环境微生物的毒性影响仍有待深入开展.通过流式细胞术测定了酵母菌在不同浓度PFOA胁迫下细胞膜通透性、ROS、线粒体跨膜电位的变化,并且测定了MDA含量和Na+K+-ATPase、Ca2+Mg2+-ATPase活性变化.结果显示PFOA可使PI染色细胞比例增高,酿酒酵母细胞膜通透性增大、ROS和MDA含量升高、线粒体跨膜电位降低,且ROS含量、MDA含量与线粒体跨膜电位降幅均与PFOA胁迫浓度和时间呈正相关.Na+K+-ATPase、Ca2+Mg2+-ATPase活性先上升后降低,表明酿酒酵母在PFOA胁迫下,其生理活性受到抑制甚至发生细胞凋亡.证明PFOA对酿酒酵母具有生物毒性,100 mg·L-1PFOA对酿酒酵母具有即时毒性.该结果可为PFOA的影响评价提供更多依据. 相似文献
906.
农药在土壤中迁移的研究方法 总被引:13,自引:2,他引:13
农药对地下水的污染已日益为人们密切关注,本文详细介绍了用土壤柱和土壤薄层层析法研究农药在土壤迁移行为用于预测或评价农药对地下水污染程度的研究方法。 相似文献
907.
单甲脒水中溶解度及正辛醇/水分配系数的测定 总被引:4,自引:5,他引:4
有毒有机化合物在水中的溶解度(WS)及正辛醇/水分配系数(K_(ow)),是描述其在环境中行为的两个重要物理化学参数。本文用溶解度平衡曲线法和振荡法,测得单甲脒在水中的溶解度为21.8±1.3mg/1(25℃),其在正辛醇/水中的分配系数lgK_(ow)为2.92±0.06。 相似文献
908.
An evaluation of a river health using the index of biological integrity along with relations to chemical and habitat conditions 总被引:13,自引:0,他引:13
We evaluated the health condition of a temperate river during June-November 1999 through applications of the index of biological integrity (IBI) using fish assemblages and qualitative habitat evaluation index (QHEI) as well as chemical analyses. Overall IBI values ranged from 13 to 37 and averaged 23 (n = 25, standard error = 1.16), indicating a "poor" or "very poor" condition according to the criteria of modified Karr [Fisheries 6 (1981) 21]. The values of mean IBI declined at a rate of 0.22 km(-1) (R2 = 0.91, p < 0.05) along the longitudinal distance from the headwaters to the downstream sites. Reduced IBI values at downstream sites reflected low forest cover, high population density and high nutrient enrichments. Ecotoxicity tests using the river water also showed that toxic impacts were evident in the downriver sites. These factors resulted in decreases of riffle benthic species and insectivores and increases of tolerant species, anormalies and exotic species in the river. Spatial pattern in IBI agreed with QHEI values, which showed a linear relation (R2 = 0.998, p < 0.001) with species richness. Field measurements of conductivity and pH, an indicators for variation of conservative ions, showed that the river water was diluted by 40% fold by summer monsoon rain and surface run-off from the watershed, resulting in a physical and chemical instability during the monsoon. For these reasons, average IBI values during the monsoon and postmonsoon decreased >20% compared to the premonsoon, indicating that IBI values were also affected by flow regime. Based on the overall physico-chemical data and IBI values, the river health is rapidly degrading due to the combined effect of chemical contaminations and habitat modifications. 相似文献
909.
Xin Jin Wei Wang Shuai Wang Pengkang Jin Xiaochang C. Wang Wushou Zhang Weijun An Yong Wang 《环境科学学报(英文版)》2019,31(7):17-27
This study proposed a novel membrane filtration and dissolved ozone flotation integrated(MDOF) process and tested it at pilot scale. Membrane filtration in the MDOF process was operated in gravity-driven mode, and required no backwashing, flushing, or chemical cleaning. Because ozone was added in the MDOF process, ozonation, coagulation, and membrane filtration could occur in a single reactor. Moreover, in situ ozonation occurred in the MDOF process, which differs from the conventional pre-ozonation membrane filtration process. Significant enhancement of turbidity removal was further achieved through the addition of membrane filtration. Membrane fouling was mitigated in the MDOF process compared to the MDAF process. In situ ozonation in the MDOF process decreased the fluorescence intensity and transformed the high MW dissolved organics into small MW compounds. For the fouling layer, the extracellular polymeric substance(EPS) contents and cake layer morphology were analyzed. The results indicated that the contents of EPS decreased. Furthermore, a thinner and more loosely structured cake layer formed in the MDOF process. Because coagulation and ozonation occurred simultaneously in a single reactor, the generation of hydroxyl radicals was enhanced through the catalytic effect of Al-based coagulants on ozone decomposition, which further alleviated membrane fouling in the MDOF process. 相似文献
910.
Van Lancker F Adams A Delmulle B De Saeger S Moretti A Van Peteghem C De Kimpe N 《Journal of environmental monitoring : JEM》2008,10(10):1127-1133
An automated headspace solid phase microextraction method followed by GC-MS analysis was used to evaluate and compare the in vitro production of microbial volatile organic compounds (MVOCs) on malt extract agar, plasterboard and wallpaper. Five fungal strains were isolated from the walls of water-damaged houses and identified. In addition, four other common molds were studied. In general, MVOC production was the highest on malt extract agar. On this synthetic medium, molds typically produced 2-methylpropanol, 2-methylbutanol and 3-methylbutanol. On wallpaper, mainly 2-ethylhexanol, methyl 2-ethylhexanoate and compounds of the C8-complex such as 1-octene-3-ol, 3-octanone, 3-octanol and 1,3-octadiene were detected. The detection of 2-ethylhexanol and methyl 2-ethylhexanoate indicates an enhanced degradation of the substrate by most fungi. For growth on plasterboard, no typical metabolites were detected. Despite these metabolite differences on malt extract agar, wallpaper and plasterboard, some molds also produced specific compounds independently of the used substrate, such as trichodiene from Fusarium sporotrichioides and aristolochene from Penicillium roqueforti. Therefore, these metabolites can be used as markers for the identification and maybe also mycotoxin production of these molds. All five investigated Penicillium spp. in this study were able to produce two specific diterpenes, which were not produced by the other species studied. These two compounds, which remain unidentified until now, therefore seem specific for Penicillium spp. and are potentially interesting for the monitoring of this fungal genus. Further experiments will be performed with other Penicillium spp. to study the possibility that these two compounds are specific for this group of molds. 相似文献