The study of ultrasound-assisted oxidative desulfurization process applied to the utilization of pyrolysis oil from waste tires

In recent years, the increasing world population and rapid industrial development has increased the consumption of fossil fuel-derived oils. In response to the resulting exhaustion of fossil fuel energy, many countries around the world are investigating methods of waste energy recovery and reuse, including oil recovery from the pyrolysis process of waste tires. This study investigates the efficiency of an ultrasound-assisted oxidative desulfurization (UAOD) process in sulfur reduction from diesel oil and the pyrolysis oil from waste tires treatment. The results indicate that the oxidation efficiency increases as the doses of transition metal catalyst are increased. Longer sonication time also enhances the oxidation process, apparently through the biphasic transfer of oxidants, which results in a high yield of organic sulfur oxidation products. The best desulfurization efficiency was 99.7% (2.67 ppm sulfur remaining) and 89% (800 ppm sulfur remaining) for diesel and pyrolysis oils, respectively, via a process executed by two UAOD units connected in series and combined with solid adsorption using 30 g of Al₂O₃ in 6 cm columns. These batch experiment results demonstrate clean waste energy recovery and utilization, while fulfilling the requirements of Taiwan EPA environmental regulations (sulfur concentrations less than 5000 ppm).     

Chinese Policies and Practices regarding Payments for Ecological Services in Watersheds

Watersheds provide a variety of ecological services including soil and water conservation, carbon sequestration and biodiversity protection. However, activities in a fast-growing economy significantly impact the supply and demand of these watershed services. To mitigate these impacts, the concept of payment for environmental and ecosystem services from watersheds has emerged in global academic and policy circles. The governments and academic communities in China have increasingly described payments for ecological services from watersheds with the concept of watershed eco-compensation as it is urgent to protect watershed ecosystems. Watershed eco-compensation has proved to be one of the most economically effective means of solving environmental problems of watersheds to be adopted by the Chinese government. This paper presents an objective analysis of the Chinese market for watershed ecosystem services, including supply and demand for the services. It also summarizes Chinese policies on watershed eco-compensation, including relevant laws and regulations and fiscal policies. In addition, it presents a review of Chinese practices in watershed eco-compensation, including the analysis of an ecological construction project in Western China, inter-provincial watershed eco-compensation practices and plans, and payment for ecological services at the provincial and small watershed levels. Finally, it summarizes the key components of the process of payment in Chinese watershed eco-compensation. This discussion forms the basis of concluding suggestions for ecosystem services compensation and ecological protection in the large scale river basin.     

浮顶储罐二次密封卡阻问题的改造技术

原油储罐是原油储存、周转过程中的重要设备设施，储油罐的完好无疑是原油库正常运行的关键。但随着运行时间的增加，一些早期建设的储油罐暴露出了很多的问题，如罐体变形、浮盘变形、罐基础不均匀沉降，等等。本文针对浮盘和罐体变形造成二次密封失效后如何不退出运行进行改造提出了相应的解决方法。     

可燃性气体含氧量安全限值的探讨

焦炉煤气的安全含氧量目前存在一些异议。由此,提出如何确定可燃性气体含氧量安全限值的问题。笔者提出了惰性气体对含氧量安全限值的影响,探讨了采用化学计算法和作图法能对可燃性气体含氧量作简单确定,用此方法确定焦炉煤气的含氧量安全限值为４％ 。笔者认为,焦炉煤气的安全氧含量可适当放宽,以２％ 为参考值。     

文南油田注水管线防污染清洗技术研究

针对文南油田注水管线内壁结垢对油田注水的危害,以及管线常规清洗中存在的环境污染和硫化氢中毒问题,进行了注水管线防污染清洗技术的研究。通过分析消除硫化氢的反应机理,配制了三种常规清洗剂和两组硫化氢抑制剂,并将清洗剂与抑制剂复配后进行脱垢实验,从而优选出最佳复配剂(MF-1-B),经过现场试验,排酸口空气中硫化氢浓度为3～5mg/m3。防污染清洗技术的开发应用使文南油田注水管网得到了及时、全面的清洗,水质达标率由清洗前的30%上升到100%。     

UASB处理酒精废液颗粒污泥形成过程与运行效果的研究

本试验采中中温ＵＡＳＢ反应器处理酒精废液，通过启动、运行、颗粒污泥不同时期形成过程的探索，成功地培养出了颗粒污泥，取得了有机负荷高达１３－２２ｇＣＯＤ／ｌ．ｄ，ＨＲＴ１５．６－２２．３ｈｒ，ＣＯＤｃｒ去除率达８３．９－９２．２％，沼气产气率５．１－８．７１／ｌ．ｄ，ＣＨ４含量５５－７２％的良好效果。     

新型机车监控系统的研究

设计了一种基于GSM的机车监控系统。用无线电手机传输监控装置产生的原始数据至PC机 ,来达到实时监控机车运行状况的目的。实践表明 ,该系统简单灵活 ,传输可靠 ,具有良好的稳定性和可靠性。与现行车载监控装置相比 ,新型机车监控系统具有提高数据的实时性、减轻工作人员的劳动强度等优点     

职业健康与个体防护

职业健康与工作环境的职业危害密切相关,职业健康风险正比于作业时间与暴露程度.个体防护就是为了降低职业健康风险、减少人们职业健康危害程度而采取的技术措施.任何作业环境““安全与健康““的状况都是相对而言的,只要作业人员暴露于作业环境中,就有接触职业健康危害的可能,就必须进行个体防护.通常,人们将““个体防护““视为安全生产的最后一道防线,但对于职业健康而言,个体防护是常设的防线.     

水旱灾害对我国农业及社会经济发展的影响

水旱灾害首先影响到我国农业生产。粮食产量的大幅减产还会波及到整个国民经济及人民生活水平的下降。研究自然灾害不仅要注意因灾损失的自然因素，同时要联系造成灾害的社会、经济、人文因素等诸多方面进行自与非自然因素的综合分析。     

气候异常与中国小麦白粉病灾害流行关系的研究

分析了厄尔尼诺事件与我国冬小麦白粉病发病面积的相关关系。结果表明：在厄尔尼诺出现的起始年，冬小麦白粉病发病面积相对较小；在厄尔诺起始年至下一个厄尔诺起始年前的前一年，冬小麦白粉病发病面积趋势逐年增大，并在下一个厄尔尼诺起始年前一年达到最大值；在连续出现厄尔尼诺的年份，冬小麦白粉病发生面积逐年降低。厄尔尼诺事件通过引发主要麦区的诱水、温度异常来影响小麦白粉病的流行程度。造成厄尔尼诺年我国小麦白粉病发病面向相对较低的原因，与厄尔尼诺起始年前的冬半年寒潮活动加强造成冬小麦冻害严重，大大降低了小麦白粉菌的越冬基数及春季干旱不利于小麦白粉菌的侵染有关。