Ultraviolet (UV)/monochloramine (NH
2Cl) as an advanced oxidation process was firstly applied for
Aspergillus spores inactivation. This study aims to: i) clarify the inactivation and photoreactivation characteristics of UV/NH
2Cl process, ii) compared with UV/Cl
2 in inactivation efficiency, photoreactivation and energy consumption. The results illustrated that UV/NH
2Cl showed better inactivation efficiency than that of UV alone and UV/Cl
2, and could effectively control the photoreactivation. For instance, the inactivation rates for
Aspergillus flavus, Aspergillus niger and
Aspergillus fumigatus in the processes of UV/NH
2Cl (2.0 mg/L) was 0.034, 0.030 and 0.061 cm
2/mJ, respectively, which were higher than that of UV alone (0.027, 0.026 and 0.024 cm
2/mJ) and UV/Cl
2 (0.023, 0.026 and 0.031 cm
2/mJ). However, there was no synergistic effect for
Aspergillus flavus and
Aspergillus fumigatus. As for
Aspergillus niger, the best synergistic effect can reach 1.86-log
10. This may be due to their different resistance to disinfectants, which were related to the size, an outer layer of rodlets (hydrophobins) and pigments. After UV/NH
2Cl inactivation, the degree of cell membrane damage and intracellular reactive oxygen species were higher than that of UV alone. UV/NH
2Cl had the advantages of high inactivation efficiency and inhibition of photoreactivation, which provides a new entry point for the disinfection of waterborne fungi.
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