Enhanced photoelectrocatalytic degradation of ammonia by in situ photoelectrogenerated active chlorine on TiO2 nanotube electrodes

TiO_2 nanotube(Ti NT) electrodes anodized in fluorinated organic solutions were successfully prepared on Ti sheets. Field-emission scanning electron microscopy(FE-SEM) and X-ray diffraction(XRD) were performed to characterize the TiNT electrodes. The linear voltammetry results under irradiation showed that the TiNT electrode annealed at 450°C presented the highest photoelectrochemical activity. By combining photocatalytic with electrochemical process, a significantly synergetic effect on ammonia degradation was observed with Na_2SO_4 as supporting electrolyte at pH 10.7. Furthermore, the photoelectrocatalytic efficiency on the ammonia degradation was greatly enhanced in presence of chloride ions without the limitation of pH. The degradation rate was improved by 14.8 times reaching 4.98 × 10~(-2) min~(-1) at pH 10.7 and a faster degradation rate of 6.34 × 10~(-2) min~(-1)was obtained at pH 3.01. The in situ photoelectrocatalytic generated active chlorine was proposed to be responsible for the improved efficiency. On the other hand, an enhanced degradation of ammonia using TiNT electrode fabricated in fluorinated organic solution was also confirmed compared to TiNT electrode anodized in fluorinated water solution and TiO_2 film electrode fabricated by sol–gel method. Finally, the effect of chloride concentration was also discussed.     

共享"红线" ——宜昌市环境总体规划信息管理与应用系统(V1.0)开发研究

在宜昌环境总体规划(2013-2030)得到市人大批复实施的背景下,为共享环境总体规划生态功能红线、环境质量红线与资源开发红线("三条红线")、为满足提供规划实施与评估有效途径的实际需求,在市信息办及环保局现有业务信息系统现状评价基础上,综合运用GIS、海量空间数据管理、SOA架构、瓦片地图分发、移动GIS等技术,设计开发了宜昌市环境总体规划信息管理与应用系统(V1.0),实现了"三条红线"等相关数据成果的地图展示、查询等精确管理分析以及项目环境影响评价的辅助决策.     

二氧化钛光催化降解甲醛反应动力学研究

以钛酸丁酯为前驱体，应用溶胶一凝胶法制备TiO2粉体和负载TiO2薄膜，考察了不同活化温度和活化时间对TiO2光催化降解甲醛性能的影响，并对TiO2薄膜光催化降解甲醛的反应动力学进行了研究。试验结果表明，在活化温度450℃、活化时间5h条件下，所得TiO2粉体及薄膜的光催化活性较好。不同初始浓度下甲醛光催化降解率与时间关系的动力学研究表明，一级反应动力学模型与试验数据拟合较好，方差R^2大于或等于0．99。     

受限空间烟气运动盐水模拟研究的现状和展望

回顾了受限空间火灾烟气运动盐水实验模拟研究的发展历史;介绍了盐水实验模拟的理论基础及其在火灾烟气运动研究领域的应用情况和最新进展;分析和讨论了模拟研究过程中所存在的主要问题及其可能的解决方法。所有这些研究和探索,对于受限空间火灾烟气运动盐水实验模拟研究方法的创新和完善有重要的启发作用。     

土壤渗滤对污染河流重金属去除效果研究

本试验通过模拟野外河滩土壤渗滤,分析测定原水和渗滤出水水质重金属浓度,研究天然土壤和填充碎石、沸石、活性炭、陶粒的土壤组合介质对水中重金属浓度的去除效果。结果表明：天然土壤和填充碎石、沸石、陶粒的土壤组合介质对河水中Hg的平均去除率分别为73．3％、49．4％、25．0％、75．0％。填充沸石的土壤组合介质在运行15天左右对河水中Cd的去除率也能达到30％。     

水库水质安全保障对策研究——以长潭水库为例

水库的供水功能日渐重要,水库水质安全已经成为保障社会稳定和经济发展的基础。水库环境污染问题不断加剧,保障水库水质安全日趋紧迫。水库水质安全保障需从外源污染控制、内源污染控制、水库生态系统恢复和突发事故应急等多方面着手。本文结合长潭水库情况,全面分析水库水质安全的保障对策。     

分子筛装置长周期运转影响因素及对策

针对中国石油抚顺石化公司石油三厂分子筛装置预分馏单元空冷系统泄漏与塔盘堵塞影响装置长周期运转问题,通过对分子筛装置生产原料杂质含量和运行情况的分析,判断出空冷系统腐蚀与塔盘堵塞的原因,对存在的问题采取了相应的改进措施,并进一步提出了保证装置长周期运行的对策。     

沈阳市热岛动态及其影响因子分析

对沈阳市1960-2006年的热岛效应及其驱动机制分析表明：沈阳市热岛强度表现为春季最大,夏、冬季次之,秋季最小。春、夏、秋、冬季热岛强度的年均值分别为1.0℃,0.8℃,0.6℃和0.7℃,其热岛强度增幅分别为0.23℃/10 a、0.33℃/10 a、0.30℃/10 a和0.23℃/10 a。沈阳市热岛强度的年均值达0.84℃,增幅为0.27℃/10 a。驱动沈阳市热岛强度的主要因素为城市人口数量（相关系数r=0.88）和城市绿地覆盖率。当城市绿地覆盖率超过30%时,城市热岛强度与城市绿地面积呈负相关,相关系数r=-0.74。     

Sequestration of toxic Pb(Ⅱ) ions by chemically treated rubber(Hevea brasiliensis) leaf powder

Rubber leaf powder(an agricultural waste) was treated with potassium permanganate followed by sodium carbonate and its performance in the removal of Pb(Ⅱ) ions from aqueous solution was evaluated.The interactions between Pb(Ⅱ) ions and functional groups on the adsorbent surface were confirmed by Fourier transform infrared(FT-IR) spectroscopy,scanning electron microscopy(SEM) coupled with X-ray energy dispersive spectroscopy(EDX).The effects of several important parameters which can affect adsorption capacity such as pH,adsorbent dosage,initial lead concentration and contact time were studied.The optimum pH range for lead adsorption was 4-5.Even at very low adsorbent dosage of 0.02 g,almost 100% of Pb(Ⅱ) ions(23 mg/L) could be removed.The adsorption capacity was also dependent on lead concentration and contact time,and relatively a short period of time(60-90 min) was required to reach equilibrium.The equilibrium data were analyzed with Langmuir,Freundlich and Dubinin-Radushkevich isotherms.Based on Langmuir model,the maximum adsorption capacity of lead was 95.3 mg/g.Three kinetic models including pseudo first-order,pseudo second-order and Boyd were used to analyze the lead adsorption process,and the results showed that the pseudo second-order fitted well with correlation coefficients greater than 0.99.     

基于HAZOP的保护层分析技术研究

介绍了“基于HAZOP的保护层分析技术”的工艺安全管理新模式。在此基础上,利用该方法对水煤浆气化装置进行了分析,识别出了装置存在的重大工艺危险,提出对策建议,对整个装置重大工艺安全事故的预防提供了有力的技术支持。