循环式超声强化光催化降解双酚A

设计了一种循环式超声强化光催化反应器,以TiO2作为光催化剂,研究了超声功率、TiO2加入量、循环液流速和空气流量对双酚A(BPA)降解效果的影响。实验结果表明:超声与光催化过程在循环式超声强化光催化反应器中实现了较好的协同效应;在初始BPA质量浓度为20.0mg/L、超声功率为600W、TiO2加入量为7g/L、循环液流速为4.05×10-2m/s、空气流量为200mL/min的条件下,反应150min后,BPA降解率可达90.5%,溶液中剩余BPA质量浓度仅为1.8mg/L,反应240min后TOC去除率可达84.5%。     

建筑垃圾再生利用存在的问题与对策

通过深入分析目前建筑垃圾再生利用存在的问题,有针对性地提出:政府在法律法规上给予再生产业扶持是建筑垃圾资源化再生利用的条件,民众理念更新是建筑垃圾再生利用的基础,建立有利于跟踪管理的再生产业链是建筑垃圾再生利用的关键.提出的对策旨在促进建筑垃圾资源化再生利用有序快速发展.     

Green manure plants for remediation of soils polluted by metals and metalloids: Ecotoxicity and human bioavailability assessment

Borage, white mustard and phacelia, green manure plants currently used in agriculture to improve soil properties were cultivated for 10 wk on various polluted soils with metal(loid) concentrations representative of urban brownfields or polluted kitchen gardens. Metal(loid) bioavailability and ecotoxicity were measured in relation to soil characteristics before and after treatment. All the plants efficiently grow on the various polluted soils. But borage and mustard only are able to modify the soil characteristics and metal(loid) impact: soil respiration increased while ecotoxicity, bioaccessible lead and total metal(loid) quantities in soils can be decreased respectively by phytostabilization and phytoextraction mechanisms. These two plants could therefore be used for urban polluted soil refunctionalization. However, plant efficiency to improve soil quality strongly depends on soil characteristics.     

诱导结晶工艺中诱品载体的选择与改性

以含铜废水为处理对象,重点考察了诱晶载体的表面性质及表面负荷对诱导结晶过程的影响。结果表明,在工艺启动初期,白云石以及碱式碳酸铜为诱晶载体时,铜的去除率在90％以上,石英砂对铜的去除率较低,但石英砂经表面改性后对铜的去除效率亦可达90％以上。在运行稳定后,几类诱导载体对铜的去除率皆能稳定在95％,说明诱晶载体的表面性质对诱导结晶工艺的影响主要在于反应启动初期,选择与目标结晶产物结构、成分相同或相似的诱晶载体有利于诱导结晶过程的进行。此外,研究结果还表明,诱晶载体表面负荷对结晶过程影响较大,诱导结晶除铜工艺中载体表面负荷不宜高于0．054gCu／（m2·d）。     

Biosorption properties of Cd(II), Pb(II), and Cu(II) of extracellular polymeric substances (EPS) extracted from Aspergillus fumigatus and determined by polarographic method

Extracellular polymeric substances (EPS) were extracted from Aspergillus fumigatus using cationic exchange resin technique. The EPS were mainly composed of polysaccharide and low quantities of protein and nucleic acid. Biosorption of Cd(II), Pb(II), and Cu(II) of EPS was investigated as a function of pH using differential pulse polarography and the Ruzic model. Results showed that the EPS biosorption capacity determined using either the direct titration curves i?=?f(C _M) or the method proposed by Ruzic (Analytica Chimica Acta 140:99–113, 1982) were coincident. Cu(II) had the highest affinity with EPS followed by Pb(II) and Cd(II). The total number of binding sites for Cu(II) and Cd(II) increased with pH in the range of 4.0–7.0. Similar trend was observed for Pb(II) at pH?4.0–5.0, while precipitates were observed at pH?6.0 and 7.0. The conditional binding constants of these three metals displayed low levels of fluctuation with pH and ranged from 4.02?±?0.02 to 5.54?±?0.05.     

长湖流域水质时空分布特征及影响因子

利用2009—2014年长湖5个水质监测点数据,采用时间序列法分析了长湖水质的时间变化规律,采用相关性分析法,分析了流域水污染的影响因子。结果表明:在时间上,长湖水污染物质量浓度季节变化明显,COD、TN、NH3-N均为7、9月较低,1、3月较高,丰水期水质好于枯水期。入湖地区TP质量浓度7月达最高值,且7月份入湖地区的桥河口、关沮口的NH3-N、TN含量稍高于5月。空间上,西北部入湖地区水质劣于湖心及东南部出湖地区。工业、生活等点源污水,以耕地为主的农业非点源以及天然降水量和径流量是影响水质的主要因素,入湖排污量、降水量和径流量与长湖水质呈显著相关关系(P0.05)。     

Cadmium accumulation characteristics of floricultural plant Cosmos bipinnata*

The artificially high soil cadmium (Cd) concentration screening method was used to screen Cd-hyperaccumulators from floricultural plants. Among the five species of floricultural plants screened, Cosmos bipinnata showed the characteristics of Cd-accumulators. A pot experiment was conducted to further study Cd accumulation characteristics of C. bipinnata. The results showed that the biomass, chlorophyll content, superoxide dismutase activity, peroxidase activity and soluble protein content of C. bipinnata first increased and later decreased with the increase in soil Cd concentration, but the carotenoid content and catalase activity of C. bipinnata reduced. Cd contents in roots, stems, leaves and shoots of C. bipinnata increased with increasing soil Cd concentration. When the soil Cd concentration was 50?mg?kg^?1, the Cd content in shoots was up to 112.62?mg?kg^?1, which was higher than the Cd-hyperaccumulator critical value. The root and shoot bioconcentration factors exceeded 1 in various Cd treatments, but the translocation factors were less than 1. When the soil Cd concentration was 50?mg?kg^?1, the Cd accumulation in shoots achieved the maximum of 224.30?μg plant^?1. Therefore, considering the tolerance and accumulation of Cd, C. bipinnata is a Cd-accumulator that could be used to remediate Cd-contaminated urban soil.     

Willingness and behavior towards e-waste recycling for residents in Beijing city,China

This paper is to investigate the behavior of residents towards electrical and electronic waste (e-waste) recycling in Beijing. For this purpose a large sample questionnaire survey was performed to explore the residents’ characteristics of recycling behavior and preference of e-waste recycling pattern. Besides, the willingness of residents to participate in e-waste recycling was also assessed in our study. For this a logistic regression model was developed to estimate and explain residents’ willingness in e-waste recycling. The model showed that Convenience of recycling facilities and service, Residential conditions, Recycling habit and Economic benefits are four determinants of Beijing residents’ willingness and behavior in e-waste recycling. And centralized recycling pattern by professional recovery spots would have a broad prospect if various kinds of channels can be provided to make the residents feel more convenient in e-waste recycling.     

微生物法和微生物生态法的评价和选用

微生物法和微生物生态法作为生物治理方案的两大类型，已日益受到环保工作者的重视。这两种类型的治理方法各有特点，各有利弊。如何选择使用？主要取决于污染场所中污染形成的时间长短、污染程度、污染物浓度、污染物中是否含有污水、是否需要快速治理等。应明确指出的是，采用生物治理法虽可在多种情况下大大降低污染物的浓度，但从长远来看，还不能单纯依靠降低污染物的排放浓度，而是应从低浓度污染物对人和环境产生的长期影响着眼，制定出一套治理标准，这样才能准确评价生物治理技术在环境保护中所起的真正作用。     

次氯酸钠氧化脱除黄磷尾气中的硫、磷杂质

采用次氯酸钠氧化工艺净化黄磷尾气，在次氯酸钠溶液中有效氯的质量分数为0．65％，PH为9、反应温度为285K，气体流速为0．6-0.8L/min的条件下，对尾气中H2S、PH3的脱除率分别达到99．9％，和99．8％，出口含量分别小于0.2mg/m^3和7mg/m^3，对有机硫也有30％的脱除能力。