全文获取类型
收费全文 | 2500篇 |
免费 | 157篇 |
国内免费 | 941篇 |
专业分类
安全科学 | 234篇 |
废物处理 | 134篇 |
环保管理 | 193篇 |
综合类 | 1541篇 |
基础理论 | 445篇 |
污染及防治 | 700篇 |
评价与监测 | 129篇 |
社会与环境 | 128篇 |
灾害及防治 | 94篇 |
出版年
2024年 | 13篇 |
2023年 | 72篇 |
2022年 | 142篇 |
2021年 | 149篇 |
2020年 | 122篇 |
2019年 | 107篇 |
2018年 | 122篇 |
2017年 | 136篇 |
2016年 | 100篇 |
2015年 | 155篇 |
2014年 | 201篇 |
2013年 | 207篇 |
2012年 | 219篇 |
2011年 | 220篇 |
2010年 | 159篇 |
2009年 | 154篇 |
2008年 | 192篇 |
2007年 | 137篇 |
2006年 | 147篇 |
2005年 | 86篇 |
2004年 | 60篇 |
2003年 | 84篇 |
2002年 | 88篇 |
2001年 | 86篇 |
2000年 | 63篇 |
1999年 | 55篇 |
1998年 | 51篇 |
1997年 | 43篇 |
1996年 | 51篇 |
1995年 | 36篇 |
1994年 | 38篇 |
1993年 | 21篇 |
1992年 | 20篇 |
1991年 | 11篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有3598条查询结果,搜索用时 62 毫秒
391.
Determination of atmospheric nitrate particulate size distribution and dry deposition velocity for three distinct areas 总被引:1,自引:0,他引:1
In this study, both atmospheric particulates and dry deposited particulates were collected at a highway intersection, coastal location and suburban area in Taichung, Taiwan for the characterization of nitrate containing particulates (NCPs) in size distribution and dynamic properties. Collected particulates were placed in contact with nitron (C20H16N4) to form distinctive products of NCPs, which were examined by a SEM. For total atmospheric particulates, the sum of NCP and non-nitrate containing particulate (NNCP), the average shape factor values are 1.69, 1.49, and 1.36 for the highway intersection, coastal area and suburban area, respectively. The calculated shape factors show no significant differences with sizes. Dry deposition fluxes and atmospheric concentrations at various size ranges were estimated. The mass distributed in fine particle range (相似文献
392.
393.
The parameters affecting the electron spin resonance (ESR) detection of hydroxyl free radical in water are studied and optimized. The hydroxyl radical is generated by the Fenton reaction with iron (II) ammonium sulfate and hydrogen peroxide reacting in a phosphate buffer using N-tert-butyl-alpha-phenylnitron as the spin trap. The concentrations of Fe2+, H2O2, and phosphate buffer are the parameters studied. The Taguchi method and the orthogonal experiment design were used to evaluate the effects of these parameters on the ESR signal intensity. By the analysis of the signal-to-noise ratio and the analysis of variance, the order of importance of the various parameters on the hydroxyl radical formation is determined for optimal ESR detection of hydroxyl radical. The results will help the development of water purification technologies using hydroxyl free radical as a green oxidant. 相似文献
394.
395.
396.
397.
398.
垃圾填埋场渗滤液处理工艺研究进展 总被引:1,自引:0,他引:1
介绍了垃圾渗滤液的来源和特点,结合近些年的工程实际和实验研究,主要综述了垃圾渗滤液的处理方案和技术,包括回灌法、土地处理法、物化法、生物法以及其他处理方法,在比较这些方法的基础上提出了一些建议。 相似文献
399.
分别采用7-乙氧基异酚恶唑酮.脱乙基酶(EROD)活性测定法,重组人激素受体基因的酵母测试和Q67发光菌试验方法,对北京市某生活污水处理厂的进水、二沉出水以及经过石灰法深度处理后的出水中的类二恶英物质、类雌激素物质和急性毒性物质进行了分析。进水中的三类生物毒性效应物质中的急性毒性物质,可通过活性污泥法基本去除,而对类雌激素物质和类二恶英物质的去除率分别为76%和52%。经过石灰沉淀法的深度处理后,可使上述两类物质的总去除率达到95%和68%。出水中的雌激素当量水平与欧洲国家污水处理厂出水水平相当,而类二恶英物质的总浓度低于美国EPA饮用水中二恶英的最大允许浓度。展示了生物毒性测试方法在排水生态风险和工艺评价方面的应用潜力。 相似文献
400.
The comparative toxicities of selected phenols to higher plants Cucumis sativus were measured and the negative logarithm molar concentration of the root elongation median inhibition (IRC50) were derived. Quantitative structure-activity relationships (QSARs) were developed to explore the toxicity influencing factors and for predictive purpose. The toxicity data, fell into two classes: polar narcosis and bio-reactive. For polar narcotic phenols, a highly significant two-parameter QSAR based on 1-octanol/water partition coefficient (logKow) and energy of the lowest unoccupied orbital (E(lumo)) was derived (IRC50 = 0.77 log Kow - 0.39E(lumo) + 2.36 n = 22 r2 = 0.89). The five bio-reactive chemicals proved to show elevated toxicity due to their typical substructure involved diverse reactive mechanisms. In an effort to model all chemicals, a robust multiple-variable QSAR combining logKow, E(lumo) and Qmax, the most negative net atomic charge, was developed (IRC50 = 0.65 logKow - 0.72E(lumo) + 0.23Qmax + 2.81 n = 27 r2 = 0.94), indicating that hydrophobicity, electrophilicity and hydrogen bond interaction contribute mainly to the phytotoxicity. The toxicological data was compared with Tetrahymena pyriformis 2-d population growth inhibition toxicity (IGC50) and excellent interspecies correlations were observed both for the polar narcotics and for five reactive chemicals (for polar narcotics: IRC50 = 0.95IGC50 + 1.07 n = 16 r2 = 0.89; for bio-reactive chemicals: IRC50 = 0.98IGC50 + 2.19 n = 5 r2 = 0.97; and for all: IRC50 = 0.93IGC50 + 1.63 n = 21 r2 = 0.87). This suggested that T pyriformis toxicity could serve as a surrogate of C. sativus toxicity for phenols and interspecies correlation also could be established for reactive chemicals. 相似文献