背景溶液对纳米氧化铁吸附病毒的影响

以噬菌体X174为病毒替代,通过等温静态批量吸附实验,研究了4种纳米氧化铁(α-Fe2O3、γ-Fe2O3-B、γ-Fe2O3-N、Fe3O4)对病毒在不同背景溶液中的吸附行为及其影响因素.结果表明,在模拟地下水中,4种纳米氧化铁对病毒均具有较高的吸附比例,其中α-Fe2O3对病毒吸附比例最高,在病毒初始浓度比较低(约1E+03PFU.mL-1)时可达100%.经Langmuir和Freundlich吸附等温线方程对上述吸附结果进行拟合表示,纳米氧化铁对病毒的吸附均为有利吸附(favorable adsorption),并可能存在多层吸附,吸附比例均随着病毒初始浓度的增加而减少.纳米氧化铁对病毒的吸附比例随着背景溶液离子强度的增加而降低,表示其吸附行为以电性吸附为主.背景溶液中阴离子存在显著降低了病毒的吸附量,这可能与阴离子竞争病毒吸附位点有关,其中HPO24-比HCO3-表现得更为明显.结果同时显示背景溶液中多价阳离子的存在(比如Ca2+和Mg2+)比单价阳离子(比如Na+和K+)更有利于纳米氧化铁对病毒的吸附.综上可知,纳米氧化铁是一种潜在的病毒净化理想材料,应用时需考虑其环境因素的影响.     

Monitoring of air pollution by polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans of pine needles in Korea

The atmospheric contamination levels of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were evaluated from the analysis of pine needles in South Korea. Pine needles were collected from 30 sampling points at five main cities in South Korea (Busan, Daegu, Gwangju, Changwon and Jeju island). The highest concentrations of PCDDs/DFs (2.19–26.88 pg I-TEQ/g of dry weight) were measured at Busan, where is the city of the highest population density and traffic volume among five cities. The lowest concentration was detected at Jeju with 0.62 pg I-TEQ/g dry weight, suggesting Jeju could be an environmental background area in Korea. The dominant homologues of PCDDs/DFs in pine needles were the lower chlorine-substituted compounds such as tetra CDDs and CDFs, and the distribution ratios of PCDDs/DFs decreased with increase of the number of chlorine substituents. Homologue profiles of pine needle samples were similar to PCDDs/DFs profiles of the vapor phase in the ambient air, and thus the pine needles absorbed the vapor phase of PCDDs/DFs from air. Results suggested that pine needles could be used as an indicator of the atmospheric contamination for PCDDs/DFs in Korea.     

Exploring the impact of new particle formation events on PM2.5 pollution during winter in the Yangtze River Delta, China

New particle formation（NPF） events are an increasingly interesting topic in air quality and climate science. In this study, the particle number size distributions, and the frequency of NPF events over Hefei were investigated from November 2018 to February 2019. The proportions of the nucleation mode, Aitken mode, and accumulation mode were 24.59%,53.10%, and 22.30%, respectively, which indicates the presence of abundant ultrafine particles in Hefei. Forty-six NPF events occurred during the obser...     

Study on Residential Water Use in North China:Analysis of Nationwide Statistical Data and Case Study of Taiyuan City

Residential water use is gradually becoming the focus in China‘s municipal water supply planning and management in recent years. Little is known, however, about the residential water use in modem China due to the transition of economy and enhancement of management on water conservation. In order to better understand the characteristics of residential water use in North China, a model for identifying the determinants of residential water use was established and analyzed by using panel data and cross-section data methodologies. Then Taiyuan city, the capital city of Shanxi Province in Northern China was selected as a case study. Both the analyses and field investigation indicate that the relatively slow increase of residential water use in recent years may result from the implementation of strict laws and regulations on water conservation. And through the investigation,first-hand information about water consumption pattern, water reuse/conservation, people‘s attitude toward water quantity and quality, etc. have been obtained.     

可计算一般均衡(CGE)模型与环境政策分析

CGE模型是进行环境政策分析的理想工具，实际上CGE模型也是唯一胡可能精确评估环境政策社会成本的分析手段。本文介绍了在环境政策分析中应用CGE模型的基本思路和不同类型；回顾了CGE模型在环境政策分析中的应用领域及国内应用现状；指出今后的环境政策分析中应用的CGE模型应该更多地结合经济体的现实特征，其发展方向则体现在三个方面；在分析环境政策社会成本的同时也考虑这些政策的社会效益、分析环境政策的分配效应、加强区域CGE模型在环境政策分析中的应用。     

区域二氧化硫控制优化模型研究

传统的区域二氧化硫控制优化都是基于损害函数法和环境标准化法的。本文在分析比较了传统二氧化硫污染控制战略优化中的损害函数法和环境标准化法各自的优点与局限的基础上。建立了基于时间序列决策的整数规划优化模型。这一理论模型更好地描述了控制战略实施的过程。把时间作为模型优化的一个因子。这种基于时间序列的过程充分考虑了货币的时间价值。并能分析这些时间价值对二氧化硫污染控制战略的动态过程影响。本文的模型是更加符合现实的情况。它对于区域二氧化硫控制的中长期决策优化显得更为有效和准确。     

饮用水中半挥发性有机物的定性检测

内江二水厂以沱江水为水源，本文通过对该水厂出厂水的液—液萃取，用色—质联机定性检测出９７种半挥发性有机物。结果表明：沱江水质的有机污染仍很严重     

江苏海洋开发的资源环境条件评述

江苏海洋的区位优越，海域广阔，环境条件总体有利，海洋资源种类多，数量大，具有综合开发功能，而且资源和环境的区域组合良好，有利于海洋产业的集约经营和协调发展，但也存在不少限制因素，如深水区离岸较远，海底矿产勘探程度低，自然灾害较多等。应根据实际情况确定本省海洋的开发战略。     

A numerical simulation model of cyclic hardening behavior of AC4C-T6 for LNG cargo pump using finite element analysis

This paper is concerned with the evaluation of cyclic hardening models within the stress–strain behavior of aluminum alloy AC4C-T6 that can be used to LNG cargo pump operating in cryogenic temperature. To insure the strength assessment of LNG cargo pump, material model of cyclic hardening and plasticity for aluminum alloy AC4C-T6 is investigated through FEA (Finite Element Analysis) with various hardening options including linear and non-linear hardening, isotropic and kinematic hardening, and combined hardening model. Monotonic tensile and cyclic tensile experiments for AC4C-T6 alloy were performed at room temperature and temperature of ?165 °C. Parameters of each hardening model are obtained from the experimental data; thus five hardening models are numerically simulated thereafter. Appropriate hardening models which describe the cyclic stress–strain relationship are investigated through the simulations of cyclic hardening behavior by FEA. In order to verify the predicted behavior of cyclic hardening obtained by FEA, the results of FEA and those measured by experiments are compared.