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381.
Yongfeng Ji Zidan Yuan Guoqing Zhang Xing Wu Xu M Jinru Lin Shaofeng Wang 《环境科学学报(英文版)》2023,35(2):31-41
An advanced cost-saving method of removal of high-As(Ⅲ) from SO4(-Ⅱ)-rich metallurgi cal wastewater has been developed by diluting the SO4(-Ⅱ) content with As(Ⅲ)-Cl(-Ⅰ)-rich metallurgical wastewater and then by the direct precipitation of As(Ⅲ) with Fe(Ⅲ) at pH2.3.As(Ⅲ) removal at various SO4(-Ⅱ)/Cl(-Ⅰ) molar ratios and temperatures was investigated The results showed that 65.2–98.2%of As(III) immobilization into solids occurred at the SO4(Ⅱ)/Cl(-Ⅰ) mo... 相似文献
382.
The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric
reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO
initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10−3 and 1.94 × 10−5 min−1respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H2O2 and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed. 相似文献
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386.
J. N. Proust J. F. Deconinck J. R. Geyssant J. P. Herbin J. P. Vidier 《Geologische Rundschau》1995,84(2):255-271
An interdisciplinary approach based on high-resolution physical stratigraphy, biostratigraphy, organic matter analysis and clay mineralogy has been applied to the mixed siliciclastic/carbonate Kimmeridgian/Tithonian deposits of the Boulonnais (north-western France). These rocks are the age-equivalents of some of the offshore marine source rocks of the North Sea and were deposited in an overall storm-dominated homoclinal ramp setting which may represent one of the most shore-proximal sediments of this age cropping out in north-western Europe. Comparison with data from the Yorkshire, Dorset, Lorraine and Aquitaine areas allows the discrimination of three major transgressive-regressive sediment packages with disconformities of interregional extent: (1) from the Baylei Zone to top Eudoxus Zone; (2) from the Autissiodorensis Zone to base Scitulus Zone; (3) from the upper Scitulus Zone to the Pectinatus Zone. The lower two regionally correlative disconformities correspond to the sequence boundaries at the top of the Eudoxus Zone and the top of the Autissiodorensis Zone, formed by high-frequency relative sea-level variations during the periods of maximum transgression of the platform. The latter disconformity (the P1 nodule bed) reflects a major tectonically induced reorganization of the north-west European intrashelf sedimentary basin, characterized by a shift in both the location of the main depocentre and the sources of sediment production. 相似文献
387.
N. V. Kovganko Zh. N. Kashkan Yu. G. Chernov S. K. Ananich S. N. Sokolov et al. 《Die Naturwissenschaften》1995,82(5):252-252
XII Ecdysone Workshop July 22–26, 1996 Barcelona, Spain 相似文献
388.
降低油品储运损耗 改善大气环境 总被引:4,自引:0,他引:4
从石油开采到成品油进入清费的过程中,损耗量约占原油量的3%-5%,其中储运过程中的损耗占总耗的40%-50%,着重论述了油品储运过程中降低损耗的措施,以减少经济损失和对环境的破坏。 相似文献
389.
S.M.Semenov 《环境科学学报(英文版)》1992,4(1):10-14
An integrated approach was developed to determine the critical levels of air pollution for ecological standard setting based on the unified index of biological response, by taking into account the effects of all pollution components simultaneously. An empirical model of plant productivity was taken as the dose response model for gaseous pollutant effect on the productivity of trees and the annual productivity of plants was used as the above mentioned index. The CO2 increase in the lower atmosphere was considered to potentially increase plant productivity and NO2 was estimated as neutral while being dangerous for plants as a chemical precursor of ozone or as a source of acidification. The maximum permissible chronic O3 and SO2 levels for trees were estimated and it was found that O3 is much more phytotoxic, as compared to SO2 , with a rather narrow range of permissible levels (27-33 ppb) which complicates its monitoring and control. 相似文献
390.
杂多化合物脱硫化氢动力学研究 总被引:5,自引:0,他引:5
在双搅拌、无浓度梯度气液反应器中考察了磷钼杂多化合物吸收H2S过程的宏观动力学行为.结果表明,吸收剂浓度提高,脱硫效果增强,当磷钼酸钠浓度超过6.25×10-3mol/L后,单一与复配体系对H2S的吸收速率均趋恒定.从工业操作角度来看,6.25×10-3mol/L是适宜的操作浓度温度提高,吸收效果略有降低,但变化幅度不大,实际操作温度可选择常温;进气H2S浓度提高,吸收效果增强.两种脱硫体系中,以复配体系脱硫性能为优.实验测得25℃下反应器中H2S的气、液相传质系数分别为:kGH-2S =8.201×10-10kmol/(m2.s.Pa),kLH-2S=3.440×10-4m/s.吸收反应对磷钼酸钠及硫化氢的反应级数分别为0.339与1.055. 相似文献