脱硫后净烟气携带浆液量监测的实验研究

在WFGD系统中,净烟气携带的浆液液滴引起后续设备的腐蚀堵塞,带来的景观污染问题影响周围居民的正常生活.为了精确量化脱硫后净烟气携带浆液量,提出了适用于环境监测专业的测试取样分析方法,并对该方法进行了讨论分析.实验结果表明:该方法的适用范围为净烟气浆液液滴含量在1.1 mg/Nm3以上,通过对取样分析关键环节的讨论分析...     

过渡金属浸渍改性ACF去除H2S研究

为探讨活性炭纤维(ACF)去除恶臭气体H2S的性能,采用过渡金属浸渍改性ACF吸附H2S,揭示出改性ACF前后吸附H2S的性能差异及浸渍剂的浓度和种类对ACF吸附性能的影响。结果表明,通过过渡金属改性后的ACF吸附性能有显著提高,对H2S吸附是物理吸附和化学吸附共同作用的结果,改性后的ACF硫容量大小依次为：5％硝酸铜...     

Effect of aeration modes on the characteristics of composting emissions and the NH3 removal efficiency by using biotrickling filter

A pilot biotrickling filter (BTF) packed with ZX02 fibrous balls as packing material was tested for the treatment of ammonia (NH₃) released from a composting plant of dairy manure. In order to investigate the effects of three compost aeration modes (mode Co-I, Co-II and In-II) on the NH₃ removal efficiency, a field experiment was continuously carried out for more than eight months. The results demonstrated that under the intermittent aeration mode (In-II), the NH₃ removal efficiency reached 99.2 ± 0.1% when the inlet NH₃ concentration was 7.5-32.3 mg m⁻³ (9.8-42.5 ppmv). The maximum and critical elimination capacity of the biotrickling filter was 22.6 and 4.9 g NH₃ m⁻³ h⁻¹, respectively. The effluent concentration of NH₃ was lower than 1.0 mg m⁻³, which meets the first class discharge standards of GB14554-93. When the concentration of free ammonia in the trickling liquid was varied from 0.1 to 0.4 mg L⁻¹, the nitrification yield was between 47.9% and 103.8%. In addition, the optimum liquid tricking velocity (LTV) of the biotrickling filter was 0.5 m³ m⁻² h⁻¹ for low inlet concentrations and 2.2 m³ m⁻² h⁻¹ for high inlet concentrations. Therefore, the use of the biotrickling filter for the compost under the third aeration mode (In-II) yielded an effective optimum NH₃ removal and reduced the nitrogen loss in the compost.     

废旧印刷线路板的热重分析及热解动力学模型

采用热重(TG)分析法研究了废旧FR4型印刷线路板(PCB)的热解特性,探讨了不同升温速率下废旧PCB的TG和微分热重(DTG)曲线及变化规律,利用Starink法精确求解热解反应活化能(E),利用Malek法判断得出废旧PCB的热解动力学机理函数和指前因子(A).研究结果表明:废旧FR4型PCB的TG和DTG曲线随着...     

An overview of municipal solid waste management in Inner Mongolia Autonomous Region,China

Rapid industrialization and urbanization in developing countries have created serious problems in municipal solid waste (MSW) management. New case studies can shed light on these problems and point the way to potential solutions for improving the overall eco-efficiency of MSW management. This paper employs a case study approach, analyzing MSW management in Inner Mongolia. This study encompasses all aspects of MSW management, including collection, separation, recycling, and disposal. Problems and challenges are identified through our analysis, and recommendations are raised by considering the local realities. Our main findings are: (1) while large cities have already established a solid foundation for MSW management, small- and medium-sized cities deserve more attention; (2) MSW in rural areas is even worse than urban areas; (3) enforcement of MSW regulations is ineffective and needs improvement; (4) lack of funds, R&D efforts and advanced technologies have impeded sustainable MSW management; (5) lack of coordination and communication among different stakeholders further damages the efforts for improvement of MSW management. Therefore, integrated efforts that combine the above concerns should be initiated so that the overall effectiveness and efficiency of MSW management can be improved.     

中国环保行政体制结构初探

环保行政体制结构是环保行政组织系统的基本框架,是实现环保行政管理职能的组织方式。我国长期以来的环保行政体制改革较为关注机构地位提升与管理职能强化,环保行政体制的结构较少得到关注。对环保行政体制结构的分析揭示了在机构地位提升与管理职能得到强化的前提下我国环保行政管理依然面临执法监督难、部门协调难等问难题的深层体制原因。本文首先根据组织行为学的基本原理,提出我国环保行政体制的矩阵结构模式,这一矩阵结构在纵向上存在双权威系统,横向上协调关系较为薄弱,从而造成环保监管权威弱化。其次,基于对我国地方环保行政体制改革效果的调查,指出我国环保行政体制结构出的了若干变化。最后,结合我国"十二五"时期落实国家环保意志的基本要求,提出改善我国环保行政体制结构的若干政策建议,即在基层改善体制结构中的双权威系统,并以流域水环境管理体制创新为大部门体制改革突破点,探索环境管理职能组织方式的优化途径。     

卡马西平降解菌的筛选分离及其降解机理

药品污染物日益成为新兴污染物研究的重点,药品卡马西平因具有多种药效被广泛使用,在环境中频繁被检出,且浓度较高,不易去除,通常作为环境中药品污染状况的指示化合物。本研究从长期用于去除药品废水的曝气生物滤池中分离出一株细菌YK-6,其能以卡马西平为惟一碳源、氮源和能源生长,通过生理生化以及16S rDNA基因序列分析鉴定并命名为Pseudomonas putida YK-6。该菌株YK-6在pH为7.2、温度30℃、卡马西平初始浓度为20 mg/L、摇床振荡速率为160 r/min的生长条件下培养5 d,对卡马西平的降解率可达54.66%。菌株YK-6对卡马西平的可能降解途径为首先通过生物的氧化作用,将CBZ氧化成CBZ-EP,CBZ-EP经过水解作用转化为CBZ-DiOH,CBZ-DiOH经丙酮酸氧化脱羧及在NADH还原性辅酶的作用下,裂解成苯胺和邻苯甲酸,苯胺和邻苯甲酸再经进一步氧化,直至最终矿化。     

Control strategies of atmospheric mercury emissions from coal-fired power plants in China

Atmospheric mercury (Hg) emission from coal is one of the primary sources of anthropogenic discharge and pollution. China is one of the few countries in the world whose coal consumption constitutes about 70% of total primary energy, and over half of coals are burned directly for electricity generation. Atmospheric emissions of Hg and its speciation from coal-fired power plants are of great concern owing to their negative impacts on regional human health and ecosystem risks, as well as long-distance transport. In this paper, recent trends of atmospheric Hg emissions and its species split from coal-fired power plants in China during the period of 2000-2007 are evaluated, by integrating each plant's coal consumption and emission factors, which are classified by different subcategories of boilers, particulate matter (PM) and sulfur dioxide (SO2) control devices. Our results show that the total Hg emissions from coal-fired power plants have begun to decrease from the peak value of 139.19 t in 2005 to 134.55 t in 2007, though coal consumption growing steadily from 1213.8 to 1532.4 Mt, which can be mainly attributed to the co-benefit Hg reduction by electrostatic precipitators/fabric filters (ESPs/FFs) and wet flue gas desulfurization (WFGD), especially the sharp growth in installation of WFGD both in the new and existing power plants since 2005. In the coming 12th five-year-plan, more and more plants will be mandated to install De-NO(x) (nitrogen oxides) systems (mainly selective catalytic reduction [SCR] and selective noncatalytic reduction [SNCR]) for minimizing NO(x) emission, thus the specific Hg emission rate per ton of coal will decline further owing to the much higher co-benefit removal efficiency by the combination of SCR + ESPs/FFs + WFGD systems. Consequently, SCR + ESPs/FFs + WFGD configuration will be the main path to abate Hg discharge from coal-fired power plants in China in the near future. However advanced specific Hg removal technologies are necessary for further reduction of elemental Hg discharge in the long-term.     

非农就业、社会保障与农户土地转出——基于30镇49村476个农民的实证分析

基于江苏省沭阳县的调查数据,对农民非农就业、社会保障与其土地转出意愿与行为的关系进行了实证分析。首先,结构方程模型(SEM)研究结果表明,土地所具有的多重功能价值对农民的土地流转意愿具有重要影响。其中土地的直接经济价值与农民土地转出意愿呈现出负相关关系;土地转出预期价值对农民土地转出意愿的影响最大,农民土地转出的预期回报对意愿具有显著的正向影响;若有完善的非农就业环境与社会保障制度能代替土地本身承载的就业价值与社会保障功能,则会对农民土地转出意愿产生积极的正向作用。其次,Probit和Tobit模型计量检验结果表明,具有非农就业经验以及家庭非农劳动力越多的农民转出其土地的可能性越大,转出的面积也越多;农民参加的社会保障水平越高,土地的保障性功能相对就越小,农民对土地的依赖性越低,从而转出其土地的可能性越大,转出的面积也越多。在此基础上,得出了要大力发展非农产业,营造良好的外部就业环境,进一步完善农村社会保障体系等政策启示。     

太湖流域上游河流污染空间分布特征研究

为把握太湖流域上游西北部河网区域水体的N、P污染特征及其空间分布,2010年8月在该区域内的武进港 直湖港水系、洮滆水系、丹扁孟河（丹金溧漕运河、扁担河及孟津河）以及宜溧河水系的河网,监测了39个河流断面的水质。研究表明,4水系TN平均浓度分别为388、283、291及193 mg/L,DTN占TN比重分别为9180%、7843%、7001%及8444%,河网氮输出均以DTN为主。在DTN中NO-3 N浓度所占比重分别为6747%、5275%、7748%及4281%,NH+4 N浓度所占比重分别为1633%、3316%、1127%及4351%。TP平均浓度分别为059、030、026及015 mg/L,DTP所占比重分别为6213%、4019%、4673%及3197%,而PO3-4 P浓度占DTP比重分别为2073%、5461%、4327%及7772%。武进港 直湖港水系N平均浓度显著（〖WTBX〗p〖WTBZ〗<001）高于宜溧河水系,与其它两水系无显著差异,P平均浓度显著（〖WTBX〗p〖WTBZ〗<005）高于宜溧河水系和丹扁孟河,与洮滆水系无显著差异。影响太湖流域上游西北部区域河流水网水质的主导因素为氮污染,而其中以DTN污染最为严重。太湖西北部是蓝藻水华暴发的重灾区,上游区域DTN的大量输入,将成为引发太湖水体生态系统灾变的潜在风险