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三维电极-好氧生物法联合处理酸性染料废水模拟研究 总被引:1,自引:0,他引:1
采用电解-好氧生物法联合处理酸性大红G模拟废水,三维电解反应器填料为活性炭与玻璃珠混合物,平板电极材料为石墨,通过正交实验确定的最佳实验条件为:电解时间150min,活性炭/玻璃珠体积比为2:1,槽电压20V、pH为5、Na2SO4投加量1.5g/L,进水初始浓度2000mg/L。此时COD去除率及色度去除率分别可达49.78%和81.45%,废水BOD,/COD由0.12提高到0.42。电解后的废水采用生物接触氧化法处理12h后,出水COD为48mg/L,色度120倍,达到综合污水排放二级标准。 相似文献
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The important role of microwave receptors in bio-fuel production by microwave-induced pyrolysis of sewage sludge 总被引:1,自引:0,他引:1
Microwave receptor plays an important role in the microwave pyrolysis of sewage sludge in view of its significant influence on the yield and property of bio-fuel products. The yield and the chemical compositions of bio-fuels (gases and oils) obtained from sewage sludge mixed with different receptors (graphite, residue char, active carbon or silicon carbide) were investigated in this study by Gas Chromatography (GC), Gas Chromatography-Mass Spectrometry (GC-MS), and Fourier Transform Infrared Spectroscopy (FTIR). The results showed that the use of silicon carbide gave rise to the highest final temperature of 1130 °C, resulting in the highest yield of gas fraction (up to 63.2 wt.%). The low heating rate (200 °C/min) which was attributed to the addition of residue char promoted condensation reactions and resulted in an increase in solid yield. The existence of active carbon could prolong the resistance time of volatiles in the hot zone owing to its porous structure, generating the maximum concentration of H2 + CO (60%) in the pyrolysis gas. When graphite was used, the final low temperature favoured the cyclization of the alkenes, giving rise to a higher concentration of mononuclear aromatics in the pyrolysis oils. The model established in this study revealed that the quantity and quality of the products obtained from the microwave pyrolysis highly depended on the process conditions, which were influenced by the receptor significantly. 相似文献
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Production of monoclonal antibody and application in indirect competitive ELISA for detecting okadaic acid and dinophytoxin-1 in seafood 总被引:1,自引:0,他引:1
SY Lu Y Zhou YS Li C Lin XM Meng DM Yan ZH Li SY Yu ZS Liu HL Ren 《Environmental science and pollution research international》2011,19(7):2619-2626
Background, aim, and scope
Okadaic acid (OA) and analogues of dinophysistoxin (DTX) are key diarrheic shellfish poisoning (DSP) toxins, which possibly arouse DSP symptoms by consuming the contaminated shellfish. Because of the stable toxicity in high temperature and the long-term carcinogenicity, the outbreaks of DSP related to consumption of bivalve mollusks contaminated by DSP toxins pose a hazard to public health. Therefore, it is worth developing a fast and reliable analytical method for the detection of OA and analogues in shellfish. In this paper, an indirect competitive enzyme-linked immunosorbent assay (ELISA) (icELISA) for detecting OA and DTX-1 in seafood was developed based on monoclonal antibody (McAb).Methods
The OA was conjugated to human immunoglobulin G (IgG) and bovine serum albumin (BSA) by the active ester method as the immune antigen and the detective antigen. The spleen cells from BALB/c mice immunized with OA-IgG were fused with SP2/0 myeloma cells. A hybridoma cell line, which secreted McAb against OA, was selected by ??limiting dilution?? cloning. An icELISA was developed based on immobilized conjugate (OA-BSA) competing the McAb with the free OA in seafood sample.Results
A hybridoma cell line, which secreted IgG1 subclass monoclonal antibody (McAb) against OA, was selected. The IC50 of the McAb for OA and dinophytoxin-1 (DTX-1) were 4.40 and 3.89 ng/mL, respectively. Based on the McAb, an indirect competitive ELISA for detection of OA and DTX-1 in seafood was developed. The regression equation was y?=?54.713x???25.879 with a coefficient correlation of R 2?=?0.9729. The linear range and the limit of detection were 0.4?C12.5 and 0.45 ng/mL, respectively. The average recovery of OA and DTX-1 spiked shellfish was 82.29% with the coefficient of variation of 7.67%.Conclusion
The developed icELISA is a fast, sensitive, and convenient assay for detecting of total amount of OA and DTX-1 in seafood. 相似文献997.
用生命周期的方法评价铜炉渣作为铜选矿原料的环境影响 总被引:3,自引:0,他引:3
运用生命周期评价的方法,分别对铜炉渣和铜矿石回收铜的选矿过程的环境协调性进行了对比研究,得到了选矿生产过程中各工序的环境负荷数据。评价结果表明,铜炉渣的人类健康损害、生态系统损害和资源损害分别为0.20783、0.00764和0.01919,而铜矿石的分别是0.08165、0.0075和0.08857,铜炉渣生产铜的资源损害比铜矿石低,而人类健康损害和生态系统损害比铜矿石高,铜炉渣选矿生产过程每生产1 kg渣精矿的环境负荷约为铜矿石的1.32倍。随着国内铜精矿供应缺口的增大,从铜炉渣中回收铜资源将显著地提高资源利用率,有利于循环经济的发展。 相似文献
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给水厂与污水厂污泥制陶粒技术研究 总被引:4,自引:2,他引:2
对天津凌庄自来水厂的给水厂污泥和天津东郊污水处理厂的污水厂污泥的成分进行了分析,在此基础上根据焙烧陶粒的原理,设计了以2种污泥为原料焙烧陶粒的工艺流程。通过实验,研究了其工艺过程中的影响因素并确定了工艺参数。性能检验结果表明,添加量为30%的混合污泥陶粒,在1 140℃焙烧5 min,可得到强度标号为40 MPa的高强陶粒。因此,以2种污泥为原料烧制陶粒的处置方法可行,并能带来一定的经济效益、社会效益和环境效益。得到的产品符合国标中高强陶粒的要求,可广泛应用于建筑行业中的承重结构。 相似文献