Accumulation of perfluorinated compounds in captive Bengal tigers (Panthera tigris tigris) and African lions (Panthera leo Linnaeus) in China

The accumulation of perfluorinated compounds (PFCs) in the sera of captive wildlife species Bengal tigers (Panthera tigris tigris) and African lions (Panthera leo Linnaeus) from Harbin Wildlife Park, Heilongjiang Province, in China were analyzed by high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). Perfluorooctanesulfonate (PFOS) was the predominant contaminant with a mean serum concentration of 1.18 ng mL(-1) in tigers and 2.69 ng mL(-1) in lions. Perfluorononanoic acid (PFNA) was the second most prevalent contaminant in both species. The composition profiles of the tested PFCs differed between tigers and lions, and the percentages of perfluorooctanoic acid (PFOA) were greater in lions than in tigers, indicating different exposures and/or metabolic capabilities between the two species. Assessments of the risk of PFC contamination to the two species were obtained by comparing measured concentrations to points of departure or toxicity reference values (TRVs). Results suggest no risk of PFOS exposure or toxicity for the two species.     

ClO2氧化/TiO2复合吸附剂协同体系处理印染废水的实验研究

利用ClO2 氧化/TiO2 复合吸附剂协同体系对处理实际印染废水进行了实验研究.结果表明,对于COD为750 mg/L、色度为250倍、SS为100 mg/L的1 000 mL印染废水,当溶液pH为4.0、ClO2 用量20 mg/L、TiO2 复合吸附剂用量2.5 g、反应时间和吸附时间分别为2、8 min时,处理后的废水COD＜100 mg/L、色度＜40倍、SS＜70 mg/L,达到了《纺织染整工业水污染物排放标准》(GB 4287-92)排放要求.并对两者的协同机理进行了理论上的探讨.     

适于环境容量初始配置的两步削减模型及应用

在由目标总量控制向容量总量控制的过渡时期,现有排污量往往超过区域的环境容量.因此,确定企业排污削减的比例,成为该时期环境容量初始配置的核心任务.以公平与效率为基本原则,构建了由法定削减与公平削减组成的两步削减模型,并联合应用模糊聚类分析法和层次分析法对模型参数进行求解,在太仓经济开发区环境容量的初始分配中进行了运用.模型的建构思路与求解方法可为相关的环境管理者提供参考.     

Assessment of the temporal and spatial distribution of atmospheric PCNs and their air–soil exchange using passive air samplers in Shanghai,East China

A total of 47 passive air samples and 25 soil samples were collected to study the temporal trend, distribution, and air–soil exchange of polychlorinated naphthalenes (PCNs) in Shanghai, China. Atmospheric PCNs ranged from 3.44 to 44.1 pg/m³ (average of 21.9 pg/m³) in summer and 13.6 to 153 pg/m³ (average of 40.0 pg/m³) in winter. In the soil samples, PCN concentrations were 54.7–1382 pg/g dry weight (average of 319 pg/g). Tri-CNs and tetra-CNs were two dominant homolog groups in air samples, while di-CNs were also found at comparable proportions to tri-CNs and tetra-CNs in soil samples. Most air and soil samples from the industrial and urban areas showed higher PCN concentrations than those from suburban areas. However, some soil samples in urban centers presented higher PCN concentrations than industrial areas. Analysis of PCN sources indicated that both industrial thermal process and historical usage of commercial PCN mixtures contributed to the PCN burden in most areas. The fugacity fraction results indicated a strong tendency of volatilization for lighter PCNs (tri- to hexa-CNs) in both seasons, and air–soil deposition for octa-CNs. Moreover, air–soil exchange fluxes indicate that soil was an important source of atmospheric PCNs in some areas. The results of this study provide information for use in the evaluation of the potential impact and human health risk of PCNs around the study areas.

     

高校大学生教材循环利用态度的调查分析

高校教材数量多,使用寿命短,每年毕业季大量教材被废弃或当做废纸卖掉,缺乏良好的处理途径,造成严重的资源浪费。在提倡节约型社会和可持续发展的大背景下,以网络问卷的方式调查了在校大学生目前的教材利用情况以及对教材循环利用的态度,并查阅相关文献资料,综合分析实施教材循环的基础和现状,并提出相应的可行性措施和建议。调查结果表明,高校教材保存完好、学生参与教材循环利用的态度积极以及部分高校教材循环利用的经验相对成熟等。因此,高校具备实施教材循环利用的良好基础。教材循环利用的开展不仅可以获得生态效益和经济效益,还可以增强学生的环保节俭意识,对培育绿色环保的校园文化,培养学生社会责任感具有极大的帮助。     

Sources of methacrolein and methyl vinyl ketone and their contributions to methylglyoxal and formaldehyde at a receptor site in Pearl River Delta

Methacrolein(MACR) and methyl vinyl ketone(MVK) are two major intermediate products from the photochemical oxidation of isoprene, the most important biogenic volatile organic compound. In addition, MACR and MVK have primary emissions. Investigating the sources and evolution of MACR and MVK could provide helpful information for the oxidative capacity of the atmosphere. In this study, hourly measurements of isoprene, MACR, and MVK were conducted at a receptor site in the Pearl River Delta region(PRD), i.e., the Heshan site(HS), from 22 October to 20 November, 2014. The average mixing ratios of isoprene,MACR and MVK were 151 ± 17, 91 ± 6 and 79 ± 6 pptv, respectively. The daily variations and the ratios of MVK/MACR during daytime and nighttime suggested that other sources besides isoprene photooxidation influenced the MACR and MVK abundances at the HS.Positive matrix factorization was utilized to resolve the sources of MACR and MVK. Five sources were identified and quantified, including biogenic emissions, biomass burning,secondary formation, diesel, and gasoline vehicular emissions. Among them, secondary formation made the greatest contribution to observed MACR and MVK with average contributions of ～ 45% and ～ 70%, respectively. Through the yields of secondary products from the oxidation of MACR and MVK by the OH radical and the concentrations of MACR and MVK, it was found that methylglyoxal and formaldehyde were the main oxidation products of MACR and MVK at the HS site. Overall, this study evaluated the roles of primary emissions on ambient levels of MACR and MVK and advanced the understanding of photochemical oxidation of MACR and MVK in the PRD.     

基于遥感影像的近30年西宁市热岛效应时空变化

利用1987?—?2015年多个时相的Landsat卫星影像及同期气象和社会经济数据,结合多年建成区边界,利用单窗算法反演了地表温度,结合热场变异指数定量分析了西宁市城市建成区热岛强度时空演化特征,探讨了其与城市绿化程度、车辆数等要素的关系,提出了城市化进程中城市热岛效应的调控措施。研究结果显示:(1)西宁市夏季表现为"热岛"效应,冬季为"冷岛"效应;(2)西宁市热岛效应强度在时间序列有三个节点,2000年以前西宁市夏季和冬季白天各个热岛区面积变化不明显,2000年以后热岛区面积,尤其是较强热岛区面积和中热岛区面积都出现迅速增加的趋势,2003年热岛区面积达到最高,2003年以后热岛区面积渐渐回落,2011年以后又增强;(3)夏季"热岛"区面积变化趋势和冬季"冷岛"区面积变化趋势一致,且与建成区变化一致。     

石墨炉原子吸收分光光度法测定土壤中总铬

建立了土壤中总铬测定的石墨炉原子吸收分光光度法;以塞曼效应扣除背景,优化了石墨炉灰化、原子化温度、停留时间及基体改进剂用量。结果表明:当原子化温度为2 700℃,灰化温度为700℃,原子化时间2 s,灰化时间为9 s;基体改进剂用量为3~5μL时,仪器可以达到最佳工作状态。该方法铬元素浓度在0~32μg/L内呈良好的线性关系,相关系数r=0.999 9,检出限为0.3 mg/kg;对土壤标样GSS-1和ESS-1的铬测定精密度均小于5%,相对误差在-4.8%~-0.7%之间,方法的灵敏度和准确度均符合要求。因此,石墨炉原子吸收分光光度法测定土壤中总铬具有原子化温度高、干扰少、灵敏度高等特点可适用土壤中总铬的测定。     

绿色包装材料的进展

较为详尽地论述和介绍了绿色包装及绿色材料的内涵，从可降解包装材料、包装纸、可食性包装材料、天然生物包装材料和陶瓷包装材料等几个方面来探讨绿色包装材料的发展趋势。绿色包装材料是绿色包装的重要组成部分，包装问题与环境密不可分，采用绿色包装材料是2l世纪包装工业的发展方向和必然抉择。     

应用遥感技术监测珠江口大气状况

采用航天遥感技术方法对广东珠江口区域大气污染物分布进行宏观的面状调查，分析了卫星遥感像元信息构成的物理机制。通过实验证明，像元信息可概化为土壤、植被、水体等基本信息类型的线性集合与污染气体信息的简单叠加，用多波段卫星遥感数据，经公式计算，从美国陆地卫星5号的数据直接定量提取区域大气污染气体累加浓度的信息表明，该污染信息将对珠江口大气污染状况有较客观、形象地再现。