陶瓷膜生物反应器处理生活污水膜污染机理的研究

采用一个经典模型描述了陶瓷膜生物反应器处理生活污水过程中的通量衰减,通过模型参数分析了膜的污染机理.分析结果表明,孔径为50、200和500 nm的陶瓷膜主要由"部分孔堵塞"机理、"完全孔堵塞"机理和"部分孔堵塞"机理控制.实验表明,孔径为200 nm的陶瓷膜较适用于陶瓷膜生物反应器体系.     

错流式生物滴滤床净化甲苯废气

采用焦化厂污泥为菌源驯化甲苯降解菌,接种错流式生物滴滤床,净化含甲苯废气。研究了生物滴滤床的挂膜启动和长期运行情况,填料和营养液对滴滤床去除能力的影响,并对长期运行的压降进行了观察分析。反应器挂膜启动需要6 d时间,稳定运行的平均去除效率为95％,单位体积最大去除负荷为251 g/(m³·h)。结果表明,采用错流式生物滴滤床可以有效去除甲苯废气;以比表面积大的生物陶粒作为填料以及定期适量更换营养液,均有助于提高生物滴滤床的去除能力;错流式生物滴滤床具有压降小、气液分布均匀的特点。     

土壤柴油污染修复的抽气提取去除实验研究

为得到土壤气相抽提(SVE)去除柴油的优化条件,进行了一维土柱抽气提取去除柴油污染物的实验研究,研究不同初始含水率、不同抽气量对污染土壤中柴油去除率的影响及不同深度残留柴油的变化规律。结果表明：在本实验模拟的范围内,抽气量越大,SVE处理效果越好;初始含水率越低,处理效果越好;此外,不同深度去除率变化的规律基本上是随深度的增大而减小。实验结果可为土壤轻油污染实际治理提供实验数据基础。     

碱渣对锌（Ⅱ）离子吸附特性的研究

研究了锌在碱渣表面的吸附特征.结果表明,碱渣总吸附量随体系温度的升高而降低;随体系 pH 值的升高而增加;随吸附质初始浓度的增加而增大.在 pH<5.51 时其等温吸附能较好地符合 Freudlich 等温吸附规律,而在 pH5.51 时,能较好地符合 Langmuir 等温吸附规律,吸附热随 pH 的增大而升高.当pH≤5.51时,碱渣的吸附力以范德华力平和疏水键力的作用为主,而当 pH6.17 时,以化学键力为主.在 pH 为 5.05、6.07和7.03时,碱渣对 Zn26 的吸附动力学方程都以 Langmuir 方程的拟合效果最优.     

基于模糊四元联系数的防洪工程体系安全综合评价模型

防洪工程体系是由随机、模糊、未确知等众多不确定性因子组成的复杂系统,它至今仍是洪水灾害管理的主体,对该体系综合安全进行定量评价可为洪水灾害管理提供重要依据.模糊四元联系数是集对分析中同异反联系数的推广,它可更深入地分析系统中的各种不确定性.利用模糊四元联系数建立了防洪工程体系安全综合评价模型,用联系度可描述评价对象与评价标准之间的关系,其结果简便直观,能清晰地反应评价对象和评价标准间的动态联系.用该模型综合评价了实际防洪工程体系的安全程度,其结果与物元分析等方法所得结果一致.     

西安城市暴雨内涝灾害气象预警系统研究

介绍了西安城市暴雨内涝灾害气象预警系统的技术路线及原理.该系统包含本地化的城市暴雨内涝仿真模型,并以城区加密气象自动站资料、多普勒雷达降水估算产品、数值预报产品、主观预报等作为实况和模拟用的降雨边界条件,结合西安市区地理地貌特征、城市规划、排水系统特征、排水规则、防洪工程等多方面的非气象资料建立而成,具备一定的内涝动态监测预报能力.对2006年6月3日内涝过程进行了模拟,效果较好,能够满足预警需求.     

阵性泥石流运动与堆积的欧拉─拉格朗日模型──Ⅰ.理论

自然界中的泥石流具有突发性和非恒定性的特点。为了模拟典型泥石流现象,在流团模型的 基础上,进一步完善了基于欧拉─拉格朗日（Ｅ—Ｌ）观点的ＰＩＣ（Ｐａｒｃｅｌ　Ｉｎ　Ｃｅｌｌ）算法,细化了流元结 构,建立了能够模拟典型阵性泥石流发生、运动和堆积的准结构两相流模型。求解该模型不仅可以 模拟泥石流运动过程,而且可以对泥石流的堆积过程、停积形态、冲刷特征及泥石流中多组分颗粒 的分选特征进行定量描述。     

Co-treatment of hydrogen sulfide and methanol in a single-stage biotrickling filter under acidic conditions

Biofiltration of waste gases is cost-effective and environment-friendly compared to the conventional techniques for treating large flow rates of gas streams with low concentrations of pollutants. Pulp and paper industry off-gases usually contain reduced sulfur compounds, such as hydrogen sulfide and a wide range of volatile organic compounds (VOCs), e.g., methanol. It is desirable to eliminate both of these groups of compounds. Since the co-treatment of inorganic sulfur compounds and VOCs in biotrickling filters is a relatively unexplored area, the simultaneous biotreatment of H2S and methanol as the model VOC was investigated. The results showed that, after adaptation, the elimination capacity of methanol could reach around 236 g m(-3) h(-1) with the simultaneous complete removal (100%) of 12 ppm H2S when the empty bed residence time is 24 s. The pH of the system was around 2. Methanol removal was hardly affected by the presence of hydrogen sulfide, despite the low pH. Conversely, the presence of the VOC in the waste gas reduced the efficiency of H2S biodegradation. The maximal methanol removal decreased somewhat when increasing the gas flow rate. This is the first report on the degradation of methanol at such low pH in a biotrickling filter and on the co-treatment of H2S and VOCs under such conditions.     

Spectroscopic Distribution of Dissolved Organic Matter in a Dam Reservoir Impacted by Turbid Storm Runoff

Spectroscopic characteristics of dissolved organic matter (DOM) in a large dam reservoir were determined using ultraviolet absorbance and fluorescence spectroscopy to investigate spatial distribution of DOM composition after turbid storm runoff. Water samples were collected along a longitudinal axis of the reservoir at three to four depths after a severe storm runoff. Vertical profiles of turbidity data showed that a turbid water layer was located at a middle depth of the entire reservoir. The spectroscopic characteristics of DOM samples in the turbid water layer were similar to those of terrestrial DOM, as demonstrated by the higher specific UV absorbance (SUVA) and the lower fluorescence emission intensity ratio (F ₄₅₀/F ₅₀₀) compared to other surrounding DOM samples in the reservoir. Synchronous fluorescence spectroscopy revealed that higher content of humic-like DOM composition was contained in the turbid water. Fluorescence excitation–emission matrix (EEM) showed that lower content of protein-like aromatic amino acids was present in the turbid water DOM. The highest protein-like fluorescence was typically observed at a bottom layer of each sampling location. The bottom water DOM exhibited extremely high protein-like florescence near the dam site. The particular observation was attributed to the low water temperature and the isolation of the local bottom water due to the upper location of the withdrawal outlet near the dam. Our results suggest that the distribution of DOM composition in a dam reservoir is strongly influenced by the outflow operation, such as selective withdrawal, as well as terrestrial-origin DOM inputs from storm runoff.     

芳香酸稀溶液的络合萃取研究

络合萃取法分离极性有机物稀溶液具有高效性和高选择性。本文利用三辛胺或磷酸三丁酯为络合剂,四氯化碳、三氯甲烷、正辛醇或煤油为稀释剂,实验测定了苯甲酸、邻硝基苯甲酸稀溶液的萃取相平衡分配系数,讨论了影响因素。