Combined effect of tributyltin and benzo[a] pyrene on the levels of sex hormone and vitellogenin in female Sebastiscus marmoratus

Tributyltin（TBT）, an organometal used as an antifouling biocide, has been reported to induce masculinization of fish. Benzo [a]pyrene （BaP）, a widespread carcinogenic polycyclic aromatic hydrocarbon, has been reported that its microsomal metabolites can produce an estrogenic response when tested in vitro. This study was therefore designed to examine the potential in vivo influence of TBT, BaP and their mixture on sex hormone levels in serum of Sebastiscus marmoratus, which were given 2 separate intraperitoneally （ip） injections（a single injection every 7 d） of TBT（0.5, 1, 5 and 10 mg/kg）, BaP（0.5, 1, 5 and 10 mg/kg）, or both in combination（0.5, 1, 5 and 10 mg/kg）; control fish received olive oil vehicle only. Six days after the 2nd injection, serum samples were collected and analyzed for sex hormone levels and alkali labile protein phosphorus （ALPP）, which is related to the yolk precursor protein vitellogenin. The pollutants at all doses significantly reduced serum testosterone, estradiol and ALPP content after 2 injections compared with the corresponding controls. The reduction of the estradiol levels should be response for the decrease of the vitellogenin levels. The results in the present study suggested that aromatase seems not the major target acted by TBT and BaP in fish. This study demonstrated that TBT or BaP exposure both inhibit the reproductive potential in female Sebastiscus marmoratus. Combined effect of TBT and BaP on the serum testosterone, estradiol and ALPP was not antagonism from the anticipation.     

固化法处理废干电池

介绍了电池的历史及其生产的现状、排废特征 ;简述了废旧干电池对环境的危害及其回收处理工艺和经济环境效益 ;结合金霸王 (中国 )有限公司废干电池的特点和电池废料的处理现状 ,对其采用固化法处理 ,然后进行渗漏试验并作出结果分析和评述 ;最后对废干电池的回收处理提出建议。     

水稻烤田期间N2O排放及其影响因素

水稻田间实验研究了烤田期间的土壤温度、Eh、含水量和裂缝基本性质,矿质态氮以及与氮有关的酶活性的演变规律,及其对N2O排放的影响.试验表明,在水稻分蘖期间烤田,N2O有一个排放高峰,其最高值可达75.6μg·m-2·h-1.在排放高峰后,即使继续烤田,N2O的排放值也将降低.N2O排放与尿素氮肥的施用量没有明显关系.裂缝的生成,改变了N2O的日排放规律.随着烤田时间的延长,脲酶和羟胺还原酶活性呈波动变化,硝酸还原酶活性递减,亚硝酸还原酶活性极低.硝酸还原酶活性与N2O排放之间没有显著相关性.土壤中的脲酶活性与N2O日排放通量呈显著的线性正相关.在烤田期间,NO-3含量呈增加趋势.土壤中的硝态氮含量与N2O排放通量之间呈显著正线性关系.土壤中的铵态氮含量与N2O排放通量之间呈显著负线性相关.     

硫代氨基甲酸盐提取工业废水中的锌离子

本文主要探索了金属离子络合剂———硫代氨基甲酸盐的合成制备 ,并通过其对锌离子的络合作用 ,以达到脱除金属离子的目的 .实验表明 ,由吗啡啉合成制得的硫代氨基甲酸盐 锌离子络合剂在酸性废水中 ,对锌离子具有良好的络合能力 .通过对废水中金属锌离子的脱除工艺条件的相应探索 ,发现在体系的pH =2～ 6范围内 ,硫代氨基甲酸盐对锌离子的脱除率均达99 %以上     

煤矿环境污染评价及“三废”资源化探讨

煤矿对生态环境的污染与破坏日益严重，已成为当前我国环境保护面临的重要问题之一。文中阐述了煤矿对生态环境的污染问题，探讨了煤矿环境污染评价指标。分析了煤矿“三废”（即矿井水、瓦斯、煤矸石）的资源化问题，指出煤矿企业需加大在环境保护方面的投入，通过提高对“三废”的综合利用，逐步迭到循环经济的生产模式，在解决煤矿环境污染问题的同时取得良好的经济效益和社会效益。     

生活垃圾填埋污染控制标准比较研究

详细介绍了美国《城市生活垃圾填埋场标准》，德国《生活垃圾技术条例》．日本《废弃物最终处置场指南》和欧盟《废弃物填埋导则》等有关生活垃圾填埋污染控制的标准的主要内容以厦其主要特点．井与中国现行的《生活垃圾填埋污染控制标准》（GB16889—1997）相比较，主要从选址、入场垃圾要求、渗滤液排放标准、防渗结构和终场覆盖系统等5方面分析了GB16889中存在的一些问题，并对今后其修订、完善工作提出了具体的建议。     

食品垃圾的综合利用研究

食品垃圾在生活垃圾中所占的比例较大，它的处理是解决城市生活垃问题的重要环节，分析了国内外食品垃圾处理的现状及目前垃圾处理存在的问题，提出了食品垃圾综合利用的途径。     

索风营水电站Dr2号危岩体破坏模式分析

在专门性工程地质勘察的基础上,系统分析了Dr2危岩体的边界条件、形成机理及破坏模式,并简要介绍了目前所采取的处理措施。     

On-line optical determination of floc size of Fe(Ⅲ) coagulants

This study investigated the floc aggregation, average floc size, floc size variance and floc growth velocity when ferric chloride （FeCl3） and polyferric chloride （PFC） were used to treat the simulated water samples. The factors including coagulant dose, ionic strength and solution pH, which affect the floc aggregation, were studied. Experiments were carried out in a bench-scale reactor using photometric dispersion analyzer （ PDA）. Results showed that there were great differences between the floc aggregation of PFC and FeCl3. The average floc size and fioc growth velocity of PFC were much larger than those of FeCl3. Compared with FeCl3, PFC gave a better coagulation performance in wider range of pH, dosage and ionic strength. It was also found that the coagulation efficiency of PFC did not depend on average floc size but on floc growth velocity.     

Sorption of pyrene on two paddy soils and their particle-size fractions

In the present study, the sorption of pyrene on two kinds of bulk paddy soils, Gleyic Stagnic Anthrosols, and Ferric accumulic Stagnic Anthrosols as well as their particle-size fractions was investigated. The sorption isotherms fitted well with Freundlich equation. For both soils, the clay fraction（ 〈 2μm） and coarse sand fraction（2000-250μm） had higher sorption capacity than fine sand fraction（250-20 μm） and silt fraction（20-2 μm）. The IogKoc values obtained of each soil and its particle-size fractions were similar, proving that SOM content was a key factor affecting pyrene sorption. The Kd values showed a significant correlation with contents of dithionite-extractable Fe in both paddy soils and a good relationship with CEC in Gleyic Stagnic Anthrosols, indicating possible effects of surface properties of particle-size fractions on the sorption of pyrene.