黔中石漠化地区不同土地利用方式对土壤环境的影响

在贵州省普定县喀斯特石漠化地区通过调查分析,对3种土地不同利用方式（Ⅰ封山育林地、Ⅱ退耕还林地、Ⅲ农耕地）土壤物理性质、化学性质及土壤种子库进行了研究。结果表明利用方式的不同对土壤物理性质、化学性质及土壤种子库均产生了显著的影响。土壤容重、土壤毛管孔隙度随土壤扰动的加剧而下降,表现为Ⅰ＞Ⅱ＞Ⅲ;土壤总孔隙度与非毛管孔隙度呈现出随土壤扰动程度增加而增加的趋势,表现为Ⅲ＞Ⅱ＞Ⅰ;不同层次之间容重的变异较小,土壤质地比较均一;Ⅱ土壤有机质低于类型Ⅲ和Ⅰ;Ⅰ初步形成了林地环境,林地土壤表现出良性转变。随土壤深度的增加,有机质、全氮、全磷、速效氮表现出减少的趋势,土壤扰动降低了土壤化学性质层次间变异。不同利用方式下土壤种子库物种组成变化不大,土壤中的种子集中分布在表层0～5 cm内,随土层的加深所含种子数量、物种数逐渐降低。不同利用类型的土壤种子数量在0～5 cm层次差异显著（〖WTBX〗p〖WTBZ〗=0.021 897）,种子种类差异不显著（〖WTBX〗p〖WTBZ〗=0.097 628）。土壤扰动促进种子向深层传播,退耕还林有利于土壤质量的恢复。     

上海城市街道灰尘重金属铅污染现状及评价

对上海市区和郊区城镇中心街道灰尘中铅的含量水平进行了研究,并应用克里格插值法分析了市区街道灰尘中铅的空间分布特征,结果表明:市区街道灰尘中铅的含量为28～4443 mg·kg^-1,平均含量为264 mg·kg^-1,为上海土壤环境背景值的10.4倍;郊区城镇中心街道灰尘中铅的含量为155～364 mg·kg^-1,平均含量为237 mg·kg^-1,为环境背景值的9.3倍;市区内环线以内黄浦江两岸区域铅污染较为严重,平均含量为359 mg·kg^-1;铅污染中心主要位于商业区和交通干道,平均含量分别为642和520 mg·kg^-1.地积累指数法和铅污染指数法的评价结果表明:上海城市街道灰尘中铅污染整体上处于中度污染水平,其中,市区内环线以内黄浦江两岸区域街道灰尘中铅污染处于偏重污染水平.研究结果以期为上海市的城市环境污染防治和城市规划提供重要的科学依据.     

自然权利的批判与辩护

环境伦理的突出功能表现在对人与自然关系的调整上。从法学视角切入．以“权利”作为分析文本．论述了人类中心主义与非人类中心主义在“自然权利”上的理论分歧．人类中心主义者从权利的一人性、权利义务的不对等性、主张自然权利的非现实性以及自然权利的不可操作性四个方面对自然的权利提出了批判．而非人类中心主义者指出权利撅念的在不断地扩展．人类中心主义不可能完全解决好人与自然的关系,自然权利存在着转化为在法律上具有可操作性的可能．并且自然权利理论已在法律实践领域拓展．对自然的权利进行了辩护。由此提出了“非人类中心主义”、“自然的权利”的环境伦理定位。     

基于云模型的油气管道坡面水毁安全评价

针对在管道坡面水毁评价过程中定性概念的随机性和模糊性共存的特性,提出了一种基于云模型的综合评价方法,用于油气管道坡面水毁安全评价.首先,建立管道坡面水毁因素集、因素评价云模型、分值集和分值评价云模型;其次将管道坡面水毁各因素基础数据输入云不确定性推理发生器,得出分值云滴;再次将分值云滴输入逆向云发生器进行推算,得到带有“危险等级”属性的分值云模型;最后综合各因素分值云模型得到管道坡面水毁综合分值云模型.该方法评价结果直观、灵活,符合实际情况.     

房间开门形式和走廊转角条件对人员疏散规律影响的实验研究与数值模拟分析

为了研究房间开门形式和走廊转角条件对人员疏散规律的影响,通过一系列实验并采用计算机数值模拟相结合,对比分析了不同开门形式和走廊转角条件下的人员疏散规律。结果表明:房间开门总宽度一定且出口出现拥堵条件下,只设置一道门,疏散效率最高。当房间需要满足设置两道门时,门应尽量设置在房间的两对边墙上,这样疏散效率较高。两道门设置在房间相邻边墙上时最不利于人员疏散。走廊转角角度从0°增加到90°,疏散时间先增长然后缩短最后又增长。同条件下,圆角疏散能力优于折角。圆角半径大小对人员疏散没有显著影响。研究结果为建筑房间开门形式和走廊设计提供了参考依据。     

紫外吸收剂在湖泊中的分布及其对底栖动物的毒性效应

紫外吸收剂大量用于工业材料和个人护理品中,近年来在水体中不断被检出,同时由于其高度亲脂性,易在底泥和水生生物体内富集,产生潜在的毒性效应,已成为一类新型污染物。本文综述了紫外吸收剂在湖泊环境中的分布和生物富集效应,重点分析了二苯甲酮类等典型紫外吸收剂对底栖动物的药物代谢系统、抗氧化系统及其生长发育的影响及其毒性作用机制,并对未来该领域的研究进行了展望。     

Quantitative health risk assessment of inhalation exposure to automobile foundry dust

With a growing awareness of environmental protection, the dust pollution caused by automobile foundry work has become a serious and urgent problem. This study aimed to explore contamination levels and health effects of automobile foundry dust. A total of 276 dust samples from six types of work in an automobile foundry factory were collected and analysed using the filter membrane method. Probabilistic risk assessment model was developed for evaluating the health risk of foundry dust on workers. The health risk and its influencing factors among workers were then assessed by applying the Monte Carlo method to identify the most significant parameters. Health damage assessment was conducted to translate health risk into disability-adjusted life year (DALY). The results revealed that the mean concentration of dust on six types of work ranged from 1.67 to 5.40 mg/m³. The highest health risks to be come from melting, cast shakeout and finishing, followed by pouring, sand preparation, moulding and core-making. The probability of the risk exceeding 10⁻⁶ was approximately 85%, 90%, 90%, 75%, 70% and 45%, respectively. The sensitivity analysis indicated that average time, exposure duration, inhalation rate and dust concentration (C) made great contribution to dust health risk. Workers exposed to cast shakeout and finishing had the largest DALY of 48.64a. These results can further help managers to fully understand the dust risks on various types of work in the automobile foundry factories and provide scientific basis for the management and decision-making related to health damage assessment.

     

Recovery of Ni(II) from real electroplating wastewater using fixed-bed resin adsorption and subsequent electrodeposition

Resin adsorption and subsequent electrodeposition were used for nickel recovery. Treated wastewater can meet the Electroplating Pollutant Discharge Standard. The spent resin is completely regenerated by 3 BV of 4% HCl solution. 95.6% of nickel in concentrated eluent was recovered by electrodeposition. Effective recovery of high-value heavy metals from electroplating wastewater is of great significance, but recovering nickel ions from real electroplating wastewater as nickel sheet has not been reported. In this study, the pilot-scale fixed-bed resin adsorption was conducted to recover Ni(II) ions from real nickel plating wastewater, and then the concentrated Ni(II) ions in the regenerated solution were reduced to nickel sheet via electrodeposition. A commercial cation-exchange resin was selected and the optimal resin adsorption and regeneration conditions were investigated. The resin exhibited an adsorption capacity of 63 mg/g for Ni(II) ions, and the average amount of treated water was 84.6 bed volumes (BV) in the pilot-scale experiments. After the adsorption by two ion-exchange resin columns in series and one chelating resin column, the concentrations of Ni(II) in the treated wastewater were below 0.1 mg/L. After the regeneration of the spent resin using 3 BV of 4% (w/w) HCl solution, 1.5 BV of concentrated neutral nickel solution (>30 g/L) was obtained and used in the subsequent electrodeposition process. Using the aeration method, alkali and water required in resin activation process were greatly reduced to 2 BV and 3 BV, respectively. Under the optimal electrodeposition conditions, 95.6% of Ni(II) in desorption eluent could be recovered as the elemental nickel on the cathode. The total treatment cost for the resin adsorption and regeneration as well as the electrodeposition was calculated.     

磺胺氯哒嗪在海水中的间接光降解

以有色溶解有机物(CDOM)作为主要光敏剂研究磺胺氯哒嗪(SCP)间接光降解行为和机理,分析CDOM组成、盐度和pH值对SCP间接光降解的影响.SCP间接光降解速率随CDOM浓度升高而逐渐加快.CDOM产生的光化学反应活性中间体对SCP间接光降解的贡献率不同,其中³CDOM^*起主要作用,对SCP间接光降解的贡献率高达77.94%.所用CDOM由4种荧光组分组成,包含3种外源腐殖质(C1,C2,C3)和1种内源腐殖质(C4), SCP间接光降解去除率和³CDOM^*浓度分别与荧光组分的相关性大小顺序均为C3>C2>C4>C1.其中C3和C2与[³CDOM^*]具有较高线性相关性(R²>0.97),是³CDOM^*的主要贡献者.盐度和pH值对SCP间接光降解的影响作用显著.在盐度为15‰时,SCP的间接光降解速率最大.在低盐度范围(0~15‰)内,离子强度效应对间接光降解的促进作用大于无机阴离子带来的抑制作用,使得间接光降解速率随着盐度的升高而加快.溶液pH=(5.00±0.10)时,SCP的间接光降解速率最大.SCP的间接光降解速率随着溶液pH值的升高而减慢,中性和碱性环境不利于SCP的间接光降解.     

深水水下测试树球阀剪切连续油管性能分析

为研究不同工况、不同结构参数对于深水水下测试树球阀剪切连续油管性能的影响,采用有限元分析软件建立剪切分析模型,对不同工况下剪切过程进行数值模拟,并与试验对比验证分析模型的准确性;结果显示,有限元模型结果与试验结果相对偏差小于5%;油管剪切过程中会出现2个剪切力矩峰值,通过分析不同工况下2个峰值变化规律,发现油管承受拉力越大、球阀剪切速度越小、球阀外径越小剪切过程所需剪切力越小,剪切性能越好。研究结果表明:得到的剪切模型及不同工况下剪切力变化规律,可为水下测试树的设计选型及现场应用提供指导及参考意义。