循环式超声强化光催化降解双酚A

设计了一种循环式超声强化光催化反应器,以TiO2作为光催化剂,研究了超声功率、TiO2加入量、循环液流速和空气流量对双酚A(BPA)降解效果的影响。实验结果表明:超声与光催化过程在循环式超声强化光催化反应器中实现了较好的协同效应;在初始BPA质量浓度为20.0mg/L、超声功率为600W、TiO2加入量为7g/L、循环液流速为4.05×10-2m/s、空气流量为200mL/min的条件下,反应150min后,BPA降解率可达90.5%,溶液中剩余BPA质量浓度仅为1.8mg/L,反应240min后TOC去除率可达84.5%。     

Occurrence, distribution, and sources of six phenolic endocrine disrupting chemicals in the 22 river estuaries around Dianchi Lake in China

The objectives of this study are to track the occurrence, distribution, and sources of phenolic endocrine disrupting compounds (EDCs) in the 22 rivers around Dianchi Lake in China, to estimate the input and output amounts of phenolic EDCs in the water system, and to provide more comprehensive fundamental data for risk assessment and contamination control of phenolic EDCs in aquatic environment. Six phenolic EDCs were systematically evaluated in water and surface sediment in the estuaries of those rivers. The water and sediment samples were preconcentrated by solid-phase extraction system and microwave-assisted extraction system, respectively. Phenolic EDCs were analyzed by GC-MS (Thermo Fisher Scientific, USA) after derivatization. Phenolic EDCs were found ubiquitously in the aquatic environment. The total concentrations ranged from 248 to 4,650 ng/L in water, and 113 to 3,576 ng/g dry weight in surface sediment. The residue amount of phenolic EDCs in Dianchi Lake was 258 kg/a. Concentrations of the phenolic EDCs in the Lake decreased with increase in distance to the estuaries of those rivers which run through urban and industrial areas. The rivers seriously contaminated by phenolic EDCs were Xin River, Yunliang River, Chuanfang River, Cailian River, Jinjia River, Zhengda River, and Daqing River which run through the old area of Kunming City. Satisfying correlations were observed between the concentrations of the target compounds in water and in surface sediment. NP1EO, NP2EO, and BPA were identified as the three predominant phenolic EDCs. There were significant correlations between phenolic EDCs and many basic water quality parameters. Urban and industrial areas are the major contributors for phenolic EDCs, especially in Kunming City. Compositional profiles of phenolic EDCs in surface sediment were similar to those in river water. The concentrations of phenolic EDCs in the rivers located in the northwest part of the valley were very high, and posed a potential risk to aquatic organisms and even human. The concentrations of NP2EO, NP1EO, and BPA were at moderate levels of other areas. The basic water quality parameters (TOC, TN, DO, and pH) play important roles on the distribution, fate, and behavior of phenolic EDCs in the valley.     

高效降解环己酮红球菌JDM-3-12的分离及其系统发育分析

从岳阳巴陵石化公司环己酮生产车间总出水口的污泥中筛选到一株环己酮降解菌株,菌号为JDM-3-12;该菌能以环己酮为唯一碳源且能忍受5000 mg/L的环己酮,当环己酮的质量浓度为2000 mg/L时,在温度为30℃,转速为150 r/m in,pH=7的条件下,72小时内该菌株对环己酮的降解率达到97.91%。通过形态观察、生理生化特征检测和基于16S rRNA基因序列的系统发育分析,初步鉴定其为赤红球菌(Rhodococcus ruber)中的一个菌株,该菌最适生长温度为35℃,最适生长pH 7。     

B／S模式下基于角色的权限管理系统设计与实现

结合基于角色的访问控制的原理,实现了一个基于Struts框架B/S模式的权限管理系统.该系统围绕用户、角色、功能、单位等基本定义以及它们之间的关系进行模块编码,实现了灵活、实用的基于角色的权限管理功能,达到了页面级别的权限控制.利用Struts配置文件,隐藏了系统的文件结构,提高了系统安全性.同时利用过滤器技术,通过重载Filter接口,可有效拦截直接在IE的地址栏中输入内部页面地址的访问.实际应用表明,该系统具有很好的可扩展性和通用性.     

塑烧管除尘器在冶金精轧线的应用

冶金精轧线烟气烟尘含油含水，采用传统的布袋除尘等方式难以治理。塑烧管具有刚性结构、高过滤效率、压降稳定、疏水疏油性、防静电等特性，适合于治理含油含水的烟气。塑烧管除尘器在冶金精轧线的应用取得了良好的效果。     

近场地震作用下框架结构的损伤机理

首先讨论了近场地面运动的特征及各种抗震规范对近场地震的设防，然后采用非线性时程分析方法，对一个10层框架结构在近场地震作用下的响应特性进行了研究。同时对该框架结构进行了Pushover分析，通过与非线性时程分析结果进行对比，说明Pushover分析方法不能正确评估结构在近场地震作用下的抗震性能。     

某厂化学装置爆炸对设备房结构的损坏——调查与模拟分析

在对某厂化学爆炸所作的现场调查的基础上，对设备房钢筋混凝土框架结构构件的受损状况进行了分类描述，采用有限元方法对框架结构在静力和爆炸冲击荷载下的反应进行了模拟分析，分析结果与现场调查情况基本一致，给出了一些有意义的结论。     

浅析国内外重大危险源辨识中危险物质临界量的差异

通过分析国内外重大危险源辨识标准中危险物质临界量的差异,以汽油和液化石油气为例,分别选择池火灾和沸腾液体扩展蒸气云爆炸模型计算事故后果,并结合我国企业的安全管理状况,说明了修改我国《重大危险源辨识》中危险物质临界量的必要性。     

基于XML的国家重大危险源中间数据库研究与实现

为建立国家重大危险源监管信息系统,针对目前地方数据库系统异构问题,提出了基于XML中间数据库的解决方案.首先对XML与关系数据库的关系进行了分析,并对XML文档结构与数据库结构的映射以及XML与关系数据库之间的转换进行了探讨;接着定义了国家标准中九大类重大危险源信息的XML模版;最后采用JDOM技术,实现了从省市重大危险源数据库集中到国家中间数据库,为进一步建立国家中心数据库奠定了基础.     

石英砂加工企业职业病危害防护措施与管理对策研究

通过对安徽省石英砂加工企业生产工艺流程和现场进行调查分析,得出矽尘和噪声是两种最主要的职业病危害因素,发现石英砂生产企业矽尘和噪声危害十分严重,生产作业现场未配备任何防护装备和个人防护用品,作业人员接触职业病危害的比率非常高。分析了石英砂加工企业在职业病危害防护与管理方面的欠缺与不足,提出了针对矽尘和噪声危害因素的具体工程防护措施与管理对策,从源头控制和消除职业病危害,保护劳动者的生命安全与健康。