秸秆还田方式对东北农田土壤NH3挥发和N2O排放的影响

秸秆还田是有效利用资源、增加土壤有机质含量和培肥地力的有效措施,但也会影响土壤NH₃挥发和N₂O的排放.探索不同秸秆还田方式对NH₃挥发和N₂O排放的影响对于减少土壤氮素损失和保护生态环境具有重要意义.采用田间小区试验,利用Los Gatos Research（LGR）超便携NH₃分析仪和密闭式静态箱-气相色谱法探究不同秸秆还田方式下土壤NH₃挥发和N₂O排放的特征,试验设4个处理（覆盖还田,即表面覆盖玉米秸秆,0~20和20~40 cm土壤分层扰动后填回,记为JG0-0;常规还田,即秸秆与0~20 cm土壤混合,20~40 cm土壤扰动后填回,记为JG0-20;深还田,秸秆与20~40 cm土壤混合,0~20 cm土壤挖出后填回,记为JG20-40;对照处理,即无玉米秸秆还田,0~20和20~40 cm土壤分层扰动后填回,记为CK）.结果表明:①相比于CK,不同秸秆还田方式均显著降低了土壤NH₃挥发量,增加了土壤N₂O排放量.与CK相比,JG0-0、JG0-20和JG20-40处理下土壤NH₃累积排放量分别减少了12.38%、9.87%和5.73%;土壤N₂O累积排放量分别增加了30.19%、82.82%和36.53%,其中JG0-0和JG20-40处理之间无显著性差异.②JG20-40处理下玉米产量显著高于其他处理,比CK增加了23.15%,JG0-0处理下玉米产量高于CK和JG0-20处理,但并未达到显著水平.③对于NH₃和N₂O这两种气体的总累积排放量,各处理间均达到显著性差异.与CK相比,JG0-0、JG0-20和JG20-40处理下NH₃和N₂O总累积排放量分别增加了16.67%、52.08%和22.92%.④不同秸秆还田方式下的氮素气态损失率均高于CK,JG0-0、JG0-20和JG20-40处理下氮素气态损失率分别比CK增加了17.50%、52.50%和22.50%.因此,综合考虑土壤NH₃挥发量、N₂O排放量和玉米产量等因素,JG0-0处理优于JG20-40、JG0-20处理.      

沈阳市农村生活污水处理设施有机废弃物归趋

采用实地观察法、文献调查法对沈阳市农村生活污水处理设施基本状况进行研究分析。结果显示:沈阳市已建成农村生活污水处理设施297处,有机废弃物产生量(干重)约为:剩余污泥637 t/a、湿地植物废弃物169 t/a。     

油气田在役管道高后果区识别与完整性评价方法

根据油气管道建设与管理的相关标准与规范或导则,针对目前油气田在役管道,明确了其高后果区识别的划分及其在不同标准中的差异以及识别的原则和时间间隔,分别介绍了在管道的相关数据采集的基础上开展地质灾害和第三方破坏造成的管道风险评价方法,管道内外腐蚀的直接评价以及包括剩余强度、剩余寿命和材料在内的管道适用性评价方法,同时给出了这些评价工作所涉及到的相关内容项,对油田管道的完整性管理具有重要的指导作用和应用价值。     

Nanoencapsulation of hexavalent chromium with nanoscale zero-valent iron: High resolution chemical mapping of the passivation layer

Solid phase reactions of Cr(Ⅵ) with Fe(0) were investigated with spherical-aberration-corrected scanning transmission electron microscopy(Cs-STEM) integrated with X-ray energy-dispersive spectroscopy(XEDS). Near-atomic resolution elemental mappings of Cr(Ⅵ)–Fe(0) reactions were acquired. Experimental results show that rate and extent of Cr(Ⅵ) encapsulation are strongly dependent on the initial concentration of Cr(Ⅵ) in solution. Low Cr loading in nZⅥ(1.0 wt%) promotes the electrochemical oxidation and continuous corrosion of n ZⅥ while high Cr loading(1.0 wt%) can quickly shut down the Cr uptake. With the progress of iron oxidation and dissolution, elements of Cr and O counter-diffuse into the nanoparticles and accumulate in the core region at low levels of Cr(Ⅵ)(e.g., 10 mg/L). Whereas the reacted n ZⅥ is quickly coated with a newly-formed layer of 2–4 nm in the presence of concentrated Cr(Ⅵ)(e.g., 100 mg/L). The passivation structure is stable over a wide range of pH unless pH is low enough to dissolve the passivation layer. X-ray photoelectron spectroscopy(XPS) depth profiling reconfirms that the composition of the newly-formed surface layer consists of Fe(Ⅲ)–Cr(Ⅲ)(oxy)hydroxides with Cr(Ⅵ) adsorbed on the outside surface. The insoluble and insulating Fe(Ⅲ)–Cr(Ⅲ)(oxy)hydroxide layer can completely cover the n ZⅥ surface above the critical Cr loading and shield the electron transfer. Thus, the fast passivation of nZⅥ in high Cr(Ⅵ) solution is detrimental to the performance of nZⅥ for Cr(Ⅵ) treatment and remediation.     

盐酸付玫瑰苯胺若干性质讨论

盐酸付玫瑰苯胺是三苯甲烷类染料，分子中存在的共轭体系使其具有以下特性：１．本身带色；２．随介质的ｐＨ变化产生显著的颜色效应，ｐＨ值越高，颜色越深，ｐＨ值越低，颜色越浅；３．对光和水洗的坚牢度较差；４．可发生重氮化反应；５．杂质使其颜色加深。     

Utility of dynamics as indicators of stress in population models

The relationships between the dynamics of environmentally and chemically stressed populations and indicators of the effects of the stressor are explored in a model framework. The physiologically structured population, represented by a system of McKendrick–von Foerster hyperbolic partial differential equations, includes the dynamics of numerous individuals distinguished by ecotype. Chemical uptake of nonpolar narcotics is modeled by first order kinetics. Classical methodologies, frequency analysis and phase space reconstruction, are explored in a search for indicators of magnitude of stress. When these techniques proved generally unsuccessful for the objective of indicator selection in our model setting, summary statistics, as related to bifurcation diagrams, were constructed and appear more useful as indicators. It is concluded that physiological structures generally lead to more feasible measurable indicators of magnitude of stress than do specifics of population dynamics.     

贵阳地区基本地质环境和主要岩土工程问题综述

本文系笔者对贵阳地区主要地质环境和工程地质特点进行的初步总结,内容为贵阳地区主要岩土构成情况、分布范围及与之相应的岩土工程地质特点和主要的岩土工程地质问题的描述,旨在给同行提供宏观性的了解和方向性的参考。     

曲面零件在拉深过程中内皱时刻及影响因素

进一步推导了曲面零件悬空区上的应力分布及临界失稳公式。然后通过计算机编程 ,求解了临界失稳方程 ,得到了拉深系数、相对锥顶半径、相对圆角半径、材料相对厚度与临界失稳时刻间的关系曲线 ,并对曲线变化的规律进行了分析。     

城市化对湖泊和港湾环境的影响

全球经济的发展必然经历工业化和城市化。在城市化过程中 ,不可避免地产生工业和生活垃圾。这些垃圾不仅污染土地 ,也污染河流和湖泊 ,特别在湖泊和港湾中 ,由于水流速度变缓 ,污染物容易随着沉积物沉淀下来。又由于气候变化和人类活动 ,湖泊和港湾的沉积物会再次释放污染物而污染水体。这些污染物主要是过量的氮、磷、有毒有机物和重金属 ,由于经济和人文环境的不同 ,在不同地区污染程度有差异 ,目前在发展中国家较为严重。针对这些污染 ,人们用机械的、化学的和生物的方法来治理湖泊和港湾的污染 ,但根本上要从源头控制污染———减少污染物的排放