Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant

A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l⁻¹ from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu₃(HTDC)₂]_n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment.     

城市垃圾处理与管理对策研究

对北京、天津、上海、重庆、广州等１７个城市垃圾的调查,结果表明,近１０年,上述城市垃圾总量的增长城市化关系密切,城市垃圾的组分受经济发展,生活水平、消费行为方式的影响,地域差异显著;城市垃圾处理技术欠完善,管理体制不合理,急需通过市场化动作国吧改善。     

环境管理、规划管理与项目管理

文章从深入分析环境管理的内涵出发,进而提出树立项目管理意识,强化项目管理的概念,说明项目管理在环境管理中的地位和作用,从这个意义上讨论环境管理与项目管理的关系,简述环境保护项目管理的主要环节,达到提高环境管理效能的途径的目的。     

The Outcome of Northern Fur Seal Harvesting: The Results of Calibration of Mathematical Models Based on Observation Data (the Example of Tyulenii Island Population)

Tendencies in the dynamics of harvested northern fur seal (Callorhinus ursinus) population on the Tyulenii Island have been analyzed in detail. The results show that retardation of reproduction (decrease in the numbers of pups) and decline in the survival of young females (up to 3 years of age) by the late 1980s resulted in a reduction of the total number of females and a significant increase in the proportion of older females. This tendency changed during the later observation period (after 1988–1989) due to increase in the survival of young females: the female population has gradually recovered, with the proportion of young females increasing at the expense of old females (aged over 10 years). The age composition of males has also changed: the proportion of young animals has decreased, while that of large mature males (bulls) has increased. Moreover, the number of bulls continues to increase and has already exceeded the level that formerly provided for the well-being of the population. This, a paradoxical situation has arisen: the numbers of females and bulls are increasing, whereas pup production remains at a low level.

     

微波强化CWPO工艺CuO_x-CeO_2/GAC催化剂的制备及其对二甲亚砜的降解

以颗粒活性炭(GAC)为载体、铜为活性组分、铈为助剂组分、草酸钠为沉淀剂,采用浸渍焙烧法制得CuO_x-CeO_2/GAC催化剂。以H_2O_2为氧化剂,微波强化催化湿式过氧化氢氧化(CWPO)处理二甲亚砜(DMSO)初始质量浓度为1 000 mg/L的废水,处理3 min后DMSO去除率达93.8%。催化剂第7次使用时DMSO去除率仍保持在75%以上。初始废水pH在3~9范围内,DMSO去除率均在85%以上。助剂Ce的加入提高了催化剂表面活性组分的分散性和稳定性,使催化剂的活性稳定性和使用寿命显著提高。     

Changes in the structure and phytomass of tree stands at the upper limit of their growth in the Southern Urals

Relationships between stem diameter and phytomass of trees and their parts (single- and multistemmed growth forms) have been studied at different altitudinal levels of the present-day upper treeline ecotone on the Iremel’ Massif, the Southern Urals. The time course of changes in the structure and phytomass of birch–spruce stands during the past centuries has been reconstructed. It is shown that the expansion of forests to the mountains in this period has occurred against the background of rise in summer and winter temperatures and increase in the amount of solid precipitation in the Southern Urals.     

城市周边高标准基本农田建设时序研究——以重庆市南岸区为例

高标准基本农田建设是夯实农业基础,保障国家粮食安全的重要抓手。以重庆市南岸区为研究对象,从基础地力、利用条件、区位条件3方面筛选出12个指标,构建高标准基本农田建设综合评价体系,引入熵权法、障碍度模型等测算各评价单元的建设潜力和建设难度系数,最后以行政村为评价单元耦合两者评价结果,提出了南岸区高标准基本农田建设时序。结果表明:南岸区已基本具备高标准基本农田条件的耕地面积约76.6 hm~2,占永久基本农田总量的11%,其余624.19 hm~2耕地可通过土地整治逐步建成高标准基本农田。在空间上,建设潜力较高的区域主要集中在东北部广阳镇,建设难度等级呈现出"南高北低"的分布规律,按照先易后难的建设原则,建设时序也需遵循从北向南的规律依次开展整治工程。研究结果可为南岸区高标准基本农田规划实施提供参考。