堤防工程综合安全模型和风险评价体系研究及应用

为获得荆南长江干堤的安全特性,在层次分析法及模糊一致理论的基础上,考虑堤防工程水、土两相系材料的特点,建立了模糊综合评判系统结构模型。通过正态型模糊隶属函数,结合两种权值理论实现了对堤防工程的安全综合评判。在模糊综合评判结论的基础上,结合模式识别的间接方法,提出了广义多维加权模糊识别模型,实现了对典型堤身段的安全模式识别,并对模型指标体系作了敏感性分析。所得成果比较全面地反映了干堤在复杂运行条件下的综合安全特性,对指导工程现场管理与监测有现实意义。对于复杂堤防系统,模糊综合评判是实现全面风险分析的有效手段,而广义多维加权模糊识别模型可以为工程安全决策提供有力依据。     

简析绿色产业在威海的振兴及其发展的启示

通过剖析绿色产业的概念及科学内涵,系统地阐述了国内外绿色产业体系构建的特点及进展,详细描述了威海市以绿色能源、节能减排、农村环保、循环经济和生态农业为主导的绿色产业体系,总结了威海市利用区位优势及地理条件,将发展绿色产业与环保模范城市、生态市创建等活动相结合,把绿色产业体系建设纳入国民经济与社会发展规划,采取加大关键技术研究推广力度,加速绿色产业工业园创建等一系列举措推进绿色产业发展,为利用绿色产业发展机遇振兴地区经济提供有益借鉴。     

水培彩叶草抑制藻类繁殖的试验研究

通过人为控制光照、温度和培养液体积栽种水培彩叶草(简称彩叶草),并对彩叶草的抑藻能力进行测定,分析了彩叶草抑藻过程中营养物质浓度变化,并与凤眼莲的抑藻效果进行对比.结果表明,在不同培养条件下,彩叶草均能明显抑制藻类的过度生长;在保持培养液营养物质自然变化的条件下,栽种彩叶草与不栽种彩叶草培养液的营养物质浓度均直线下降,...     

基于天气分型的北京地区雷电潜势预报预警系统

对1997-2006年457个雷暴过程的环流形势进行对比分析,将北京地区的雷暴天气分为东北低涡低槽、贝蒙低涡低槽、西来槽等11种雷暴天气型;利用南郊观象台(54511站)的探空资料计算对流有效位能、抬升指数和相对风暴螺旋度等33个对流参数,通过与北京地区SAFAIR3000获取的闪电定位资料进行统计分析,提取BCAPE、BLI、MDCI、BIC、KNEW和SWISS等6个对流参数作为北京地区潜势预报参数;采用事件概率回归(REEP)方法,利用获取的6个对流参数作为变量,形成了11种雷暴天气型下的潜势预报方法。利用WRF模式的预报场,建立适用于北京地区3～36 h雷电潜势预报系统。个例实验结果表明其具有较好准确性。由于该系统建立过程中使用了高分辨率探测资料和中尺度模式的输出结果,实现了雷电潜势预报由点到面,由粗到细的突破,对北京地区雷电预警预报具有一定的应用价值。     

Residue determination and dissipation of ioxynil octanoate in maize and soil

A simple and efficient residue analysis method for direct determination of ioxynil octanoate in maize and soil was developed and validated with High Performance Liquid Chromatography-Ultra Violet (HPLC-UV). The samples were extracted with mixtures of acetonitrile and deionized water followed by Solid Phase Extraction (SPE) to remove co-extractives prior to analysis by HPLC-UV. The recoveries of ioxynil octanoate extracted from maize and soil samples ranged from 86 %–104 % and 84 %–96 %, respectively, with relative standard deviation (RSD) less than 7.84% and sensitivity of 0.01 mg kg^?1. The method was applied to determine the residue of ioxynil octanoate in maize and soil samples from experimental field. Data had shown that the dissipation rate in soil was described as pseudo-first-order kinetics and the half-life (t_1/2) was less than 1.78 days. No ioxynil octanoate residue (<0.01 mg kg^?1) was detected in maize at harvest time withholding period of 60 days after treatments of the pesticide. Direct confirmation of the analytes in field trial samples was realized by Liquid Chromatography-Mass Spectrometry (LC-MS).     

锆(Ⅳ)负载交联壳聚糖吸附硫酸根的性能

以甲醛、苯甲醛为交联剂,制备交联壳聚糖树脂,再与锆(Ⅳ)离子反应制备锆负载交联壳聚糖吸附剂。采用静态吸附法考察了该吸附剂对水中硫酸根离子(SO24-)的吸附性能。实验发现,吸附时间2 h,SO24-溶液初始浓度500 mg/L,pH值3.0,溶液温度35℃为较优的吸附条件;吸附过程符合Langmuir等温吸附模型,属于优惠吸附型,吸附容量可达78.65 mg/g;吸附过程较好地符合拟二级动力学模型;锆负载前后交联壳聚糖对硫酸根的吸附量提高了约4.5倍;该吸附剂具有良好的耐酸性和再生性能。     

Comparative and competitive adsorption of Cr(VI), As(III), and Ni(II) onto coconut charcoal

This study evaluates the behavior of coconut charcoal (AC) to adsorb Cr(VI), As(III), and Ni(II) in mono- and multicomponent (binary and ternary) systems. Batch experiments were carried out for mono- and multicomponent systems with varying metal ion concentrations to investigate the competitive adsorption characteristics. The adsorption kinetics followed the mechanism of the pseudo-second-order equation in both single and binary systems, indicating chemical sorption as the rate-limiting step of adsorption mechanism. Equilibrium studies showed that the adsorption of Cr(VI), As(III), and Ni(II) followed the Langmuir model and maximum adsorption capacities were found to be 5.257, 0.042, and 1.748 mg/g, respectively. In multicomponent system, As(III) and Ni(II) adsorption competed intensely, while Cr(VI) adsorption was much less affected by competition than As(III) and Ni(II). With the presence of Cr(VI), the adsorption capacities of As(III) and Ni(II) on AC were higher than those in single system and the metal sorption followed the order of Ni(II)?>?As(III)?>?Cr(VI). The results from the sequential adsorption–desorption cycles showed that AC adsorbent held good desorption and reusability.     

文丘里对脉冲喷吹过滤系统清灰的影响

在自建的脉冲喷吹实验台上,利用Y—YD-7044型压电式传感器和MYD-8801加速度传感器,测试0120×2000mm覆PTFE膜无纺布滤袋在不同喷吹压力下,加文丘里与不加文丘里时的最大侧壁压力峰值和最大反向加速度,并对比计算了获得同样清灰强度时的脉冲阀一次喷吹耗气量。结果显示,添加文丘里能显著增大滤袋中下部最大侧壁压力峰值和整条滤袋上的最大反向加速度,即提高脉冲喷吹清灰强度;对应同样的喷吹压力,加文丘里时的平均最大侧壁压力峰值和平均最大反向加速度比不加文丘里时分别平均提高大约70％和50％;加文丘里获得同样清灰强度时的脉冲阀一次喷吹耗气量比不加文丘里时节省40％左右。证实对于脉冲喷吹清灰系统,添加文丘里能有效改善清灰效果以及减小能量？肖耗。     

Occurrence and distribution of organic trace substances in waters from the Three Gorges Reservoir, China

This study deals with the evaluation of water quality of the Three Gorges Reservoir (TGR) in order to assess its suitability as a raw water source for drinking water production. Therefore, water samples from (1) surface water, (2) tap water, and (3) wastewater treatment plant effluents were taken randomly by 2011–2012 in the area of the TGR and were analyzed for seven different organic contaminant groups (207 substances in total), applying nine different analytical methods. In the three sampled water sources, typical contaminant patterns were found, i.e., pesticides and polycyclic aromatic hydrocarbons (PAH) in surface water with concentrations of 0.020–3.5 μg/L and 0.004–0.12 μg/L, disinfection by-products in tap water with concentrations of 0.050–79 μg/L, and pharmaceuticals in wastewater treatment plant effluents with concentrations of 0.020–0.76 μg/L, respectively. The most frequently detected organic compounds in surface water (45 positives out of 57 samples) were the pyridine pesticides clopyralid and picloram. The concentrations might indicate that they are used on a regular basis and in conjunction in the area of the TGR. Three- and four-ring PAH were ubiquitously distributed, while the poorly soluble five- and six-ring members, perfluorinated compounds, polychlorinated biphenyls, and polybrominated diphenyl ethers, were below the detection limit. In general, the detected concentrations in TGR are in the same range or even lower compared to surface waters in western industrialized countries, although contaminant loads can still be high due to a high discharge. With the exception of the two pesticides, clopyralid and picloram, concentrations of the investigated organic pollutants in TGR meet the limits of the Chinese Standards for Drinking Water Quality GB 5749 (Ministry of Health of China and Standardization Administration of China 2006) and the European Union (EU) Council Directive 98/83/EC on the quality of water intended for human consumption (The Council of the European Union 1998), or rather, the EU Directive on environmental quality standards in the field of water policy (The European Parliament and The Council of the European Union 2008). Therefore, the suggested use of surface water from TGR for drinking water purposes is a valid option. Current treatment methods, however, do not seem to be efficient since organic pollutants were detected in significant concentrations in purified tap water.