Effects of Cu（Ⅱ） and humic acid on atrazine photodegradation

This work was designed to explore the characteristics of photodegradation of herbicides in the copper-polluted water body. The results showed that Cu(II) alone could induce a photo Fenton-like reaction to enhance the degradation of atrazine, in which hydroxyl radical ( OH) was a main active species. Humic acids restrained atrazine degradation, nevertheless, when introducing Cu(II), the photodegradation was accelerated, in which singlet oxygen (1O2) replaced OH acting as the prevailing species. A feasible mechanism for the photochemical process was also proposed, which is helpful for better understanding the environmental photochemistry of atrazine in the copper-polluted water.     

Potential particulate pollution derived from UV-induced degradation of odorous dimethyl sulfide

UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively. Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere.     

Interspecific competition effects on phosphorus accumulation by Hydrilla verticillata and Vallisneria natans

The competition between submersed plants has been recognized as an important factor influencing the structure of plant communities in shallow lakes. The ability of different species to take up and store nutrients from the surrounding ambience varies, and hence plant community structure might be expected to affect the cycling of nutrients in lake ecosystems. In this study, the uptake of phosphorus by Hydrilla verticillata and Vallisneria natans was studied and compared in monoculture and competitive mixed-culture plantings. Results showed that for both studied species the phosphorus concentrations of different tissues and of whole plants was unaffected by competition. However, the quantity of phosphorus accumulated by whole plants of H. verticillata was significantly higher in mixture culture than in monoculture, while that of V. natans was lower in the mixed culture. The results indicated that H. verticillata has a competitive advantage over V. natans, when the two species are grown in competition, and is able to accumulate a greater quantity of phosphorus.     

Preparation and coagulation efficiency of polyaluminium ferric silicate chloride composite coagulant from wastewater of high-purity graphite production

The aim of the present work was to produce a polyaluminium ferric silicate chloride (PAFSiC) coagulant from acidic and alkaline wastewater of purifying graphite by roasting, and subsequently to evaluate coagulation efficiency of the reagent by treating surface water from the Yellow River as well as municipal wastewater in comparison with the conventional coagulant polyaluminium chloride (PAC). The PAFSiC coagulant was prepared by co-polymerization. The effects of (Al+Fe)/Si molar ratio, OH/(Al+Fe) molar ratio (i.e., value), coagulant dosage and pH value of test suspension on the coagulation behavior of FAFSiC and the stability of the PAFSiC were also examined. Results showed that PAFSiC performed more efficiently than PAC in removing turbidity, chemical oxygen demand (COD), and total phosphate (TP). The PAFSiC with a value of 2.0 and (Al+Fe)/Si ratio of 5 (PAFSiC 2.0/5) showed excellent coagulation effect for both turbidity and COD, while PAFSiC 1.0/5 was the best for TP. The optimum coagulation pH range of PAFSiC 2.0/5 was 5.0–9.0, slightly wider than that of PAC (6.0–8.0). The process can be easily incorporated into high-purity graphite production plants, thereby reducing wastewater pollution and producing a valuable coagulant.     

Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period

Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir.     

Synthesis and scale inhibitor performance of polyaspartic acid

Polyaspartic acid (PASP) has been extensively studied in recent years as a green scale inhibitor. PASP was synthesized by thermal polycondensation of maleic anhydride and ammonium carbonate in this study. The optimal polycondensation reaction conditions were the raw material (maleic anhydride and ammonium carbonate) molar ratio of 1.0:1.2, the polymerization temperature of 180°C and reaction time of 2.0 hr. The results showed that PASP exhibits very good scale inhibiting performance. The inhibition rate was 95% for calcium carbonate and 90% for calcium sulfate by the application of 5 mg/L PASP.     

西辽河流域沙土的氨氮解吸行为研究

采用小型回填式土柱淋溶实验方法研究了西辽河流域沙土的氨氮解吸行为。结果表明,西辽河流域沙土的氨氮解吸行为符合Langmuir和Freundlich解吸等温式;沙土氨氮解吸比率Dr在0.44～0.99之间,平均为0.75,解吸迟滞性指数TⅡ在0.05～0.65之间,平均为0.29,沙土对氨氮的解吸迟滞性较强,解吸可逆性较弱。被吸附的氨氮解吸淋失的环境风险较小;沙土氨氮解吸比率Dr与土壤有机质含量、粘粒含量和粗粘粒含量呈极显著负相关,影响程度顺序为:有机质含量>粗粘粒含量>粘粒含量;解吸分配系数k和解吸迟滞性指数与土壤有机质含量分别呈极显著和显著正相关,与粘粒含量和粗粘粒含量没有相关性;草地、农田和林地结构由于土壤有机质和团聚体含量较高,氨氮解吸迟滞性较强,氨氮流失的环境风险较小,沙荒地结构氨氮流失的环境风险较大。     

电厂二氧化碳捕捉技术对比研究

由于全球温室效应的不断加剧,发展二氧化碳捕捉技术变得十分必要.通过分析燃烧前捕捉、燃烧后捕捉和富氧燃烧捕捉三种二氧化碳捕捉方式流程及其特点,指出三种不同的二氧化碳捕捉技术的发展现状以及应用途径.通过具体对比现有二氧化碳捕捉技术的工作原理以及优缺点,针对现有的几种具体的二氧化碳捕捉技术进行详细的分析,积极应用各种物理、化...     

微生物絮凝剂的絮凝性及抗氧化性研究

考察了一株产絮凝剂细菌BK-4所产絮凝剂的絮凝能力、组成及抗氧化性.结果表明,接种量2％、培养24 h后BK-4菌发酵液的最大絮凝率可达96.9％.发酵液的主要组成为多糖,提取方法对粗提物的絮凝率有明显影响,水溶醇沉法粗提物的最大絮凝率可达95.6％,粗提物多糖含量为1.65g/L时对DPPH自由基的捕获率可达最大值3...