Use of a multi-layer column device for study on leachability of nitrate in sludge-amended soils

This paper described a multi-layer column device constructed with six cylindrical polythene tubes with installation of Rhizon soil moisture samplers (Rhizon SMS). The feasibility of using the column device to collect soil solution and percolate and to monitor leachability of nitrate in two sludge-amended soils was evaluated under glasshouse conditions. The soil moisture sampler in the device was demonstrated to be a non-destructive, simultaneous, sequential, convenient and rapid sampling tool for multiple-site porewater extraction. The device provided an in situ monitoring technique for leachability of nitrate in a soil profile following application of the anaerobically digested sewage sludge. The monitored results showed that surface soil amendment of the sewage sludge increased markedly the concentration of nitrate in the soil solutions at depths of 10-30 cm in a neutral paddy soil and at 30-50 cm in an acid red paddy soil. This amendment also largely increased nitrate in the percolates of the acid red soil. The movement and distribution patterns of nitrate in the profile were related to soil types, profile depths and experimental periods. Land application of sewage sludge may pose a risk in groundwater contamination of nitrate.     

2株漂白废水高效降解菌的选育

用含氯漂白废水驯化城市污水处理厂的好氧污泥 ,从中分离出两株高效去除有机氯的菌 ,并对其适应条件进行了研究。结果表明 ,当pH为 7.0、废水浓度为 5 0 %、加入 0 .4g/L葡萄糖、2mL菌液时 ,处理效果较好 ,有机氯的去除率最高可达 74 .8%。     

DDTC—TX—100胶束增溶直接光度法测定水中痕量铜

在ＴｒｉｔｏｎＸ－１００存在下，ＤＤＴＣ（二乙基二硫代氨基甲酸钠）与铜反应生成络合物Ｃｕ（ＤＤＴＣ）２有增溶增敏作用，建立了痕量铜的直接光度测定方法。该方法操作简便快捷，选择性［１］、精密度与准确度都较好，相对标准偏差为０８％～４３％，回收率为９６％～１０６％，摩尔吸光系数ε＝６４×１０３Ｌ／ｍｏｌ·     

Oil spill model development and application for emergency response system.

The paper introduces systematically the developing principle of CWCM 1.0 oil spill model based on Lagrange system and oil spill fate processes in environment, reviews two oil spill incidents of "East Ambassador" in Jiaozhou Bay and "Min Fuel 2" in the mouth of Pearl River, and designs the predictable system simulating oil spill applied in contingency plans. It is indicated that CWCM 1.0 has met preliminarily the demands for functions of precision simulating and predicting oil spill, and can plan an important role to support oil spill response.     

基于博弈模型的水价策略与节水策略分析

在当前水资源浪费、用水效率较低的背景下,仍然有许多地区继续实行低水价政策,本文认为这是供水企业与用水企业以及政府水务部门相互博弈的结果。通过构建一个供水企业与用水企业的博弈模型,并采用演化博弈分析方法分析动态演化的结果,本文发现当前采用低水价的主要原因在于：供水企业制定水价时要同时考虑私人收益与公共节水收益,而高水价对经济产生的冲击成本不足以弥补高水价产生的公共节水收益与私人收益,从而导致有些地区供水企业不敢提高水价,一直采用低水价策略。进一步地,本文采用不完全信息动态博弈方法分析供水企业与政府关于水价的议定过程,发现提高水价对经济的冲击越大,且节水技术投入成本越大而节水的公共收益越小时,政府水务部门同意低水价的概率越大;反之,则同意高水价的概率越大。从博弈论的角度系统地分析了低水价产生的决策过程,可对提高水价、促进节约用水具有一定的指导意义。     

从银铅锌废渣中回收硝酸银的研究

介绍了用灼烧、浸取、沉淀、溶转和离子交换等方法,从银铅锌废渣中直接回收硝酸银,收率可达80.12%,AgNO3纯度为99.9%。考察了试料粒度、FeCl3质量浓度、溶液酸度、固液比,反应温度及浸取时间对银浸出率的影响。     

Carbon nanotubes and Cu–Zn nanoparticles synthesis using hyperaccumulator plants

This article reports a novel way to synthesize carbon nanotubes and Cu/ZnO nanoparticles using metal hyperaccumulator plants. Metal hyperaccumulator plants are traditionally used for phytoremediation to clean soil polluted by toxic metals. However, the transfer of toxic metals in plant shoots and leaves is an environmental issue because animals and other living organisms feeding on plants will transfer the metals to the ecosystem. Therefore, we suggest that hyperaccumulator plants could be used to synthesize nanoparticles. Here, Brassica juncea L., a Cu-hyperaccumulator plant, was collected around a copper mine and used as a raw chemical to produce carbon nanotubes and Cu/ZnO nanoparticles. The chlorophyll in shoots of B. juncea plants was ethanol extracted to yield chlorophyllin. Cu and Zn were extracted by HNO₃ to form Cu/Zn(NO₃)₂. The chlorophyllin reacted with Cu/Zn(NO₃)₂ to form Cu/Zn chlorophyllin. Cu/ZnO nanoparticles were synthesized by direct precipitation of Cu/Zn chlorophyllin with NaOH and ethanol. The vascular bundles in B. juncea plants, which have been purified and carbonized by HNO₃, were rapidly heated to about 400°C and then they were cooled to room temperature to obtain carbon nanotubes. Results indicate that the outer diameter of carbon nanotubes was around 80 nm. Cu/ZnO nanoparticles have a Cu_0.05Zn_0.95O composition, and had a diameter of about 97 nm. Our study not only inspires the search for a new strategy on the synthesis of nanostructure from renewable natural products, but also breaks through the traditional and limited ideas about the reuse of metals by hyperaccumulator plants.     

Comparative studies of the fate of atrazine‐14C and pentachlorophenol‐14C in various laboratory and outdoor soil‐plant systems

Abstract

Mass balance and fate of atrazine‐ ¹⁴C and pentachlorophenol‐ ¹⁴C (PCP‐ ¹⁴C) were studied in short‐term tests in a closed aerated laboratory soil‐plant system, using two concentrations in soil and two plant species, as well as under outdoor conditions for one vegetation period. In the laboratory, for both pesticides bioaccu‐mulation factors of radiocarbon taken up by the roots into plants were low. They were higher for lower (1 ppm) than for higher soil concentrations (6 ppm for atra‐zine, 4 ppm for pentachlorophenol) and varied with the plant species. Mineralization to ¹⁴CO₂ in soil was negatively related to soil concentration only for PCP‐ ¹⁴C. Conversion rates in soil including the formation of soil‐bound residues were higher for the lower concentrations of both pesticides than for the higher ones; conversion rates in plants were species‐dependent. In 14 terms of CO₂ formation and of conversion rates, PCP was less persistent in soil than was atrazine. For both pesticides, laboratory data on conversion and mineralization gave a rough prediction of their persistence in soil under long‐term outdoor conditions, whereas bio‐accumulation factors in plants under long‐term outdoor conditions could not be predicted by short‐term laboratory experiments.     

Lead-induced oxidative damage in steriled seedlings of Nymphoides peltatum

The effects of increasing concentrations of lead (Pb) on Pb accumulation and its influence on nutrient elements, malondialdehyde (MDA) content, generation of superoxide anion (O₂ ^?·), hydrogen peroxide (H₂O₂) content, antioxidant enzymes activities, soluble protein, and photosynthetic pigment, as well as chloroplast ultrastructure in steriled seedlings of Nymphoides peltata (S. G. Gmel.) Kuntze were investigated in order to understand Pb-induced toxicity. The accumulation of Pb was found to increase in a concentration-dependent manner. Nutrient elements (Ca, K, Fe, Mn, and Mo) were also affected. MDA content and O₂ ^?· generation rate increased progressively, while H₂O₂ content first boosted up at a low Pb concentration of 12.5 μM but then declined. Guaiacol peroxidase and catalase activities increased alternately, while superoxide dismutase activity gradually fell. Negative correlations were found between Pb and soluble protein and photosynthetic pigment. Moreover, Pb exposure resulted in a significant damage of chloroplasts. Taken together, these findings supported the hypothesis that Nymphoides peltatum underwent oxidative stress induced by Pb. In addition, both the disorder of nutrient elements and the damage to the ultrastructure of chloroplasts were indicative of general disarray in the cellular functions exerted by Pb.     

基于Logistic模型的中国各省碳排放预测

在“碳排放量与能源消费成正比”假设的基础上,对中国30个省区2011～2020年碳排放进行了预测。首先对中国30个省区1987～2010年的历史累计排放量和人均累计排放量进行计算,依据历史累计排放量和人均累计排放量两个指标,运用K-均值聚类分析法将中国各省区碳排放分成了5类。分别绘出5类区域中各省的历年碳排放量曲线,并进行数据分析,发现：以2002年为界线,2002年前后两个时段中国各省区碳排放变化差异很大。这一现象说明2002年以前的各省碳排放趋势并不能表征未来年份各省的碳排放。在此结论的基础上,构建了碳排放量增长的Logistic预测模型,并以2002～2010年碳排放数据为样本数据,对2011～2020年中国各省区碳排放进行了预测。为了验证预测模型的精确性,利用Logistic预测模型对中国30个省区2002～2010年的碳排放进行了预测,并将预测值与实际排放值进行比较发现,除了宁夏自治区的误差达1458%外,其他地区的误差均在7%以下。除宁夏外的中国各省区预测误差的平均值为622%,由此验证了Logistic预测模型的精确性。同时,也说明对中国30个省区2011～2020年碳排放的预测值具有较高的可信性。本研究为中国各省未来碳排放政策的制定提供了方法与数据支持