国家高新区提升城市绿色创新效率的作用机制与效果识别--基于双重差分法的检验

绿色创新作为将环境保护与经济增长有机整合的发展战略,是当前解决城市发展困境的一剂良方,实践中,促进城市绿色创新水平提升成为政界和学界共同关注的话题。国家高新区是推动城市绿色创新水平提升,实现经济可持续发展的重要载体,然而关于国家高新区设立是否对城市绿色创新发展起作用仍需要进一步实证检验。利用中国285个地级市2003—2016年的面板数据,通过构建双向固定效应模型实现双重差分的目的,识别国家高新区建立影响区域绿色发展的作用机制,并评估高新区驱动城市绿色创新效率提升的净效应。研究结果表明:①国家高新区显著提高了城市绿色创新效率,这一结果在经过了反事实检验和多项稳健性检验后依然成立。②从理论上构建了高新区驱动绿色创新效率提升的影响机制,并通过实证检验甄别出了高新区促进城市绿色创新效率提升的创新驱动机制和结构驱动机制,而未通过集聚驱动机制,"形聚而神不聚"的现象仍广泛存在。③高新区驱动绿色创新效率的提升呈现明显的区域异质性,高新区对东部区域的绿色创新效率驱动效果明显,而对中西部区域效果不明显。④高新区驱动绿色创新效率提升还存在着城市等级的差异,一定程度上表现为"边际递减规律",相比于省会城市,副省会城市、较大的市和一般的市从高新区设立当中获得的政策效益更大。为了进一步提升高新区对城市绿色创新水平的驱动作用,文章据此从发挥集聚推动效应、增强自主创新能力、推动产业转型升级、因地制宜发展高新区等方面提出相关政策建议。     

Numerical Study of Hydrodynamic and Solute Transport with Discontinuous Flows in Coastal Water

This paper aimed to develop a depth-averaged explicit model for flow and pollutant transport in coastal waters based on the shallow water equations and the mass advection-diffusion equation. The proposed model was discretized using the finite volume method (FVM) with triangular cells. Then, it applied Roe’s approximate Riemann solution to compute the water momentum flux on the grid interfaces. This model enabled the higher accuracy in capturing the dry-wet moving fronts (discontinuous problems for flow and solute). The high-resolution scheme was evaluated to solve the advection and diffusion terms for mass transport. The model was verified by comparing the predictions of analytical solutions, laboratory tests, and other simulations for Gironde estuary with good computational accuracy. The developed model was also used to calculate the circulation and the motion of chemical oxygen demand (COD) pollutants from the sewage outfalls in the Zhuanghe coastal water with dry and wet moving boundaries. The research results showed that the residual current directions of spring and neap tides were basically the same in the Zhuanghe coastal water. However, the tide residual current of spring tide was slightly greater than that of the neap tide. In addition, there were tide residual currents from the northeast to the southwest in nearshore water and from the southwest to the northeast outside the banks, respectively. The tidal flows in the alongshore direction were strong, resulting in highly spread concentration distributions. In particular, the COD concentration reached some parts of the southern water. It could be seen that the excessive pollutant discharge from the sewage outfalls located at Zhuanghe district would cause serious pollution in aquaculture water near Shicheng island.     

Modeling vehicle interior noise exposure dose on freeways: Considering weaving segment designs and engine operation

Vehicle interior noise functions at the dominant frequencies of 500 Hz below and around 800 Hz, which fall into the bands that may impair hearing. Recent studies demonstrated that freeway commuters are chronically exposed to vehicle interior noise, bearing the risk of hearing impairment. The interior noise evaluation process is mostly conducted in a laboratory environment. The test results and the developed noise models may underestimate or ignore the noise effects from dynamic traffic and road conditions and configuration. However, the interior noise is highly associated with vehicle maneuvering. The vehicle maneuvering on a freeway weaving segment is more complex because of its nature of conflicting areas. This research is intended to explore the risk of the interior noise exposure on freeway weaving segments for freeway commuters and to improve the interior noise estimation by constructing a decision tree learning–based noise exposure dose (NED) model, considering weaving segment designs and engine operation. On-road driving tests were conducted on 12 subjects on State Highway 288 in Houston, Texas. On-board Diagnosis (OBD) II, a smartphone-based roughness app, and a digital sound meter were used to collect vehicle maneuvering and engine information, International Roughness Index, and interior noise levels, respectively. Eleven variables were obtainable from the driving tests, including the length and type of a weaving segment, serving as predictors. The importance of the predictors was estimated by their out-of-bag–permuted predictor delta errors. The hazardous exposure level of the interior noise on weaving segments was quantified to hazard quotient, NED, and daily noise exposure level, respectively. Results showed that the risk of hearing impairment on freeway is acceptable; the interior noise level is the most sensitive to the pavement roughness and is subject to freeway configuration and traffic conditions. The constructed NED model shows high predictive power (R = 0.93, normalized root-mean-square error [NRMSE] < 6.7%).

Implications: Vehicle interior noise is usually ignored in the public, and its modeling and evaluation are generally conducted in a laboratory environment, regardless of the interior noise effects from dynamic traffic, road conditions, and road configuration. This study quantified the interior exposure dose on freeway weaving segments, which provides freeway commuters with a sense of interior noise exposure risk. In addition, a bagged decision tree–based interior noise exposure dose model was constructed, considering vehicle maneuvering, vehicle engine operational information, pavement roughness, and weaving segment configuration. The constructed model could significantly improve the interior noise estimation for road engineers and vehicle manufactures.     

基于资源-技术-环境的高技术城市矿产战略性筛选

城市矿产中蕴含大量的高技术矿产,它们是战略性新兴产业发展的关键原材料。本文从中国国情出发,界定了涵盖新能源技术、通讯设备、交通工具、电池、电器电子产品等5大类共计27种高技术城市矿产,从资源、技术、环境三个维度设计了11项指标,对高技术城市矿产进行战略性筛选;并通过半定量化不确定性分析方法确定研究结果的可靠性。结果显示:(1)从资源-技术两维度看,电器电子产品用电池资源指数高,且技术相对成熟;动力汽车电池资源指数值略低,但未来开发潜力大。(2)从资源-环境两维度看,电池是拆解处置重点。(3)从资源-技术-环境三维度来看,高技术城市矿产可以分为四个梯队:高资源指数、高技术指数、高环境指数的"三高"梯队,包括EEE用镍氢电池、EEE用镍镉电池、EEE用锂离子电池;中高资源指数、中高技术指数、中高环境指数的"三中高"梯队,包括手机和动力汽车电池;低资源指数、低技术指数、中高环境指数的"二低一中高"梯队,包括风涡轮机、荧光灯、动力汽车永磁电机和电话机;资源指数、技术指数、环境指数都相对较低的"三低"梯队,包括电器电子产品和光伏电板。此外,随着时间的推移,筛选结果会发生动态变化,因此高技术城市矿产的战略性筛选是一个持续动态的评估过程,需要建立与之相适应的"开发一批、储备一批、谋划一批"的动态管理系统。基于研究结论,本文从高技术城市矿产的基础数据库建立、重点开发目录制定与调整、在线回收与交易平台构建、拆解技术储备以及可持续供应体系建立等方面提出了建议。     

低温NH_3-SCR脱硝催化剂的研究现状与进展

高效催化剂的研制与开发是低温氨气选择性催化还原(NH_3-SCR)脱硝技术的核心。从活性组分(单一氧化物型、复合氧化物型)和载体(金属氧化物、碳基材料、分子筛)两方面详细介绍了低温NH_3-SCR催化剂,总结了其研究现状,并讨论了其抗水、抗硫性能及失活原因。指出在保证催化剂具有较高活性的同时提高其抗水、抗硫性能,是低温NH_3-SCR催化剂未来研究的重点。     

ZnO NPs对水培小麦(Triticum aestivum L)种子不同发育阶段的影响

氧化锌纳米颗粒(ZnO NPs)是目前应用最为广泛的纳米材料之一,已有研究表明其对生物体具有显著的毒性效应。为了研究ZnO NPs的毒性与种子发育阶段的关系,选择小麦(Triticum aestivum L)作为受试植物,将处于不同发育阶段的小麦种子置入ZnO NPs悬浮液中进行培养,研究了ZnO NPs对水培小麦种子不同发育阶段的影响。结果表明,虽然ZnO NPs对处于吸胀阶段、萌动阶段和发芽阶段的小麦都可以产生毒性,但是毒性的大小随小麦发育阶段的不同而表现出明显的差异(P0.05)。在60 mg·L-1暴露浓度下,用ZnO NPs对处于吸胀阶段、萌动阶段和发芽阶段的小麦种子进行处理,小麦根长的抑制率分别为37.8%、80.2%和95.7%;就萌动阶段和发芽阶段而言,ZnO NPs的毒性与其浓度有关,浓度越大毒性越大,即具有显著的浓度效应。上述研究结果对于全面准确地评价ZnO NPs毒性具有重要的意义。     

The cause and influence of self-cementing properties of fine recycled concrete aggregates on the properties of unbound sub-base

The use of coarse recycled concrete aggregates (CRCA) in conjunction with fine recycled concrete aggregates (FRCA) as sub-base materials has been widely studied. Although research results indicate that it is feasible to employ both CRCA and FRCA as granular sub-base, the influence of the unhydrated cement in the adhered mortar of the RCA on the properties of the sub-base materials has not been thoroughly studied. Generally, it is known that the strength of the sub-base materials prepared with RCA increases over time. However, this mechanism, known as the self-cementing properties, is not well understood and is believed to be governed by the properties of the fine portion of the RCA (<5mm). This paper presents an investigation on the cause of the self-cementing properties by measuring X-ray diffraction patterns, pH values, compressive strength and permeability of various size fractions of the FRCA obtained from a commercially operated construction and demolition waste recycling plant. Their influence on the overall sub-base materials was determined. The results indicate that the size fractions of <0.15 and 0.3-0.6mm (active fractions) were most likely to be the principal cause of the self-cementing properties of the FRCA. However, the effects on the properties of the overall RCA sub-base materials were minimal if the total quantity of the active fractions was limited to a threshold by weight of the total fine aggregate.     

生态足迹计算模型应用中热点问题及探讨

简要介绍了生态足迹计算模型,论述了近年国际上争论的几个主要热点问题,数据的准确完整性,初级产品与二级产品,均衡因子与产量因子,全球产量与本地产量,以及能源足迹计算等,并对其进行了探讨和指出今后研究发展的方向。     

湖南省红色村落空间分布格局及公路可达性研究

基于“红色村落”概念内涵界定,以湖南省262个乡村红色旅游景区(点)为数据样本,综合运用数理建模和GIS空间分析方法,定量刻画了全省红色村落空间分布格局及可达性特征。结果表明：(1)全省红色村落呈集聚型分布状态,不同空间板块或行政单元红色村落分布非均衡性特征突出,集聚强度具有随尺度距离增加而不断弱化的“空间衰减”规律;(2)红色村落整体呈“大分散、小集聚”分布格局,全省存在三大高密度集聚区以及多个红色村落跨界连绵集群组团,长征沿线、湘鄂赣及湘粤赣边区等形成多个“中低密度”集聚片区;(3)红色村落通行时间平均值为221.58 min,标准差为42.75,可达性整体状况不理想,且内部差异显著,可达性水平稳健性欠佳,不同可达时段内红色村落数理分布近似于呈“金字塔”状结构;(4)红色村落可达性空间分布呈现“中心-外围”结构特征,省际边缘区形成多个交通可达性低谷,与其核密度格局存在“空间错位性”,且具有沿交通干线分布的指向特征。最后,提出了优化红色村落可达性格局、驱动交通区位重构和推进红色旅游开发的对策建议。     

酸析-Fenton试剂氧化-混凝法处理制浆废水

用酸析-Fenton试剂氧化-混凝法对自偶氧化清洁制浆废水进行预处理,考察了各种因素对处理效果的影响。最佳处理条件：酸析时的废水pH为3．0;酸析后上层清液无需调节pH,加水稀释至COD为2000mg／L后进行Fenton试剂氧化,H2O2加入量为84．56mmol／L,FeS04加入量为8．44mmol／L,反应时间60min;混凝时Ca（OH）：加入量为2g／L。最终出水的COD为577．20mg／L（COD去除率为71．14％）,色度为36倍,pH为8．60。