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971.
Giuseppe Esposito Riccardo Salvini Fabio Matano Marco Sacchi Claudia Troise 《Journal of Coastal Conservation》2018,22(5):957-972
Geomorphic evolution of sea cliffs has significant impact on coastal settlements worldwide, so that evaluation of cliff instability processes, failure factors, and retreat rates involves a growing number of scientists for coastal risk and management purposes. Aerial photogrammetry and lidar are among the most used techniques for topographic characterization and geomorphic monitoring of coastal environments. A crucial role in the combined use of such techniques is the evaluation of different spatial accuracy and co-registration between derived terrain models, so that a robust error analysis is required. In this study, we present a change detection analysis of the Torrefumo coastal cliff, in the Campi Flegrei volcanic area (Southern Italy). Aerial images taken in 1956 and 1974, processed through digital photogrammetry, and an airborne lidar point cloud acquired in 2008 were used to produce Digital Elevation Models of the cliff. The analysis was based on the multi-temporal comparison of these models and included the calculation of volumetric changes and average retreat rates of the cliff face with reference to the 1956–1974 and 1974–2008 time intervals. The spatially variable elevation uncertainty of each Digital Elevation Model was evaluated with a probabilistic approach based on the fuzzy set theory. The results of this study showed significant eroded volumes during the period 1956–1974 and relatively smaller volumes in the 1974–2008 time span, with mean annual retreat rates of 1.2 m/year and 0.17 m/year, respectively. We infer that the significant decrease of erosion characterizing the second period was induced by the sheltering effect at the base of the cliff produced by the construction of a seawall in the early 80’s. 相似文献
972.
Yan SHAO Haobo HOU Guangxing WANG Sha WAN Min ZHOU 《Frontiers of Environmental Science & Engineering》2016,10(1):192-200
Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure. 相似文献
973.
单甲脒在水生生物中的积累和释放 总被引:1,自引:0,他引:1
本文朱生环境中对单甲脒在鱼和藻类中的积累释放及鱼体中的BCF值进行了研究,结果表明,鱼体在3,5,6d的BCF值分别为3.53,4.73及5.29,鱼体中单米积累为内脏〉锶〉肌肉,饲养7d达积累最高量;藻类在6h后达积累最高量;单甲脒在水藻和鱼(内脏)的富集比分别为1:3及1:12。 相似文献
974.
Spatial distribution and temporal variation of epibenthic assemblages of coralligenous biogenic rocky outcrops occurring in
the northern Adriatic Sea (45°04′–45°24′N; 12°23′–12°43′E) were investigated by photographic sampling from 2003 to 2006 at
12 randomly selected sites. The dominant reef-forming organisms were the encrusting calcareous algae (Lithophyllum stictaeforme, Lithothamnion minervae and Peyssonnelia polymorpha), while the main bioeroders were boring sponges (Cliona viridis, C. celata, C. thoosina, C. rhodensis, Piona vastifica) and the bivalve Gastrochaena dubia. Composition of the assemblages varied thorough years and among sites. Spatial heterogeneity, at local and regional scale,
prevailed over temporal variation. This variability was related both to the geo-morphological features of the outcrops and
to environmental variables. Sites clearly differed in the percent cover of reef builder and bioeroder species while only limited
temporal variation within site was found. Some taxa revealed complex intra-site temporal trends. These results provide valuable
information on the diversity and variability of epibenthic assemblages of the northern Adriatic coralligenous reefs, essential
for the management and conservation of these unique biogenic habitats. 相似文献
975.
The present study addresses the effect of maternal diet on hatching success and condition of embryos and larvae of Antarctic
krill Euphausia superba. Lipid and fatty acid content and composition were determined in field and laboratory samples. Developmental stages analyzed
in embryos included: multiple-cell, gastrula, and limb-bud stages. Larval stages analyzed included: nauplius I, nauplius II,
and metanauplius. Laboratory-reared embryos were spawned by gravid females incubated under three feeding groups: (1) phytoplankton
mixture, (2) phytoplankton mixture and minced clam, and (3) phytoplankton mixture, minced clam, and commercial larval food.
Hatching success was highest in group 3 (100%), lowest in group 1 (0%), and highly variable in field samples (0–48%). Lipid
decreased slightly in embryos during embryonic development, while large decreases in lipid were found during nauplius development.
High levels of 18:2(n-6), 20:4(n-6), and 22:6(n-3) observed with group 3 samples coincided with high hatching success in krill
embryos. The ratio of 22:6(n-3)/20:5(n-3) also correlated to hatching success of embryos. The fatty acid profile of embryos
in group 3 was similar to that of the field-collected embryos, reflecting the contribution of the commercial larval food in
the maternal diet. In our study, the maternal diet was found to influence the fatty acid composition of embryos and in turn
affects the hatching success of krill. Specific polyunsaturated fatty acids appeared to play important roles in embryogenesis
in krill. 相似文献
976.
以粉煤灰(FA)为原料,采用共沉淀法制备了层状双金属氢氧化物(LDH)和层状金属氧化物(LMO,也称LDO),并采用XRD和BET技术进行了表征。比较了FA、LDH、LMO对活性红X-3B染料(X-3B)的吸附效果;考察了LMO吸附X-3B的影响因素,并探讨了吸附机理。XRD表征结果表明,LMO在吸附X-3B后重新恢复LDH层状结构。BET表征结果表明,LMO的比表面积大于LDH。吸附实验结果表明,3种吸附剂对X-3B吸附效果的优劣顺序为:LMOLDHFA;在初始X-3B质量浓度为50 mg/L、LMO投加量为2.0 g/L、吸附温度为25℃、吸附pH为7、吸附时间为30 min的条件下,X-3B去除率可达98.1%;LMO对X-3B的吸附符合Langmuir等温吸附方程,饱和吸附量为129.53 mg/g,且吸附过程可用准二级动力学方程描述。 相似文献
977.
Dongwoo Kang Min-Gu Lee Yunsung Yoo Jinwon Park 《Journal of Material Cycles and Waste Management》2018,20(3):1562-1573
In this research, absorbents for CO2 capture were prepared by blending 30 wt% potassium carbonate, 3 wt% of a rate promoter, and 1 wt% of a corrosion inhibitor. Pipecolic acid, sarcosine, and diethanolamine were chosen as rate promoter candidates. Based on a rate promoter screening test for CO2 loading capacity and absorption rate, pipecolic acid and sarcosine were selected to be used as rate promoters. 1,2,3-benzotriazole and ammonium thiocyanate were chosen as corrosion inhibitors, and they were mixed with a 30 wt% potassium carbonate-based absorbent mixture containing one of the rate promoters. The absorption rates for four absorbent solutions (30 wt% potassium carbonate?+?3 wt% pipecolic acid?+?1 wt% 1,2,3-benzotriazole, 30 wt% potassium carbonate?+?3 wt% pipecolic acid?+?1 wt% ammonium thiocyanate, 30 wt% potassium carbonate?+?3 wt% sarcosine?+?1 wt% 1,2,3-benzotriazole, and 30 wt% potassium carbonate?+?3 wt% sarcosine?+?1 wt% ammonium thiocyanate) were measured, tabulated, and graphically displayed. These types of absorbents can be used for capturing CO2 under high temperature and pressure conditions, such as those found in coal-fired power plants. 相似文献
978.
Mihail Ionescu Zoran S. Petrović Xianmei Wan 《Journal of Polymers and the Environment》2007,15(4):237-243
Soybean polyols prepared by ring opening reactions of epoxidized soybean oil with hydrogen active compounds (water, alcohols,
organic or inorganic acids, thiols, hydrogen etc.) have a low reactivity in the reaction with isocyanates because the hydroxyl
groups are secondary. This paper presents a simple and convenient method to increase the reactivity of soybean polyols with
secondary hydroxyl groups by ethoxylation reactions with the preservation of triglyceride ester bonds. The method uses mild
reaction conditions: low alkoxylation temperature of 35–45 °C, low pressure of 0.1–0.2 MPa (15–30 p.s.i.) and a superacid
as catalyst (HBF4). The new soybean polyols have a higher reactivity toward isocyanates in polyurethane formation due to the high percentage
of primary hydroxyl groups. The primary hydroxyl content was determined by the second order kinetics of polyol reaction with
phenyl isocyanate. 相似文献
979.
反硝化生物膜对PBS表面形态及化学组分的影响 总被引:2,自引:0,他引:2
PBS是一种新型的可生物降解聚合物(BDPs),可以用做反硝化碳源和生物膜载体,去除饮用水源水中的硝酸盐.利用红外光谱和扫描电子显微镜对反硝化生物膜生长前后PBS颗粒表面形态、化学组成的变化进行了分析.结果表明,PBS仅在微生物作用下降解并为反硝化菌提供碳源.PBS颗粒可以在12 h内使进水中53 mg·L-1的硝态氮降低到10 mg·L-1以下(我国饮用水水质标准为:NO3--N<15 mg·L-1).红外光谱表明,反硝化微生物附着生长后其PBS在2 925 cm-1和2 850 cm-1附近的吸收带以及3 200 cm-1~3 410 cm-1处峰值减弱,说明PBS材料中甲基、羟基官能团比例下降,而其它官能团没有发生明显的变化,PBS的主要单体组分淀粉和乙烯都可以被反硝化微生物用作碳源.扫描电子显微镜观察结果表明,反硝化生物膜附着生长后,PBS颗粒表面会出现空洞,扩大了生物膜生物附着生长的表面积,有利于形成致密的反硝化生物膜,对反硝化菌形成保护作用. 相似文献
980.
Utilizing surfactants to control the sorption, desorption, and biodegradation of phenanthrene in soil-water system 总被引:1,自引:0,他引:1
An integrative technology including the surfactant enhanced sorption and subsequentdesorption and biodegradation of phenanthrene in the soil-water system was introduced and tested. For slightly contaminated agricultural soils, cationic-nonionic mixed surfactant- enhanced sorption of organic contaminants onto soils could reduce their transfer to plants, therefore safe-guarding agricultural production. After planting, residual surfactants combined with added nonionic surfactant could also promote thedesorption and biodegradation of residual phenanthrene, thus providing a cost-effective pollution remediation technology.0ur results showed that the cationic-nonionic mixed surfactantsdodecylpyridinium bromide (DDPB) and Triton X-100 (TX100) significantly enhanced soil retention of phenanthrene. The maximum sorption coefficient Kd* of phenanthrene for contaminated soils treated by mixed surfactants was about24.5 times that of soils without surfactant (Kd ) and higher than the combined effects of DDPB and TX100 individually, which was about 16.7 and 1.5 times Kd , respectively.0n the other hand, TX100 could effectively remove phenanthrene from contaminated soils treated by mixed surfactants, improving the bioavailability of organic pollutants. Thedesorption rates of phenanthrene from these treated soils were greater than 85% with TX100 concentration above2000 mg/L and approached 100% with increasing TX100 concentration. The biodegradation rates of phenanthrene in the presence of surfactants reached over 95% in30days. The mixed surfactants promoted the biodegradation of phenanthrene to some extent in 10-22days, and had no obvious impact on phenanthrene biodegradation at the end of the experiment. Results obtained from this study provide some insight for the production of safe agricultural products and a remediation scheme for soils slightly contaminated with organic pollutants. 相似文献