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51.
52.
A directional passive air sampler for monitoring polycyclic aromatic hydrocarbons (PAHs) in air mass
Tao S Liu YN Lang C Wang WT Yuan HS Zhang DY Qiu WX Liu JM Liu ZG Liu SZ Yi R Ji M Liu XX 《Environmental pollution (Barking, Essex : 1987)》2008,156(2):435-441
A passive air sampler was developed for collecting polycyclic aromatic hydrocarbons (PAHs) in air mass from various directions. The airflow velocity within the sampler was assessed for its responses to ambient wind speed and direction. The sampler was examined for trapped particles, evaluated quantitatively for influence of airflow velocity and temperature on PAH uptake, examined for PAH uptake kinetics, calibrated against active sampling, and finally tested in the field. The airflow volume passing the sampler was linearly proportional to ambient wind speed and sensitive to wind direction. The uptake rate for an individual PAH was a function of airflow velocity, temperature and the octanol-air partitioning coefficient of the PAH. For all PAHs with more than two rings, the passive sampler operated in a linear uptake phase for three weeks. Different PAH concentrations were obtained in air masses from different directions in the field test. 相似文献
53.
重金属污染土壤接种丛枝菌根真菌对蚕豆毒性的影响 总被引:6,自引:1,他引:5
采用盆栽实验的方法,研究了重金属(包括Cu、Zn、Pb和Cd)复合污染和接种丛枝菌根真菌(arbuscular mycorrhizal fungi,AMF)Glomus mosseae对蚕豆(Vicia faba)生长及DNA损伤的影响.结果表明,虽然接种菌根真菌对蚕豆生物量的影响并不显著,但是却显著影响植物对重金属的吸收,接种菌根真菌对蚕豆吸收4种重金属元素的作用有差异.采用单细胞凝胶电泳(single cell gel electrophoresis,SCGE)法研究接种菌根真菌对蚕豆叶片的DNA损伤的影响,与重金属吸收的结果相吻合.结果表明,接种处理可显著增加蚕豆叶片的DNA损伤程度,这与接种处理可提高植物的重金属吸收相一致. 相似文献
54.
水安全危机是人类进入新世纪以来在生存及发展方面所面临的最严重挑战之一。研究科学合理的水安全战略成为区域可持续发展的重大课题。针对区域水战略问题涉及众多因素且各因素之间动态关联的特点,提出了基于水战略方案优选的兼容度极大化动态组合评价模型(CMM—DCEM),并将其成功地应用于我国广东省北江下游及其三角洲地区水安全战略方案优选评价。评价结果及模型基于不确定性的敏感性分析结果证明:CMM—DCEM实现了主、客观赋权方法以及单一评价模型的融合,使用实码加速遗传算法求解目标函数,克服了传统的组合评价方法计算繁琐的不足,评价过程更加科学合理。 相似文献
55.
56.
Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant 总被引:1,自引:0,他引:1
A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l−1 from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu3(HTDC)2]n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment. 相似文献
57.
汉江是长江一级支流,鱼类资源较为丰富。目前汉江中下游建有4座水利枢纽工程,对鱼类洄游和繁殖产生较大影响。在鱼类繁殖季节,为促进汉江中下游鱼类繁殖,2018年6月汉江中下游首次实施梯级联合生态调度。该研究在汉江下游汉川段设置监测断面,采集鱼类早期资源,以分析汉江下游鱼类早期资源多样性,及生态调度对促进汉江下游鱼类繁殖的效果。监测结果表明汉江下游卵苗种类共有36种(属),其中22种为产漂流性卵鱼类。监测期间卵苗总径流量为118.78亿尾(粒),其中四大家鱼卵苗为0.87亿尾(粒),占0.73%,其中鱼卵0.69亿粒,推测汉江下游有4处四大家鱼产卵场。梯级联合生态调度期间,汉川江段出现一次鱼类产卵高峰,鱼卵径流量占总径流量的34.1%,其中四大家鱼鱼卵占家鱼卵总径流量的85.5%,表明梯级联合生态调度对汉江下游鱼类,特别是四大家鱼的繁殖具有积极的作用。建议今后继续开展生态调度,并加强监测和分析工作。 相似文献
58.
Pollution characteristics of 23 veterinary antibiotics in livestock manure and manure-amended soils in Jiangsu province,China 总被引:3,自引:0,他引:3
Xin Y. Guo Li J. Hao Pan Z. Qiu Rong Chen Jing Xu Xiang J. Kong 《Journal of environmental science and health. Part. B》2016,51(6):383-392
The aim of this study was to investigate the pollution characteristics of typical veterinary antibiotics in manure and soil of livestock farms in Jiangsu province. This investigation employed solid-phase extraction (SPE) coupled with ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). A total of 53 manure and 50 amended soil samples from 16 livestock farms in Jiangsu province were collected for analysis. In the manure samples, the highest detected frequencies and concentrations were those of tetracyclines (TCs, 54.1 ± 5775.6 μgkg?1), followed by fluoroquinolones (FQs, 8.4 ± 435.6 μgkg?1), sulphonamides (SAs, 3.2 ± 5.2 μgkg?1) and macrolides (MACs, 0.4 ± 110.5 μgkg?1). Statistical analysis was used to illuminate the pollution characteristics of 23 veterinary antibiotics for various animal types and different regions in Jiangsu province. The results showed that the pollution level in cow manure was relatively lower compared with pig and chicken manure due to the relative restriction of medication. Furthermore, contamination was serious in amended soil from chicken farms. The pollution level in manure among different regions was higher to the south and north compared with the centre of the region. The same outcome was found for soil. Antibiotic residues in organic fertilizer were also investigated in this study. We found that although the detected concentration was lower in organic fertilizer than in fresh manure, detection frequencies (10–90%) were high, especially for roxithromycin (90%) in MACs (30–90%). This finding suggests attention should be paid to the pollution levels in organic fertilizer. This study is the first extensive investigation of the occurrence and distribution of many kinds of typical veterinary antibiotics in manure and soil from livestock farms of Jiangsu province. This investigation systematically assesses veterinary antibiotics usage and related emissions in southeast China. 相似文献
59.
TRMM 3B42卫星降水数据在赣江流域径流模拟中的应用 总被引:1,自引:0,他引:1
以赣江流域为研究区,基于观测降水和TRMM准实时数据(3B42RTV6、3B42RTV7)和分析数据(3B42V6、3B42V7),驱动VIC水文模型,开展卫星降水产品在赣江流域的水文模拟,评估TRMM降水产品在水文模拟中的应用能力。结果表明:(1)在赣江流域,3B42V7估算的降水与实测降水的对比结果最好,3B42RTV6的估算精度最低,3B42RTV7较3B42RTV6在赣江流域的降水估算精度提升非常明显;(2)在径流模拟方面,3B42V6和3B42V7在日尺度上尽管对洪峰的模拟有所偏差,但模拟结果仍能反映径流变化特征,在月尺度上模拟结果精度较高,纳什系数均在0.9以上,并且二者在4、5月的径流模拟结果较好,7、8月的模拟结果较差,而3B42RTV6对径流的模拟能力较差,日径流量和月径流量均呈现明显低估,3B42RTV7对径流的模拟结果比3B42RTV6有明显改善,可以满足实时水文预报的需求。 相似文献
60.
为深入研究流场动力学特性对浸没式膜生物反应器系统内膜面污染的控制,应用fluent软件对浸没式膜生物反应器内气液两相流动进行了三维数值模拟研究。采用标准k-ε湍流模型和欧拉多相流模型,考察了改变曝气条件对膜面气液速度场及气含率分布的影响。模拟结果表明,在相同曝气强度下,1 mm曝气孔径下膜面气液两相的速度增加较孔径2mm、3 mm的快;曝气孔径为1 mm时,膜面的液相速度随着曝气强度的增加逐渐增大;曝气孔径为1 mm时,曝气量为5.5m3/h所形成的漩涡区较大,膜面气含率值较高且分布较均匀,气液两相接触面积较大,膜面冲刷效果较好;模拟观察到反应器底部靠近壁面局部气含率较低,不利于活性污泥中微生物的生长,需要进一步优化曝气和反应器结构。 相似文献