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Although microbial treatments of heavy metal ions in wastewater have been studied, the removal of these metals through incorporation into carbonate minerals has rarely been reported. To investigate the removal of Fe^3+ and Pb^2+, two representative metals in wastewater, through the precipitation of carbonate minerals by a microbial flocculant (MBF) produced by Bacillus mucilaginosus. MBF was added to synthetic wastewater containing different Fe^3+ and Pb^2+ concentrations, and the extent of flocculation was analyzed. CO2 was bubbled into the mixture of MBF and Fe^3+/Pb^2+ to initiate the reaction. The solid substrates were analyzed via X-ray diffraction, transmission electron microscopy and energy dispersive spectroscopy. The results showed that the removal efficiency decreased and the MBF adsorption capacity for metals increased with increasing heavy metal concentration. In the system containing MBF, metals (Fe^3+ and Pb^2+), and CO2, the concentrated metals adsorbed onto the MBF combined with the dissolved CO2, resulting in oversaturation of metal carbonate minerals to form iron carbonate and lead carbonates. These results may be used in designing a method in which microbes can be utilized to combine CO2 with wastewater heavy metals to form carbonates, with the aim of mitigating environmental problems. 相似文献
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Shiming Ding Di Xu Xiuling Bai Shuchun Yao Chengxin Fan Chaosheng Zhang 《环境科学学报(英文版)》2013,25(5):925-932
The understanding of organic phosphorus(P) dynamics in sediments requires information on their species at the molecular level,but such information in sediment profiles is scarce.A sediment profile was selected from a large eutrophic lake,Lake Taihu(China),and organic P species in the sediments were detected using solution phosphorus-31 nuclear magnetic resonance spectroscopy(31 P NMR) following extraction of the sediments with a mixture of 0.25 mol/L NaOH and 50 mmol/L EDTA(NaOH-EDTA) solution.The results showed that P in the NaOH-EDTA extracts was mainly composed of orthophosphate,orthophosphate monoesters,phospholipids,DNA,and pyrophosphate.Concentrations of the major organic P compound groups and pyrophosphate showed a decreasing trend with the increase of depth.Their half-life times varied from 3 to 27 years,following the order of orthophosphate monoesters > phospholipids DNA > pyrophosphate.Principal component analysis revealed that the detected organic P species had binding phases similar to those of humic acid-associated organic P(NaOH-NRP HA),a labile organic P pool that tends to transform to recalcitrant organic P pools as the early diagenetic processes proceed.This demonstrated that the depth attenuation of the organic P species could be partly attributed to their increasing immobilization by the sediment solids,while their degradation rates should be significantly lower than what were suggested in previous studies. 相似文献
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突发公共事件表现出了强烈的损失发生不确定性,企业或政府单位应主动地认识突发公共事件风险,积极管理突发公共事件风险,有效地控制突发公共事件风险,把突发公共事件风险减至最低的程度,实行突发公共事件全过程风险管理.本文主要介绍了突发公共事件风险管理的主要程序和重要内容. 相似文献
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OBJECTIVE: The aim of this study was to investigate head injuries, injury risks, and corresponding tolerance levels of children in car-to--child pedestrian collisions. METHODS: An in-depth accident analysis was carried out based on 23 accident cases involving child pedestrians. These cases were collected with detailed information about pedestrians, cars, and road environments. All 23 accidents were reconstructed using the MADYMO program with mathematical models of passenger cars and child pedestrians developed at Chalmers University of Technology. The contact properties of the car models were derived from the European New Car Assessment Program (EuroNCAP) subsystem tests. RESULTS: The accident analysis demonstrated that the head was the most frequently and severely injured body part of child pedestrians. Most accidents occurred at impact speeds lower than 40 km/h and 98% of the child pedestrians were impacted from the lateral direction. The initial postures of children at the moment of impact were identified. Nearly half (47%) of the children were running, which was remarkable compared with the situation of adult pedestrians. From accident reconstructions it was found that head impact conditions and injury severities were dependent on the shape and stiffness of the car front, impact velocity, and stature of the child pedestrian. Head injury criteria and corresponding tolerance levels were analyzed and discussed by correlating the calculated injury parameters with the injury outcomes in the accidents. CONCLUSIONS: Reducing head injuries should be set as a priority in the protection of child pedestrians. HIC is an important injury criterion for predicting the risks of head injuries in child pedestrian accidents. The tolerance level of head injuries can have a considerable variation due to individual differences of the child pedestrians. By setting a suitable speed limit and improving the design of car front, the head injury severities of child pedestrians can be reduced. 相似文献
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地表UV-B辐射增强对土壤-冬小麦系统呼吸速率和N2O排放的影响 总被引:1,自引:0,他引:1
通过室外盆栽实验,用静态箱-气相色谱法测定土壤-冬小麦系统的呼吸速率和N2O排放通量,研究了UV-B辐射增强20%对土壤-冬小麦系统的呼吸速率和N2O排放的影响.结果表明,相同的气象条件和田间管理下,UV-B辐射增强处理对呼吸速率和N2O排放的季节变化模式无明显影响.在返青期,UV-B辐射增强显著降低了土壤-冬小麦系统的呼吸速率,但对N2O的排放通量没有产生显著影响;在拔节孕穗期,UV-B辐射增强处理显著降低了土壤-冬小麦系统的呼吸速率和N2O的排放通量;在抽穗-成熟期,UV-B辐射增强处理对土壤-冬小麦系统的呼吸速率和N2O的排放没有显著影响.返青-齐穗期,UV-B增强处理显著降低土壤-冬小麦系统的N2O累积排放量;但从齐穗开始至小麦成熟,UV-B增强处理对土壤-冬小麦系统的N2O累积排放量没有显著影响. 相似文献