高效液相色谱法测定南昌市环境空气PM10中16种多环芳烃

建立了以二极管阵列检测器和荧光检测器串联的高效液相色谱分析方法,在标样未完全分离的情况下,采用双激发波长有效地改善了色谱分离条件.在设定的色谱条件下,各种多环芳烃(PAHs)的检出限为0.11～39.83μg/L,平均回收率为76.7%～98.3%,相对标准偏差为3.6%～12.6%.在南昌市布设4个环境空气采样点,测定PM10中PAHs含量.结果表明,八一广场、南昌市区二中老校区和罗家集区苯并(a)芘日均质量浓度最大值均超过<环境空气质量标准>(GB 3095-1996)的限值,PAHs污染状况较严重.     

Effects of open burning of rice straw on concentrations of atmospheric polycyclic aromatic hydrocarbons in central Taiwan

The sizes and concentrations of 21 atmospheric polycyclic aromatic hydrocarbons (PAHs) were measured at Jhu-Shan (a rural site) and Sin-Gang (a town site) in central Taiwan in October and December 2005. Air samples were collected using semi-volatile sampling trains (PS-1 sampler) over 16 days for rice-straw burning and nonburning periods. These samples were then analyzed using a gas chromatograph with a flame-ionization detector (GC/FID). Particle-size distributions in the particulate phase show a bimode, peaking at 0.32-0.56 microm and 3.2-5.6 microm at the two sites during the nonburning period. During the burning period, peaks also appeared at 0.32-0.56 microm and 3.2-5.6 microm at Jhu-Shan, with the accumulation mode (particle size between 0.1 and 3.2 microm) accounting for approximately 74.1% of total particle mass. The peaks at 0.18-0.32 microm and 1.8-3.2 microm at Shin-Gang had an accumulation mode accounting for approximately 70.1% of total particle mass. The mass median diameter (MMD) of 3.99-4.35 microm in the particulate phase suggested that rice-straw burning generated increased numbers of coarse particles. The concentrations of total PAHs (sum of 21 gases + particles) at the Jhu-Shan site (Sin-Gang site) were 522.9 +/- 111.4 ng/ml (572.0 +/- 91.0 ng/ml) and 330.1 +/- 17.0 ng/ml (or 427.5 +/- 108.0 ng/ml) during burning and nonburning periods, respectively, accounting for a roughly 58% (or 34%) increase in the concentrations of total PAHs due to rice-straw burning. On average, low-weight PAHs (about 87.0%) represent the largest proportion of total PAHs, followed by medium-weight PAHs (7.1%), and high-weight PAHs (5.9%). Combustion-related PAHs during burning periods were 1.54-2.57 times higher than those during nonburning periods. The results of principal component analysis (PCA)/absolute principal component scores (APCS) suggest that the primary pollution sources at the two sites are similar and include vehicle exhaust, coal/wood combustion, incense burning, and incineration emissions. Open burning of rice straw was estimated to contribute approximately 5.0-33.5% to the total atmospheric PAHs at the two sites.     

锌精炼铅塔燃烧系统烟气温度模糊控制研究

针对锌精馏铅塔动态过程中的非线性、非最小相位特征、不稳定性、时滞和负荷干扰,基于模糊控制策略下给出了锌精馏铅塔燃烧系统新的控制方法.运用模糊控制系统对锌精馏铅塔的烟气温度进行仿真研究和实时控制结果表明,该研究所设计的模糊控制器能够克服许多干扰因素,产生了良好的控制效果.     

A2/O工艺中的反硝化除磷

A2/O工艺是一种最简单的同步脱氮除磷工艺,但由于其系统中固有的基质竞争和污泥龄等矛盾,在实际应用中特别是处理低C/N比污水时脱氮除磷效率较低.反硝化除磷工艺作为近年来颇受关注的污水生物处理新技术.由于在脱氮除磷过程中可以在碳源利用上耦合,可从一定程度上缓解A2/O工艺中的基质竞争矛盾,使得其在处理低C/N比污水时也能实现较高的脱氮除磷效率.就反硝化除磷的技术原理,结合其在A2/O工艺中的最新研究成果及其控制策略,对A2/O工艺中的反硝化除磷的实现、维持及影响因素进行了分析和探讨,并对其发展方向进行了展望.     

Non-microcystin producing Microcystis wesenbergii (Komárek) Komárek (Cyanobacteria) representing a main waterbloom-forming species in Chinese waters

It is well known that several morphospecies of Microcystis, such as Microcystis aeruginosa (Kützing) Lemmermann and Microcystis viridis (A. Brown) Lemmermann can produce hepatotoxic microcystins. However, previous studies gave contradictory conclusions about microcystin production of Microcystis wesenbergii (Komárek) Komárek. In the present study, ten Microcystis morphospecies were identified in waterblooms of seven Chinese waterbodies, and Microcystis wesenbergii was shown as the dominant species in these waters. More than 250 single colonies of M. wesenbergii were chosen, under morphological identification, to examine whether M. wesenbergii produce hepatotoxic microcystin by using multiplex PCR for molecular detection of a region (mcyA) of microcystin synthesis genes, and chemical analyses of microcystin content by ELISA and HPLC for 21 isolated strains of M. wesenbergii from these waters were also performed. Both molecular and chemical methods demonstrated that M. wesenbergii from Chinese waters did not produce microcystin.     

压力式接触氧化法同步硝化反硝化脱氮性能研究

研究了压力式接触氧化法的脱氮性能,分析了容积负荷、溶解氧和停留时间等因素对反应器脱氮效果的影响.研究表明,压力式接触氧化法具有明显的同步硝化反硝化现象,当HRT=1.8 h时,DO高达5.4 mg/L,可获得90%以上的反硝化率.当HRT=1.8 h,溶解氧4～5 mg/L,容积负荷为10～12 kg COD/(m3·d)时,氨氮去除率80%左右,总氮去除率达70%～80%.     

四川汶川8．0级地震典型遗址遗迹综合评估

简要介绍了四川汶川8.0级地震现场考察的有关情况,然后重点对地震典型遗址、遗迹的综合评估原则进行了详细研究,并在此基础上设计出综合评估量表.最后,对北川、映秀等典型地震遗址、遗迹进行了综合评估,并提出了保护建议.     

基于FDS仿真火灾温度下隧道衬砌安全评估

为了研究火灾下隧道衬砌的安全性,首先采用火灾模拟软件FDS4．0模拟不同规模的火灾：通过许多小的长方体堆砌建立隧道的实体模型,并采用FDS4．0中的多重网格技术（Multiple Meshes）进行网格划分;然后结合仿真得到横断面的温度场与相应温度下的材料参数,应用荷载一结构模式（即直刚法）对二次衬砌的安全性进行评估。结果表明：小规模火灾下（〈20MW）,衬砌的安全性能够得到满足,在较大火灾规模下（≥20MW）,拱顶的安全性得不到满足,而其余部位的安全性满足要求;随着火灾规模的增大,衬砌安全系数逐渐降低,拱顶的安全系数降低梯度最大。最后,对衬砌的耐火措施提出了一些建议。     

西安市地面沉降成因机理中的若干问题探讨

针对西安市区的地质环境和地面沉降特征,总结国内外与此相关的研究成果,重点从土层渗流与变形特性、地面沉降和地裂缝的关系、下部地层压密与地面变形关系以及开采地热资源对地面沉降的影响等几个方面分析西安市区地面沉降研究的现状及存在的问题,并针对这些问题提出了几点建议.     

汶川地震灾区过渡房安置点场地选择中的地震问题

大地震后,如何在最短的时间内在灾区选择比较安全的过渡房安置点建设场地,是一项具有挑战性的工作。本文以四川省汶川8.0级大地震后灾区群众快速安置为背景,论述了选择过渡房安置点场地必须考虑的地震问题,并提出了处理地震断层、地表裂缝、砂土液化、坍塌等实际问题的方案;利用强余震的预测结果,分析了这些灾害对场地可能造成的危害;同时对可能潜在的滑坡、危岩崩塌、泥石流等地质灾害提出相应的处理建议,供安置点规划建设参考。