高浓度硫酸盐核黄素生产废水处理的应用研究

介绍了硫酸盐还原+生物脱硫+气浮+UASB+CASS工艺处理高硫酸盐核黄素生产废水的应用实例。对设计工艺流程、主要参数、调试与运行情况以及处理效果作了说明。该组合工艺对核黄素生产废水中的COD、SO24-具有很好的去除效果,出水各指标达到GB8978-1996《污水综合排放标准》三级标准。     

西樵山国家森林公园有害植物现状分析

结合西樵山国家森林公园管理公司提供的植被及道路图,运用面上调查和点调查相结合的方法对西樵山国家森林公园的有害植物进行了系统和全面的调查,对西樵山国家森林公园的有害植物危害现状进行了分析.调查结果显示,西樵山国家森林公同有害植物共有25种,录属19科25属,包括本地种20种,外来种5种,达到严重危害的有19种.本地植物成灾面积达56万m2,外来植物成灾面积14万m2,本地植物与外来植物的成灾比例是4:1.针对主要的15种有害植物,对其分布、危害面积与危害特点进行了逐一分析与描述.根据西樵山国家森林公园有害植物的危害现状的分析,本地植物的危害程度和范围都比外来植物大得多,并分析了西樵山国家森林公园有害植物的发展趋势.     

黄河三角洲滨海湿地的维管束植物区系特征

在2007-2008年多次实地调查并参照相关资料基础上,对黄河三角洲滨海湿地进行了植被类型划分和湿地维管束植物生态类群、生活型划分,利用统计方法分析了研究区湿地维管束植物区系的科、属构成,地理分布区成分构成.研究表明,黄河三角洲滨海湿地有71科、199属、298种维管束植物,蓼科、藜科、苋科、豆科、菊科、禾本科、莎草科等7个大科为区系主体,上述7科共76属128种,占总属数的39.38%和总种数的43.99%;区系中单种属多,属的分化程度较高.区系中有59种盐生植物、46种水生植物、44种湿生植物、144种中生植物、7种旱生植物,水生植物、湿生植物的生活型以地面芽植物、地下芽植物为主,陆地中生植物、盐生植物的生活型以一年生植物为主.从分布区类型构成来看,区系中蕨类植物区域分布成分较多,种子植物中温带分布属最多,这反映出湿地植被具有一定的地带性特征,种子植物中热带分布属、世界分布属较多分别表明海洋性气候对湿地植被特征的影响及湿地植被的隐域性特征.     

放牧对祁连山高寒金露梅灌丛草甸土壤环境的影响

以祁连山北支冷龙岭东段南麓的干柴滩夏季牧场集体长期混合(藏系绵羊、牦牛)放牧的高寒金露梅Potentilla froticosa灌丛草场为对象,利用空间分布代替时间演替的方法,采用方格网法取样分析,研究了土壤容重、土壤水分、土壤养分等的变化,结果表明:随着放牧压力梯度的增加,灌丛斑块和丛间草地斑块0～10 cm土层密度显著增加、毛管孔度下降显著,而10～20 cm土层的变化不显著.随放牧压力梯度的增加,土壤水分减少,金露梅灌丛0～10 cm土壤水分低于10～25 cm土层的,而丛间草地的相反.随着放牧压力梯度的增加,金露梅灌丛和丛间草地的土壤水分逐渐减少.随放牧压力梯度的增加,0～25 cm土层的土壤有机质由108.73 mg·g-1下降到80.30 mg·g-1;金露梅灌丛和丛间草地0～10 cm土壤全氮、全磷均显著降低,其中全氮平均降幅达17.07%,全磷平均降幅为29.14%,而10～25 cm土层的全氮、全磷变化不显著;放牧使土壤速效钾显著增加,其中丛间草地的增幅是41.9%,灌丛的增幅为30.18%;放牧使0～10 cm土壤pH值显著升高,对丛间草地的pH值影响比灌丛的大.     

Inhibition of bromate formation by reduced graphene oxide supported cerium dioxide during ozonation of bromide-containing water

GO or RGO promotes bromate formation during ozonation of bromide-containing water. CeO₂/RGO significantly inhibits bromate formation compared to RGO during ozonation. CeO₂/RGO shows an enhancement on DEET degradation efficiency during ozonation. Ozone (O₃) is widely used in drinking water disinfection and wastewater treatment. However, when applied to bromide-containing water, ozone induces the formation of bromate, which is carcinogenic. Our previous study found that graphene oxide (GO) can enhance the degradation efficiency of micropollutants during ozonation. However, in this study, GO was found to promote bromate formation during ozonation of bromide-containing waters, with bromate yields from the O₃/GO process more than twice those obtained using ozone alone. The promoted bromate formation was attributed to increased hydroxyl radical production, as confirmed by the significant reduction (almost 75%) in bromate yield after adding t-butanol (TBA). Cerium oxide (less than 5 mg/L) supported on reduced GO (xCeO₂/RGO) significantly inhibited bromate formation during ozonation compared with reduced GO alone, and the optimal Ce atomic percentage (x) was determined to be 0.36%, achieving an inhibition rate of approximately 73%. Fourier transform infrared (FT-IR) spectra indicated the transformation of GO into RGO after hydrothermal treatment, and transmission electron microscope (TEM) results showed that CeO₂ nanoparticles were well dispersed on the RGO surface. The X-ray photoelectron spectroscopy (XPS) spectra results demonstrated that the Ce³⁺/Ce⁴⁺ ratio in xCeO₂/RGO was almost 3‒4 times higher than that in pure CeO₂, which might be attributed to the charge transfer effect from GO to CeO₂. Furthermore, Ce³⁺ on the xCeO₂/RGO surface could quench Br⋅ and BrO⋅ to further inhibit bromate formation. Meanwhile, 0.36CeO₂/RGO could also enhance the degradation efficiency of N,N-diethyl-m-toluamide (DEET) in synthetic and reclaimed water during ozonation.     

3种抗生素对黑麦草种子萌发的生态毒性效应

为探明四环素、环丙沙星和磺胺嘧啶3种抗生素对黑麦草种子萌发的影响,为评价抗生素污染的生态影响提供科学依据,采用保湿培养法研究了它们对黑麦草种子萌发的影响,比较分析了抗生素的生态毒性差异和相对敏感的指标。结果表明,在种子萌发期,一定浓度范围的抗生素胁迫会引发植物种子抵抗逆境的应激反应,因此,3种抗生素在1 mg·L~(-1)处理水平下均能促进种子发芽。超过该浓度,四环素对黑麦草种子发芽仍有一定的促进作用,而环丙沙星和磺胺嘧啶则表现为抑制作用。四环素对种子发芽率的最大无作用浓度(NOEC)为5 mg·L~(-1),而环丙沙星和磺胺嘧啶对种子发芽率的NOEC为1 mg·L~(-1)。实验结束时,3种抗生素在1 mg·L~(-1)处理水平下的种子发芽率最高。3种抗生素浓度超过0.1 mg·L~(-1)时,种子根长和芽长即受到抑制,因此,它们对种子根长和芽长的NOEC均为0～0.1 mg·L~(-1)。其中,磺胺嘧啶的抑制作用最为显著。根长受到抑制的程度强于芽长。黑麦草种子萌发受3种抗生素影响程度依次为磺胺嘧啶环丙沙星四环素。     

基于模糊数学的火灾安全综合评价模型及应用

火灾每年给我国带来巨大的经济损失和人员伤亡,甚至造成严重的社会影响。基于模糊数学理论和综合评价模型的建模方法,给出火灾危险性的安全综合评价模型,由应用结果可看出该模型简单、易懂,应用方便。对企业的火灾危险性评价可以起到预防火灾的作用。     

基于离散元法的能源管传热过程模拟

采用自主研发的离散元软件MatDEM,依据能源管桩的现场热响应试验,提出了能源桩离散元数值模拟的建模方法,对能源管桩的热响应试验过程进行了模拟研究,得到了桩周土体的位移分布,桩芯和桩周土体的温度分布,通过与现场实测数据的对比,验证了利用离散元法研究能源桩换热性能的有效性,该方法在研究能源桩与土体的热-力学行为特征方面具有广阔的应用前景。     

典型喀斯特高原水库浮游植物与环境因子的关系

浮游植物的生长往往受多种环境因素共同作用,独特的地理特征也是影响其密度与群落结构变化的要素之一。为探索喀斯特高原水库浮游植物与环境因子的耦合关系,以贵州省典型喀斯特高原水库——阿哈水库为例,于2019年春(4月)、夏(7月)、秋季(10月)对水库各支流及库中心区域进行采样调查,探究了喀斯特水库基础水环境指标的量级、浮游植物群落组成、优势种变化及其密度的时空分布,进一步揭示浮游植物与环境因子的耦合关系,为喀斯特高原水库浮游植物研究以及水资源保护提供一定的科学依据。结果显示,阿哈水库浮游植物密度在3.95×10⁴-525.35×10⁴cells·L^?1,之间,以蓝藻、硅藻、绿藻、隐藻居多,伪鱼腥藻(Pseudoanabaena sp.)、水华束丝藻(Aphanizomenon flos-aquae)为主要优势种。单因素方差分析(One-way ANOVA)结果表明,浮游植物密度的季节性差异显著(P<0.01),呈夏季>春季>秋季的趋势。由一元线性回归分析可知,在春季,浮游植物密度与溶解氧、pH、钙离子浓度呈极显著线性相关(P<0.01),与透明度、氮磷比具有显著相关关系(P<0.05);然而,浮游植物密度仅与夏季的透明度关系显著(P<0.05),与秋季的所有环境因子均无显著相关关系(P>0.05)。由冗余分析(RDA)可知,影响春季浮游植物群落结构的主要环境因子为pH、钙离子浓度和总磷,夏季为透明度、总磷和氮磷比。秋季浮游植物群落结构可能受低温影响较大。     

Electro-catalytic activity of CeOx modified graphite felt for carbamazepine degradation via E-peroxone process

•CeO_x/GF-EP process had the better degradation efficiency than GF-EP process. •CeO_x/GF-EP process had the flexible application in the pH range from 5.0 to 9.0. •CeO_x could enhance surface hydrophilicity and reduce the charge-transfer resistance. •The interfacial electron transfer process was revealed. E-peroxone (EP) was one of the most attractive AOPs for removing refractory organic compounds from water, but the high energy consumption for in situ generating H₂O₂ and its low reaction efficiency for activating O₃ under acidic conditions made the obstacles for its practical application. In this study, cerium oxide was loaded on the surface of graphite felt (GF) by the hydrothermal method to construct the efficient electrode (CeO_x/GF) for mineralizing carbamazepine (CBZ) via EP process. CeO_x/GF was an efficient cathode, which led to 69.4% TOC removal in CeO_x/GF-EP process with current intensity of 10 mA in 60 min. Moreover, CeO_x/GF had the flexible application in the pH range from 5.0 to 9.0, TOC removal had no obvious decline with decrease of pH. Comparative characterizations showed that CeO_x could enhance surface hydrophilicity and reduce the charge-transfer resistance of GF. About 5.4 mg/L H₂O₂ generated in CeO_x/GF-EP process, which was 2.1 times as that in GF-EP process. The greater ozone utility was also found in CeO_x/GF-EP process. More O₃ was activated into hydroxyl radicals, which accounted for the mineralization of CBZ. An interfacial electron transfer process was revealed, which involved the function of oxygen vacancies and Ce³⁺/Ce⁴⁺ redox cycle. CeO_x/GF had the good recycling property in fifth times’ use.