钢渣吸附剂吸附机理的研究

采用间歇振荡法,研究了钢渣吸附模式、选择性以及等温吸附方程。结果表明,钢渣对阳离子的吸附容量远远大于对阴离子的吸附容量,其吸附模式属于离子交换;其对重金属离子具有一定的吸附选择性,其选择性能与离子的电性、电价、离子半径和水化热等因素有关;钢渣吸附Pb2＋是单层吸附,符合Langmuir等温吸附方程。     

浑河沈阳段污水排放口最优规划研究

针对沈阳市经济发展和污染加剧的特点,为合理充分利用浑河水环境容量,节约投资,建立了浑河沈阳段主要排污口最优化模型,并应用分段线性化对该模型进行了线性化,进而确定排污口最优化线性模型,最后通过M atlab软件求解出各排放口的污水允许排放浓度及最低的处理费用。     

太湖沉积物好氧细菌空间分布与氮磷来源及风险

沉积物中氮磷释放到湖水中会加剧湖泊的富营养化,危害生态安全和人类健康.微生物在氮磷转换中不可或缺,准确分析沉积物中氮磷分布特征和来源以及与微生物的关系是湖泊富营养化管控的重要前提.以太湖为研究区,采集30个表层沉积物样品,测定并分析了粒度、pH、有机质（OM）、溶解性有机碳（DOC）、全磷（TP）、全氮（TN）、硝态氮（NO₃^--N）和溶解性有机氮（DON）等指标含量及空间分布特征,同时利用营养琼脂（NA）培养基以平板计数法测定好氧细菌（AB）数量.结合主成分分析（PCA）和Pearson相关分析探究了太湖沉积物和AB空间分布特征和来源.采用综合污染指数法和有机污染指数法研究了太湖沉积物污染特征.结果表明,太湖表层沉积物指标平均值如下：AB为9.25×10⁴ CFU ·g^-1,平均粒径（M_Z）为17.59 μm,pH为7.62,ω（OM）为15.05g ·kg^-1,ω（DOC）为71.60mg ·kg^-1,ω（TP）为598.13mg ·kg^-1,ω（TN）为1113.92 mg ·kg^-1,ω（NO₃^--N）为3.22mg ·kg^-1,ω（DON）为22.60mg ·kg^-1.综合污染指数（FF）显示太湖中的点位13%为中度污染,87%为重度污染.TN除在湖心区、南部湖区和东太湖西部的部分湖区为轻度污染外,其余区域为中重度污染.除竺山湾为重度污染外,太湖中TP整体上为轻中度污染.有机污染指数（OI）表明,太湖沉积物有机污染较轻,主要与有机氮（ON）污染有关.太湖中DOC、DON、TN和OM主要来源于水生植物的影响,TP和AB主要来源于河流外源输入的影响.研究将为湖泊富营养化治理提供理论支撑,也为进一步研究AB去除沉积物中氮磷污染提供新思路.     

Application of China’s National Forest Continuous Inventory Database

The maintenance of a timely, reliable and accurate spatial database on current forest ecosystem conditions and changes is essential to characterize and assess forest resources and support sustainable forest management. Information for such a database can be obtained only through a continuous forest inventory. The National Forest Continuous Inventory (NFCI) is the first level of China’s three-tiered inventory system. The NFCI is administered by the State Forestry Administration; data are acquired by five inventory institutions around the country. Several important components of the database include land type, forest classification and ageclass/ age-group. The NFCI database in China is constructed based on 5-year inventory periods, resulting in some of the data not being timely when reports are issued. To address this problem, a forest growth simulation model has been developed to update the database for years between the periodic inventories. In order to aid in forest plan design and management, a three-dimensional virtual reality system of forest landscapes for selected units in the database (compartment or sub-compartment) has also been developed based on Virtual Reality Modeling Language. In addition, a transparent internet publishing system for a spatial database based on open source WebGIS (UMN Map Server) has been designed and utilized to enhance public understanding and encourage free participation of interested parties in the development, implementation, and planning of sustainable forest management.     

Location set covering for waste resource recycling centers in Taiwan

The efficiency of Taiwan's waste management and resource recycling systems has been well recognized in recent years, but the present model used to locate recycling centers and to assign collection depots to those centers continues to show low efficiency. To address this issue, the study herein suggests implementing a new location-planning and assignment model to reduce the number of existing recycling centers. Such a reduction would reduce the use of land resources. Moreover, the total transportation distance would decrease through the efficient assignment of collection depots to recycling centers. On the basis of results from previous studies, this study proposes a 2-stage location set covering problem-P-median integrated model that obtains exact solutions using heuristic algorithms on the basis of set operations. The results of numerical analyses show that the model introduced in this study is effective in solving the problems stated above as well as in improving the layout of Taiwan's existing recycling centers.     

有风条件下剧院火灾自然排烟效果分析

为研究某剧院休息厅的自然排烟效果的问题,根据建筑特征设计6个火灾场景。运用理论计算和数值模拟的方法,分别研究不同开窗位置、开窗面积以及环境风速对火灾时的热流场和烟气蔓延的影响。结果表明：不同开窗位置达到临界值的时间为顶窗〉东西立面侧窗〉北立面侧窗;有风条件下3.5%的开窗面积的排烟效果和无风时6%的开窗面积的排烟效果相当。结论是考虑当地环境风速,选择顶部5%和东西侧3.5%开窗方式,增强该剧院的自然排烟效果。     

大空间建筑烟气填充研究方法的对比

为了对大空间建筑烟气填充研究方法进行对比分析。以一个废弃的大空间仓库为研究对象,采用了全尺寸火灾实验、计算机数值模拟和理论分析相互应用验证的研究方法,研究理论及数值模拟两种火灾烟气层高度的描述方法的准确性。结果表明当采用t2火模型时,在与现实的吻合程度方面,数值模拟〉Zukoski理论模型〉Yamana-Tanaka理论模型;随着火灾的不断发展,相对误差逐渐增大。通过对比分析发现,全尺寸实验、理论模型和数值模拟三种方法相互验证可以更好地保证研究的准确性;总结得到了两种与现实较吻合的描述烟气层高度的理论方法,并且提出减小误差应注意的几点事项,包括尽可能提高火源热释放速率、烟气层温度描述的准确性;不考虑火源热量通过建筑边界结构散失等。     

Stereoselective toxicity of malathion and its metabolites, malaoxon and isomalathion

In recent years, the stereoselective toxicity of chiral organophosphorus pesticides has received increasing attention from environmental toxicology scientists. In an attempt to explore the stereoselective effects of chiral organophosphorus pesticides on non-target organisms and enzymes, this work investigated the stereoselective toxicity and inhibition of malathion, malaoxon and isomalathion on Daphnia magna and on acid α-naphthyl acetate esterase extracted from wheat flour, respectively. Toxicity differences were observed between the two enantiomers of malathion and malaoxon and among the four stereoisomers of isomalathion in the LC50 values on D. magna and the IC50 values on acid α-naphthyl acetate esterase. Enantiomers with (R)-configuration in all the tested compounds showed higher toxicity to D. magna than their (S)-forms and racemic forms. Racemic malaoxon and isomalathion showed the strongest inhibition on acid α-naphthyl acetate esterase compared to their respective enantiomers and stereoisomers.     

长株潭城市群核心区土地利用生态风险评价

随着长株潭城市群的快速发展,人类活动导致的土地利用结构及方式改变对生态环境构成了巨大压力。运用G IS和景观生态学方法的土地利用生态风险评价,以长株潭城市群核心区为研究区域,选择湘江岸线为典型样带,建立了基于源与汇景观功能的土地利用生态风险评价指标体系,并构建了评价模型,对生态风险进行了空间分析和综合评价。结果表明,长沙市建成区的土地利用生态风险指数整体最高,株洲和湘潭居次。其中,从城市群建成区向外,风险指数逐渐降低,长沙、株洲、湘潭三市交界处生态风险指数也较低。根据研究区域生态风险状况、变化和分布特征,提出了相应的风险调控策略和管理方法,为实现区域土地利用与生态、社会、经济的可持续发展提供决策依据。     

Effects of reductive inorganics and NOM on the formation of chlorite in the chlorine dioxide disinfection of drinking water

Chlorine dioxide (ClO₂) disinfection usually does not produce halogenated disinfection by-products, but the formation of the inorganic by-product chlorite (ClO₂^–) is a serious consideration. In this study, the ClO₂^– formation rule in the ClO₂ disinfection of drinking water was investigated in the presence of three representative reductive inorganics and four natural organic matters (NOMs), respectively. Fe²⁺ and S^2– mainly reduced ClO₂ to ClO₂^– at low concentrations. When ClO₂ was consumed, the ClO₂^– would be further reduced by Fe²⁺ and S^2–, leading to the decrease of ClO₂^–. The reaction efficiency of Mn²⁺ with ClO₂ was lower than that of Fe²⁺ and S^2–. It might be the case that MnO₂ generated by the reaction between Mn²⁺ and ClO₂ had adsorption and catalytic oxidation on Mn²⁺. However, Mn²⁺ would not reduce ClO₂^–. Among the four NOMs, humic acid and fulvic acid reacted with ClO₂ actively, followed by bovine serum albumin, while sodium alginate had almost no reaction with ClO₂. The maximum ClO₂^– yields of reductive inorganics (70%) was higher than that of NOM (around 60%). The lower the concentration of reductive substances, the more ClO₂^– could be produced by per unit concentration of reductive substances. The results of the actual water samples showed that both reductive inorganics and NOM played an important role in the formation of ClO₂^– in disinfection.