“2020年后国际化学品与废物健全管理框架”磋商进展及我国应对建议

国际化学品管理大会第四届会议(Fourth of the International Conference of Chemicals Management,ICCM4)通过第IV/4决议,建议考虑2020年后化学品与废物健全管理工作安排,并决定启动闭会期间进程,就国际化学品管理战略方针(Strategic Approach To International Chemicals Management,SAICM)及2020年后化学品与废物健全管理工作制定建议。“2020年后国际化学品与废物健全管理”是当前国际化学品管理战略闭会期间历次磋商进程谈判的重点,了解该框架的谈判进展及各方主要观点将对我国参与国际谈判产生积极作用。本文系统梳理了闭会期间历次磋商进程的主要内容,并对2020年后化学品与废物健全管理新框架文件涉及的愿景、原则和方法、战略目标和指标、体制安排和实施机制、财政考虑、高级别政治承诺等主要国家立场态度进行了观点综述。为应对国际谈判,建议我国采取以下措施推进国际谈判：做好国内发展趋势研判,积极参与谈判进程;建立协调机制,调动利益攸关方的积极性;加强知识信息共享,提升化学品管理能力;充分利用高级别会议,提升政治层面对2020年后框架的重视程度。     

Characterization and adsorption capacity of modified 3D porous aerogel from grapefruit peels for removal of oils and organic solvents

With the rapid industrialization, especially offshore oil exploitation, frequent leakage incidents of oils/organic solvents have adversely affected ecological systems and environmental resources. Therefore, great interest has been shown in developing new materials to eliminate these organic pollutants, which have become worldwide problems. In this study, a cost-effective, environmentally friendly porous aerogel with three-dimensional (3D) structure was prepared from grapefruit peel by a facile hydrothermal method as the adsorbent of oils/organic solvents. The as-prepared modified grapefruit peel aerogel (M-GPA) showed mesoporous structure with high specific surface area of 36.42 m²/g and large pore volume of 0.0371 cm³/g. The excellent hydrophobicity of M-GPA with a water contact angle of 141.2° indicated a strong potential for adsorption of oils and organic solvents. The high adsorption capacity of M-GPA for a series of oils and organic solvents was 8 to 52 times as much as its own weight. Moreover, the M-GPA was easily regenerated and a high adsorption capacity recovery above 97% was maintained after five adsorption–regeneration cycles. Therefore, the M-GPA is a promising recyclable adsorbent for the removal of oils/organic solvents from polluted water.

     

三峡工程运行前后荆江三口水文情势的变化

基于1980～2015年荆江三口五站逐日流量数据,采用IHA指标体系分析度量三峡工程运行前后荆江三口水文情势的变化。除新江口和弥陀寺在枯水期1～3月有小幅增长外,三口各站点月均流量值均减小,汛期下降幅度较大。最大日流量值持续下降,但2003年后变化趋势相对平缓。沙道观和管家铺站断流天数显著上升,各站流量变化率明显降低。荆江三口水文情势变化受长江干流径流量减少、径流过程改变以及干流与口门河段河道冲淤不一致的共同影响,对长江中游四大家鱼种群以及洞庭湖苔草草洲的发展产生一定负面作用。     

Fenton氧化-活性炭吸附协同深度处理垃圾渗滤液的研究

以上海某垃圾填埋场垃圾渗滤液为研究对象,采用Fenton氧化-活性炭吸附协同处理工艺对其处理效果进行研究。探讨了投加方式以及H2O2浓度、Fe2+浓度、活性炭投加量、温度、pH等因素对COD去除率的影响。结果表明:采用先投加活性炭吸附30 min后投加Fenton试剂反应150 min的方式能够获得最好的COD去除效果。正交实验表明各因素对COD去除的主次关系为:活性炭投加量Fe2+浓度反应温度H2O2浓度pH值;其最优化条件为:活性炭投加量为16g/L,Fe2+浓度为29 mmol/L,反应温度为60℃,H2O2浓度为78 mmol/L,pH值为3。     

工业废铝渣制备聚合硫酸铝及其絮凝性能研究

以一家金属材料厂生产过程中产生的废铝渣作为研究对象,通过对溶解条件和聚合工艺的优化,制备了聚合硫酸铝。将制备的聚合硫酸铝分别用于模拟浊度水及高色度高浓度有机工业废水的处理,实验结果表明,利用工业废渣所制得的聚合硫酸铝具有较好的除浊、脱色、去除COD效果。此工艺不仅可回收利用废铝渣,又可省去废渣处置费用,为废铝渣的综合利用提供了实用技术。     

可持续发展理论三项进展

过去10年间,可持续发展理论和实践都取得重大进展。在这些进展当中,本文辨识出3个核心的概念:地球系统观、生态文明思想、低碳经济概念,对这3个看起来没有直接关联的概念分析了其中十分密切的理论联系。地球系统观的发展深刻地改变了人类对自身和所处地球环境的认识,被称为"第二次哥白尼革命",从而强化了可持续发展理论的科学基础;生态文明思想从根本上颠覆了工业文明的思想基础,深化了可持续发展理论的哲学和伦理学内涵;低碳经济概念是全球应对气候变化过程中提出的新的理念,以提高能效、减少排放和发展可再生能源为特征的经济发展模式是可持续发展理论在实践的具体化,并具有可操作性。3个概念都突出了地球系统作为一个整体来研究、开发、利用和保护;同时也都强调了对地球表层这个自然与社会剧烈交互作用的生态圈和人类圈的理解必须运用全新的视角和多学科的研究方法。深入理解这3个概念的内涵及相互关系是把握可持续发展理论10年进展的关键。     

Carbon Embodied in International Trade of China and Its Emission Responsibility

Carbon emissions embodied in international trade of China during 1997-2007 are accounted by input-output method based on Chinese input-output table and global trade analysis project database.It is revealed that carbon emissions embodied in imports and exports both increased during 1997-2007,but carbon emissions embodied in exports are greater than those embodied in imports,China is a net export nation in embodied carbon.The net exports of embodied carbon account for about 10.82% of the total carbon emissions in 1997,dropped to 7.15% in 2002,increased to13.13% in 2006,and slightly dropped to 12.64% in 2007.Low-end position of international industry division is an objective factor of being a net exporter of embodied carbon for China,and usage of a large amount of obsolete energy-using equipments wasted much energy and increased carbon emissions embodied in exports.Importers should take more responsibilities for carbon emissions embodied in trade,and China should take a certain responsibility for unreasonable energy dissipations too.     

异波折板水解酸化-A2O一体化反应器实验研究

设计了异波折板水解酸化-A2O一体化反应器,进行生活污水处理的实验研究。10个月的实验结果表明,系统的最佳水力停留时间（HRT）为8 h时,最适COD进水浓度为240-100mg/L,最佳混合液回流比（r）-污泥回流比（R）为250%-100%。控制反应器于以上运行参数下,25±2℃所对应的COD、TN和TP去除率分别为96.84%、67.55%和81.92%。当温度降至7℃时,其COD、TP和TN分别降至86.35%、50.25%和65.68%。基于实验分析结果,阐明了一体化反应器高效性的机理在于异波折板水解酸化段具有高效传质特性和A2O段具有复合式活性污泥-接触氧化好氧池的特点。     

淄博市环境质量现状与改善对策研究

通过对淄博市环境质量变化趋势的分析,指出结构性污染和区域性污染是淄博市环境污染存在的最突出问题,既影响了环境质量状况的持续改善,也制约了环境容量和环境承载能力。提出应科学调整产业结构,加快结构性污染治理,并对加快淄博市工业结构调整提出几点建议。