红外光谱法测定粉尘中游离二氧化硅综述

全面地回顾了国内外红外光谱法测定粉尘中游离二氧化硅的研究成果。系统而重点地介绍了溴化钾压片法、粉尘滤膜样品重沉积和采样滤膜直接测定技术,分析了样品粒度、标准石英物质和矿物干扰物对测定结果的影响及干扰消除方法;还介绍了国外对红外光谱法与Ｘ－射线衍射法进行比较性研究的结果和动态,并得出结论。文章所列参考文献对本领域研究人员和基层检测人员具有很高的参考价值。     

室内空气中污染物的检测技术

室内环境空气污染对人体健康影响很大,文中指出了影响人体健康的致病因子,分析了单个微粒的光通量和粒径之间的关系。鉴于单下颗粒的散射光信号很弱,本文提出一种方法,把激光器的内腔作为颗粒注入区,利用激光器的内腔功率谱密度远大于腔外功率密度的特点,结合先进的激光散控制理论,对空气中的颗粒进行检测。     

江汉平原湖区农田防护林的小气候效应研究

在区域开发中,平原湖区的林业发展潜力很大,同时,湖区农田防护林的建设,也是促进生态平衡的一项重要措施,防护林能进一步改善湖区小气候环境,尤其对保障农业生产有着相当重要的意义。通过对江汉平原湖区的农田防护林网内的小气候效应温度,湿度,风速等要素的观测数据进行研究,我们得出的结果表明：江汉平原湖区农田林网的建设,除提供工农业生产所需的林木外,随着林木的增多,林网的完善,还可调节气候,保持水土,防风固沙     

长江流域商品粮基地建设与农业持续发展

长江流域横跨我国中亚热带,光、热、水气候资源及其时空组合优势明显,土地自然生产力较高。粮食生产在全国占有重要地位。但由于流域内山地比重大,人口稠密,人均土地资源偏少,在现有耕地资源有限和粮食市场不稳等的多重压力下,历史时期内形成的“南粮北调”正逐渐被“北粮南调”所取代。在分析长江流域粮食生产现状和近二十年来商品粮基地建设对粮食生产的促进作用的基础上,从流域经济持续发展角度,提出了发挥长江流域粮食生     

池火灾热辐射下的最小安全距离

防火间距是石油化工企业平面设计中的一个重要参数 ,笔者旨在从流体力学角度研究池火灾发生情况下邻罐之间最小安全距离 ,从而给防火间距的制定提供依据。辐射是储罐区池火灾的主要传热方式 ,作者对池火灾形状以及介质辐射吸收性质进行了适当的简化 ,用CFD软件Fluent对丙烷液化烃储罐池火灾热辐射进行了数值模拟。模拟结果表明对于锰钢材料、内径为 1 2 4 1 0mm液化烃压力储罐 ,稳态池火灾情况下 ,相邻两储罐之间的最小安全距离为 1 5m。     

Characterization of Dust Storms to Hong Kong in April 1998

In April 1998, two intense dust storms were generated in CentralAsia and transported eastward across East Asia (15 and 19 April). This article presents the chemical characterization ofHong Kong (HK) aerosols during the dust storms. During the 15 Aprildust storm, hourly respiratory suspended particles (RSP)(particle diameter smaller than 10 m) concentrationsmonitored at 7 sites in Hong Kong reached the peak valuessynchronously between 9 and 11 a.m. on 17 April, in which thehighest concentration was 267 g m^-3. Analysis ofthe RSP samples showed that concentrations of crustalelements (Ba, Ca, Cd, Cr, Fe, Mg, K⁺) and anthropogenicspecies (As, Ni, Pb, Zn, NH₄ ⁺, NO₃ ^-,SO₄ ^2- and total carbon) were substantiallyenhanced. Enhancement of these species was more than afactor of 2 to 14 relative to the non dust period. The totalcarbon content was high, at 59 g m^-3 (notincluding carbonate), and the enrichment factors of Asand Pb on 17 April were 122 and 117, respectively. Thisimplied that anthropogenic materials together with mineraldust were transported to HK from Mainland China. Based onmaterial balance calculations, mineral dust contributed41% to the observed RSP mass on 17 April, which was 2 times thatof the nondust sample (22%). From the 5-day backwardtrajectory analysis, this storm was transported directlyfrom Northwest China to HK. However, there was nocorresponding observation for the 19 April dust stormaerosol. Consequently, 15 April storm had stronger impact onHK's atmosphere than 19 April storm. Compared to the HK AirQuality Objective, 15 April dust storm did not cause seriousair pollution in HK.     

"开放型"区域资源策略探析--以浙江省为例

本文从区域资源安全的内涵出发,以浙江省为研究对象,在分析了省域资源条件及供给现状的基础上,提出了构建“开放型”区域资源安全体系的总体思路。     

Microbial degradation of phthalic acid esters under anaerobic digestion of sludge

The microbial degradation by anaerobic sludge of three phthalates, priority pollutants, listed by both China National Environmental Monitoring Center and the U.S.EPA, namely, dimethyl (DMP), di-n-butyl (DBP) and di-n-octyl (DOP) phthalates was investigated. The experimental results indicated that the biodegradation rate and the biodegradability of three phthalates under anaerobic conditions appeared to be related to the length of the alkyl-side chains. More than 90% of DMP and DBP with the short alkyl-side chain phthalates can be degraded, whereas the DOP degradation appeared to be relatively slow under the same experimental conditions. The quantity of methane produced was measured and the results showed that both the ester groups and the phthalate ring were mineralized at a significant rate. The kinetics study demonstrated that the biodegradation of three phthalates conformed to the first-order model with respect to their concentrations.     

Carbon disulfide at a Chinese viscose factory external and internal exposure assessment

This article presents the results of carbon disulfide exposure measurements in a Chinese viscose rayon factory. The objectives of the study were to identify the external exposure levels at a large factory and to investigate the 2-thiothiazolidine-4-carboxylic acid (TTCA) concentrations in the urine of the subjects who were exposed to carbon disulfide in the working place atmosphere. The metabolism of carbon disulfide in the exposed subjects was also studied in order to demonstrate the best points in time for the internal exposure sampling. The measurement of the amount of personal exposure to carbon disulfide in the air of the workplace was performed by GC-FPD; the presence of TTCA in the workers urine was analyzed by use of a modified HPLC method. The kinetics of TTCA excretion was studied by analyses at different time-points both during and after exposure to carbon disulfide in the subjects. A total of 155 personal samples were obtained. The carbon disulfide concentration in the staple viscose hall was 13.72 +/- 1.12 mg m-3 in terms of the geometric mean +/- geometric standard deviation, and was 20.05 +/- 1.33 mg m-3 in the filament spinning hall. The TTCA values in the subjects who worked in the staple spinning hall were 1.18 +/- 0.43 mg g-1 creatinine and 1.07 +/- 0.38 mg g-1 creatinine for subjects working in the filament spinning hall. The best time for TTCA sampling is at the end of the working shift, the TTCA excretion was stable for a period of 4-12 h after exposure of the subjects to the carbon disulfide. It might be that the Chinese have different anthropometric characteristics; a sampling bias may therefore appear among different races.