Effects of riboflavin on the phototransformation of benzo[a]pyrene

Riboflavin (Vitamin B2) is a natural dye-sensitizer habitually present in natural waters. Effects of riboflavin as photosensitizer on the transformation of benzo[a]pyrene (BaP) (10 microM) in the aqueous-organic solvent (water/acetonitrile/methanol 50/40/10) were investigated in this study. The photolysis half life of BaP in solution containing 50 microM riboflavin was 5 min, compared to 98 min in the absence of riboflavin. The rate of phototransformation of BaP increased as the concentration of riboflavin was raised from 10 microM to 100 microM under both natural sunlight and UVA irradiation. The half life of BaP in the presence of 50 microM riboflavin was 10.6 min and 43.1 min when exposed to visible range of natural sunlight and UVA irradiation respectively. Riboflavin decomposes under natural sunlight. Lumichrome, a principal photoproduct of riboflavin, was shown to photosensitize BaP under natural sunlight after photolysis of riboflavin. Our study indicated that other photoproducts from riboflavin, such as lumiflavin, were also involved in the phototransformation of BaP under sunlight when riboflavin diminished. The major photoproducts in the photolysis of BaP were identified as 1,6-benzo[a]pyrene-dione, 3,6-benzo[a]pyrene-dione, 6,12-benzo[a]pyrene-dione by using high performance liquid chromatography (HPLC). All these products were detected in the samples which were irradiated under different light sources and in the presence or absence of riboflavin. The possible phototransformation mechanism was discussed.     

Effect of soil characteristics on Cd uptake by the hyperaccumulator Thlaspi caerulescens

The influence of soil characteristics on the phytoremediation potential of Thlaspi caerulescens is not well understood. We investigated the effect of soil pH and Cd concentration on plant Cd uptake on one soil type, and the variation in Cd uptake using a range of field contaminated soils. On soils with total Cd concentrations of 0.6-3.7 mg kg(-1), T. caerulescens (the Ganges ecotype) produced greater biomass in the pH range 5.1-7.6 than at pH 4.4. The highest plant Cd concentration (236 mg kg(-1)) and Cd uptake (228 microg pot(-1)) were observed at pH 5.1. On soils with total Cd concentrations of 2.6-314.8 mg kg(-1), shoot Cd concentrations were 10.9-1,196 mg kg(-1). Multiple regression analysis indicated that higher Cd in soil, low pH (within the range of >5) and coarser texture were associated with higher Cd concentration and Cd uptake by T. caerulescens.     

Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red-mud

We evaluated the effectiveness of lime and red mud (by-product of aluminium manufacturing) to reduce metal availability to Festuca rubra and to allow re-vegetation on a highly contaminated brown-field site. Application of both lime and red mud (at 3 or 5%) increased soil pH and decreased metal availability. Festuca rubra failed to establish in the control plots, but grew to a near complete vegetative cover on the amended plots. The most effective treatment in decreasing grass metal concentrations in the first year was 5% red mud, but by year two all amendments were equally effective. In an additional pot experiment, P application in combination with red mud or lime decreased the Pb concentration, but not total uptake of Pb in Festuca rubra compared to red mud alone. The results show that both red mud and lime can be used to remediate a heavily contaminated acid soil to allow re-vegetation.     

反硝化生物膜对PBS表面形态及化学组分的影响

PBS是一种新型的可生物降解聚合物(BDPs),可以用做反硝化碳源和生物膜载体,去除饮用水源水中的硝酸盐.利用红外光谱和扫描电子显微镜对反硝化生物膜生长前后PBS颗粒表面形态、化学组成的变化进行了分析.结果表明,PBS仅在微生物作用下降解并为反硝化菌提供碳源.PBS颗粒可以在12 h内使进水中53 mg·L^-1的硝态氮降低到10 mg·L^-1以下(我国饮用水水质标准为:NO₃^--N<15 mg·L^-1).红外光谱表明,反硝化微生物附着生长后其PBS在2 925 cm^-1和2 850 cm^-1附近的吸收带以及3 200 cm^-1～3 410 cm^-1处峰值减弱,说明PBS材料中甲基、羟基官能团比例下降,而其它官能团没有发生明显的变化,PBS的主要单体组分淀粉和乙烯都可以被反硝化微生物用作碳源.扫描电子显微镜观察结果表明,反硝化生物膜附着生长后,PBS颗粒表面会出现空洞,扩大了生物膜生物附着生长的表面积,有利于形成致密的反硝化生物膜,对反硝化菌形成保护作用.     

Effects of sulfur dioxide and nitric oxide on mercury oxidation and reduction under homogeneous conditions

This paper is particularly related to elemental mercury (Hg0) oxidation and divalent mercury (Hg2+) reduction under simulated flue gas conditions in the presence of nitric oxide (NO) and sulfur dioxide (SO2). As a powerful oxidant and chlorinating reagent, Cl2 has the potential for Hg oxidation. However, the detailed mechanism for the interactions, especially among chlorine (Cl)-containing species, SO2, NO, as well as H2O, remains ambiguous. Research described in this paper therefore focused on the impacts of SO2 and NO on Hg0 oxidation and Hg2+ reduction with the intent of unraveling unrecognized interactions among Cl species, SO2, and NO most importantly in the presence of H2O. The experimental results demonstrated that SO2 and NO had pronounced inhibitory effects on Hg0 oxidation at high temperatures when H2O was also present in the gas blend. Such a demonstration was further confirmed by the reduction of Hg2+ back into its elemental form. Data revealed that SO2 and NO were capable of promoting homogeneous reduction of Hg2+ to Hg0 with H2O being present. However, the above inhibition or promotion disappeared under homogeneous conditions when H2O was removed from the gas blend.     

Application of SO(4)(2-)/TiO2 solid superacid in decontaminating radioactive pollutants

Polyaniline doped with SO(4)(2-)/TiO(2) superacid shows good conductive ability. When used in a strippable coating film for decontaminating radioactive pollutants, the SO(4)(2-)/TiO(2) solid superacid replacing HCl exhibits higher electrical conductivity (7.01 s/cm) and a decontamination ratio higher than 97%. Coating and electrolyzing the film in solution or in dry medium were effective methods, the latter was more promising for decontaminating radioactive pollutants which were attached to the surface or within the body of equipments used in nuclear industry.     

利用百合(Lilium davidii)根尖细胞的微核细胞率作为环境监测指标的探讨

首次报道了利用百合根尖细胞微核细胞率作为环境监测指标的可行性和优越性。实验证明,百合根尖比蚕豆根尖细胞的微核细胞率更敏感。     

企业实用安全评价方法初探--一种简单易行的企业自我评价方法

分析了当前我国安全评价中存在的问题,探讨一种企业实用的安全综合评价方法.介绍该方法的评价原理、程序和步骤,总结该评价方法的功能、特点和适用范围,提出改进方向.     

浅谈质量/环境/职业健康安全一体化管理体系的建立与实施

介绍了运用管理的系统方法,策划、推进及实施质量/环境/职业健康安全一体化管理体系的做法,并对各阶段体系建立的方法与措施进行了阐述.