全文获取类型
收费全文 | 12376篇 |
免费 | 488篇 |
国内免费 | 4445篇 |
专业分类
安全科学 | 821篇 |
废物处理 | 800篇 |
环保管理 | 929篇 |
综合类 | 6846篇 |
基础理论 | 2033篇 |
环境理论 | 6篇 |
污染及防治 | 4411篇 |
评价与监测 | 466篇 |
社会与环境 | 433篇 |
灾害及防治 | 564篇 |
出版年
2024年 | 1篇 |
2023年 | 198篇 |
2022年 | 578篇 |
2021年 | 481篇 |
2020年 | 351篇 |
2019年 | 360篇 |
2018年 | 481篇 |
2017年 | 559篇 |
2016年 | 523篇 |
2015年 | 699篇 |
2014年 | 966篇 |
2013年 | 1274篇 |
2012年 | 1017篇 |
2011年 | 1192篇 |
2010年 | 854篇 |
2009年 | 846篇 |
2008年 | 888篇 |
2007年 | 696篇 |
2006年 | 655篇 |
2005年 | 482篇 |
2004年 | 351篇 |
2003年 | 437篇 |
2002年 | 383篇 |
2001年 | 312篇 |
2000年 | 342篇 |
1999年 | 399篇 |
1998年 | 328篇 |
1997年 | 311篇 |
1996年 | 297篇 |
1995年 | 260篇 |
1994年 | 177篇 |
1993年 | 156篇 |
1992年 | 114篇 |
1991年 | 94篇 |
1990年 | 64篇 |
1989年 | 54篇 |
1988年 | 44篇 |
1987年 | 19篇 |
1986年 | 22篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 10篇 |
1982年 | 10篇 |
1981年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 750 毫秒
891.
After adding either organic or inorganic ligands, sulfidated nano-zero-valent iron (SnZVI) was used for aerobic degradation of phenol, and the effect of the ligand species on oxidation performance was investigated. We found that SnZVI hardly degraded phenol in the absence of ligand addition. Ligands initiated and promoted the degradation of pollutants by SnZVI. The data herein show that a characteristic inorganic ligand, tripolyphosphate (TPP), is more effective in enhancing oxidation than a characteristic organic ligand oxalate. In addition to the scavenging of reactive oxidants by the organic ligand, more ferrous ion (Fe(II)) dissolution from SnZVI in the TPP system is another cause for the superior enhancement by the inorganic ligand. In the oxalate system, as the sulfur content of SnZVI increased, the oxidation efficiency increased because FeS shell promoted the transfer of electrons to produce more reactive oxygen species (ROS). In TPP system, the effect of sulfur content on oxidation performance is more complex. The SnZVI with low sulfur content showed poor oxidation performance compared with that of nZVI. Further experiments proved that sulfidation might weaken the complexation of TPP with surface bound Fe, which would slow down the ionic Fe(II) dissolution rate. Therefore, sulfidation has the dual effects of enhancing electron transfer and inhibiting the complexation of inorganic ligands. In addition, the mechanisms of ROS generation in different ligand systems were investigated herein. Results showed that the critical ROS in both the oxalate and TPP systems are hydroxyl radicals, and that they are produced via one-electron activation of O2. 相似文献
892.
Dietary uptake is the major way that inorganic arsenic (iAs) enters into benthic fish; however, the metabolic process of dietborne iAs in fish muscle following chronic exposure remains unclear. This was a 40-day study on chronic dietborne iAs [arsenite (AsIII) and arsenate (AsV)] exposure in the benthic freshwater food fish, the crucian carp (Carassius auratus), which determined the temporal profiles of iAs metabolism and toxicokinetics during exposure. We found that an adaptive response occurred in the fish body after iAs dietary exposure, which was associated with decreased As accumulation and increased As transformation into a non-toxic As form (arsenobetaine). The bioavailability of dietary AsIII was lower than that of AsV, probably because AsIII has a lower ability to pass through fish tissues. Dietary AsV exhibited a high potential for transformation into AsIII species, which then accumulated in fish muscle. The largely produced AsIII considered more toxic at the earlier stage of AsV exposure should attract sufficient attention to human exposure assessment. Therefore, the pristine As species and exposure duration had significant effects on As bioaccumulation and biotransformation in fish. The behavior determined for dietborne arsenic in food fish is crucial for not only arsenic ecotoxicology but also food safety. 相似文献
893.
Yang Zhaojun Guo Xiaoting Sun Jun Zhang Yali 《Environment, Development and Sustainability》2021,23(8):12056-12076
Environment, Development and Sustainability - Sustainable supply chain emerges as a major business trend essential to long-term competitive advantage. Relevant corporate decisions concern a broad... 相似文献
894.
Zhao Yihang Liang Chen Zhang Xinlong 《Environment, Development and Sustainability》2021,23(8):11335-11356
Environment, Development and Sustainability - As one of the efficacious environmental governance instruments, environmental regulations usually have been adopted to control haze pollution in most... 相似文献
895.
Zhang Ming Sun Ruifeng Wang Wenwen 《Environment, Development and Sustainability》2021,23(9):12814-12827
Environment, Development and Sustainability - Air pollution treatment has become the priority in environmental management for Chinese government. However, environmental problems are closely related... 相似文献
896.
Liu Jianli Liang Jianyao Ding Jiannan Zhang Guangming Zeng Xianyi Yang Qingbo Zhu Bo Gao Weidong 《Environment, Development and Sustainability》2021,23(8):11240-11256
Environment, Development and Sustainability - Textiles release microfibers to the environment during production, use, and at end-of-life disposal. There is a potentially large and growing risk to... 相似文献
897.
现阶段,随着社会经济的不断发展,国家越来越重视河道整治工作。目前,依然存在着部分河道污染严重的问题。本文将对河道生态环境保护与治理工作进行分析研究,希望为相关工作人员提供参考。 相似文献
898.
给水管壁生物膜会吸附水中的重金属元素积累在管壁生物膜中,在受到扰动时释放回到水体,危害饮用水水质安全。试验以上海管网末梢水为实验对象,研究了PVC、铸铁和紫铜等三种管材上生物膜对铅、镉的解吸特性。结果表明,PVC、铸铁和紫铜附着生物膜对铅的解吸容量qe分别为:5.92211μmol·m^-2、128.3051μmol·m^-2和21.1808,解吸速率常数k分别为:0.001060 m^2·μmol^-1·min^-1、0.000041 m^2·μmol^-1·min^-1和0.000503 m^2·μmol^-1·min^-1,对于镉元素三种材质的解吸容量qe分别为:14.71519μmol·m^-2、18.50481μmol·m^-2和2.25225μmol·m^-2;解吸速率常数k分别为:0.000102 m^2·μmol^-1·min^-1、0.001070 m^2·μmol^-1·min^-1和0.000103 m^2·μmol^-1·min^-1。 相似文献
899.
900.
随着经济和社会的不断发展,地球的环境正在遭受着严重的侵害,关于环境的问题也日益显现出来,比如全球变暖、雾霾等现象。本文分析了空气污染的因素、气象要素对空气质量的影响,并提出了防治空气污染的对策。 相似文献