A new method for bisphenol A (BPA) degradation in aqueous solution was developed. The characteristics of BPA degradation in a heterogeneous ultraviolet (UV)/Fenton reaction catalyzed by FeCo2O4/TiO2/graphite oxide (GO) were studied. The properties of the synthesized catalysts were characterized using scanning electron microscopy, X-ray diffraction, and vibrating sample magnetometry. FeCo2O4 and TiO2 were grown as spherical shape, rough surface, and relatively uniform on the surface of GO (FeCo2O4/TiO2/GO). Batch tests were conducted to evaluate the effects of the initial pH, FeCo2O4/TiO2/GO dosage, and H2O2 concentration on BPA degradation. In a system with 0.5 g L−1 of FeCo2O4/TiO2/GO and 10 mmol L−1 of H2O2, approximately 90 % of BPA (20 mg L−1) was degraded within 240 min of UV irradiation at pH 6.0. The reused FeCo2O4/TiO2/GO catalyst retained its activity after three cycles, which indicates that it is stable and reusable. The heterogeneous UV/Fenton reaction catalyzed by FeCo2O4/TiO2/GO is a promising advanced oxidation technology for treating wastewater that contains BPA.
温度和pH值是影响污水脱氮除磷效果的2个重要因素.试验采用连续搅拌槽式反应器(continuous stirred tank reactor,CSTR),通过对不同温度和pH值条件下的硝化、反硝化、释磷和吸磷反应速率的测定,总结出温度和pH值对活性污泥生化反应速率的影响规律.试验表明,硝化和反硝化速率随温度的升高而加快.在5℃和33℃时,硝化速率分别为0.01 kg NH4 -N/(kg VSS·d)和0.28 kg NH4 -N/(kg VSS·d);在5℃和30℃时,反硝化速率分别为0.097 kg NO3--N/(kg VSS·d)和0.476 kg NO3--N/(kg VSS·d);但温度对吸磷和释磷速率的影响不大.pH值对硝化、反硝化、吸磷和释磷速率均有显著影响,在pH值为7.74时,硝化速率为0.095 kg NO3--N/(kg VSS·d);而在pH值为4.9和10.08时,硝化速率仅为0.005 kg NO3--N/(kg VSS·d)和0.006 kg NO3--N/(kg VSS·d).在pH值为7.85时,反硝化速率达到最大值0.36 kg NO3--N/(kg VSS·d);而在偏酸性和碱性条件下,反硝化速率显著下降. 相似文献