用加速溶剂提取仪提取污染土壤中的有机氯农药

研究加速溶剂萃取对土壤中有机氯农药的提取效果,并与索氏提取法进行比较。结果表明,加速溶剂萃取对土壤中滴滴涕的回收率明显高于索氏提取,对土壤中BHC的提取能力与索氏提取相当。用该方法测定了天津污灌区和非污灌区土壤样品中的有机氯农药残留量。结果表明,α-BHC、β-BHC、δ-BHC、γ-BHC、p,p’-DDE、p,p’-DDD、p,p’-DDT、o,p’-DDT的检出率为100％,这些有机氯农药在污灌旱地和稻田地的残留量分别为7．5－71．1ng/g和3．0－16．5ng/g。非污灌的旱地中有机氯农药的残留量为3．1－17．6ng/g。     

Effect of phosphate fertilizer application on phosphorus (P) losses from paddy soils in Taihu Lake Region. I. Effect of phosphate fertilizer rate on P losses from paddy soil

A field plot study was conducted on two types of paddy soils in the Taihu Lake Region, during the rice season of year 2000 in order to assess phosphorus (P) losses by runoff and vertical leaching, which are considered the two main pathways of P movement from paddy soil into its surrounding water course. Commercial NPK compound fertilizer and single superphosphate fertilizer were applied to furnish 0, 30, 150, and 300 kg applied P ha m(-2). The experiments consisted of three replicates of each treatment in Changshu site and four replicates in Anzhen site, with a plot size of 5 x 6 m2 in a randomized block. Results revealed that the average concentration range for total P (TP) in runoff was 1.857-7.883, 1.038-5.209, 0.783-1.255 and 0.572-0.691 mg P l(-1) respectively for P300, P150, P30 and P0 in Anzhen, while it was 2.431-2.449, 1.578-1.890, 1.050-1.315 and 0.749-0.941 mg P l(-1) respectively in Changshu. In all treatments, particulate P (PP) represented a major portion of the TP lost in runoff, it was 80% in Anzhen, and it was even more (>90%) in Changshu. Phosphate fertilizer treatments significantly affected P concentrations and P loads in the runoff. The mean concentration and average seasonal TP load from the P150 plots were 1.809 mg P l(-1) and 395 g P ha m(-2) season(-1) respectively, and lower than that from the P300 plots (2.957 mg P l(-1) and 652 g P ha m(-2) season(-1)). These were obviously higher than from the P30 (0.761 mg P l(-1) and 221 g P ha m(-2) season(-1)) and P0 (0.484 mg P l(-1) and 146 g P ha m(-2) season(-1)) respectively. There was no significant difference found between the P30 and the P0 in both sites. Under usual P application rate, there were total 31.7 and 20.6 tones P removed by runoff from permeable (Anzhen site) and waterlogged (Changshu site) paddy soils in the southern Jiangsu region (major part of the TLR) in the rice season of the year 2000. But if the P application rate is unusual high, or the Olsen P in soil accumulates to above a certain level, then this could sharply increase in the future. The average concentration of molybdate reactive phosphorus (MRP) in the vertical leachate from the four different P treatments ranged from 0.058 to 0.304 mg P l(-1) in Anzhen and from 0.048 to 0.394 mg P l(-1) in Changshu. P application rate significantly affected the MRP concentration at each depth in both sites, except for the 90 cm in Anzhen. The average MRP loads during the rice season moved by vertical leaching from the four treatments ranged from 163 to 855 g P ha m(-2) season(-1) in Anzhen and 208-1,825 g P ha m(-2) season(-1) in Changshu. Vertical leachate movement does not necessarily mean that it moves towards surface water and contaminate the watercourses in this flat plain paddy soil region, it does, however, imply that P can move down from surface layers of soil to deeper levels.     

水资源的持续开发和利用

随着人品的增长和经济的发展,越来越多的国家正面临着严重的水危机、水质的恶化和水生态系统的破坏使许多国家的淡水供应出现危机,所以水资源必须得到保护和合理的开发。本文探讨了全球水资源的短缺及其原因,并提出了解决水资源短缺的途径。     

上海郊区稻田氮素流失研究

通过测坑和大田小区试验，研究了上海郊区稻田氮素排水流失和渗漏流失的特征、相关因素和流失负荷。结果表明，稻田综合排水TN为6.55mg／L，流失负荷为16．68kg／hm^2，以铵态氮为主，稻田氮素的排水流失负荷为16．68kg／hm^2。稻田渗漏水氮浓度与前茬作物有关，草莓和蔬菜高，麦茬低，TN为5．73mg／L，渗漏负荷为22．92kg／hm^2，其中硝态氮占50％左右。稻田氮素总流失负荷占稻季化肥用量的13．23％。测坑和大田试验都证明，施用有机肥可较多地减少稻田氮素流失量。     

测定高锰酸盐指数考核样品时的计算方法修正

针对测定高锰酸盐指数考核样品时的结果偏高现象，经过查找，其原因是由于按公式计算没有考虑稀释用纯水的空白值响应。经修正公式后计算，其考核样品的结果则均为正确。     

新型湿式湍流除尘器及在电厂输煤系统中的应用

介绍了针对火电厂输煤系统作业环境粉尘治理而研制开发的新型湿式湍流除尘器的设计思路、设备结构、技术特点及在电厂输煤系统的应用情况.     

含有机物铁泥的超临界水氧化法资源化

氨基染料生产过程中产生大量含有机物的铁泥,对环境造成严重污染并造成资源的极大浪费.利用超临界水氧化法对含有机物铁泥进行资源化处理研究,并对产物进行了X射线衍射分析（XRD）、色差实验与电子探针分析.研究结果显示,用超临界水氧化法处理铁泥可以将铁泥中所含的有机物完全氧化,真正实现环境友好;超临界水首先将铁泥氧化成α-Fe2O3与γ-Fe2O3,再经过800℃煅烧后可以作为氧化铁红颜料使用;超临界反应压力对样品的晶型与颜色影响不大.     

基于熵值法改进层次分析法马拉松急救能力评价模型的构建*

为减少马拉松赛事中猝死事故的发生,基于层次分析法、熵值法及模糊综合评价法,构建马拉松赛事医疗保障体系中现场急救能力的评价模型。通过分析马拉松赛事急救系统的组成及急救成功实例,总结影响马拉松急救能力的因素并建立评价指标体系;运用层次分析法确定评价体系的初始指标权重,熵值法修正指标权重,结合模糊决策参数法建立马拉松现场急救能力评价模型,并应用于2004年和2017年北京马拉松赛事,得到2004年北京马拉松的急救能力为“较差”,2017年北京马拉松的急救能力为“较好”,符合实际情况。结果表明:评价模型可为大型马拉松赛事的急救能力评价提供参考,为预防和减少马拉松赛事中猝死事件的发生提供技术支撑。     

基于传染病模型的群体活动中恐慌心理蔓延研究*

为研究人群中恐慌心理蔓延规律,基于传染病传播模型,构建NPCN（Normal-Panic-Cool-Normal）恐慌心理蔓延模型,通过加入干预因子得到优化模型,对NPCN模型及优化模型进行数值模拟,并对模拟结果进行对比分析。结果表明:恐慌人群比例随恐慌率α和冷静损失率γ增大而增大,随冷静率β增大而减小;在干预因子ω和ψ作用下,恐慌人群比例P明显下降,说明采取及时干预措施对恐慌心理蔓延抑制效果较好。     

大气扩散浓度估算在锅炉房烟囱高度计算中的应用

锅炉房的烟囱已从单纯的排气装置发展成为控制污染、保护环境的设备。因此烟囱高度的正确估算对于环境影响评价工作、建设单位都至关重要。结合唐山某城区集中供热锅炉房环境影响评价案例,利用大气扩散浓度公式估算锅炉房烟囱高度。在计算过程中,考虑了烟气流速及当地常年风向、风速、稳定度等污染气象特征,由正态分布模式导出的简化公式导出最大着地浓度与烟囱有效高度的平方成反比,从而计算出烟囱高度。另外还总结烟囱设计中应注意的一些问题,为建有锅炉房的建设项目环境影响评价工作提供参考。