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991.
992.
基于LonWorks现场总线技术的城市污水处理系统的设计与实现 总被引:1,自引:0,他引:1
主要讨论了利用LonWorks现场总线技术来实现城市污水处理厂污水处理系统的实时控制,本系统采用IPC和PLC控制结构对现场的各种设备进行实时控制和数据的采集,通过LonWorks现场总线网络自动收集和传输污水处理系统的数据到中心控制室,中心控制室的计算机分析数据后对现场进行实时监控,实现污水处理的自动控制和无人化管理,中心控制室也可以通过Internet与远程终端互相通讯,向各终端提供实时的数据和远程终端对污水处理系统的实时监控。 相似文献
993.
Ozonation of the azo dye Cationic Red X-GRL was investigated in a bubble column reactor at varying operating parameters such as oxygen flow rate, temperature, initial Cationic Red X-GRL concentration, and pH. The conversion of dye increased with the increasing of pH and oxygen flow rate. As the reaction rate constant and the volumetric mass transfer coefficient increase while the ozone equilibrium concentration decreases with the temperature, there is a minimum conversion of dye at 25 degrees C. The increasing of initial dye concentration leads to a decreasing conversion of dye while the ozonation rate increases. The formation of intermediates and the variation of pH, TOC, and nitrate ion during ozonation were investigated by the use of some analytical instruments such as GC/MS, GC, and IC. The intermediates of weak organic acids lower the pH value of the solution. The probable degradation mechanism of the Cationic Red X-GRL in aqueous solution was deliberated with the aid of Molecular Orbital calculations. The N(12)-C(13) site in Cationic Red X-GRL, instead of the N(6)-N(7) site, is found to be the principal site for ozone cycloaddition in the degradation processes. During the degradation process, among the six nitrogen atoms of Cationic Red X-GRL, one is transferred into a nitrate ion, one is converted into an amine compound, and the remaining four are transformed into two molecules of nitrogen. 相似文献
994.
In this paper, a new alternative method, i.e., selective extraction by weakly basic anion exchange resin, has been developed for the removal of trace cadmium and mercury ions from drinking water sources. The mechanism of heavy metal removal is based on selective extraction as the results of LEWIS-base-acid interactions. Transfer of trace mercury species from liquid to resin phase coincides well with the performance of film diffusion. The results demonstrated that the presence of chlorine has a negligible influence on the removal of mercury. However, humic acids can strongly bind mercury by the formation of complex compounds and therefore become the obstacle in the diffusion progress. At neutral or base pH, the resin material exhibits the favorable uptake of heavy metals. In filter experiments, the studied resin material offers favorable properties in the selective extraction of trace mercury and cadmium. 相似文献
995.
996.
Li HY Qu JH Zhao X Liu HJ 《Journal of environmental science and health. Part. B》2004,39(5-6):791-803
The effects of Fe(II), Mn(III) and humic substances on the catalyzed ozonation of alachlor, an endocrine disruptor were investigated. Results revealed that small amounts of Fe(II), Mn(II), and humic substances could enhance the ozonation of alachlor, but larger amounts of them would retard the oxidation. These results were successfully identified by an electron paramagnetic resonance (EPR) spectroscopy spin-trapping method that could quantify hydroxyl radicals. The production of hydroxyl radicals was obviously increased with the increasing of Fe(II) concentration, which contributed to enhance ozonation at low concentrations. But the excess Fe(II) consumed some of the radicals when it was added at a higher concentration (1.5 mg/L). However, no obvious radicals were observed when a different amount of Mn(II) was used, and the catalytic ozonation of alachlor by Mn(II) mainly followed the mechanism of "active sites created on the surface of MnO2." The radical pathway was followed when alachlor was ozonated with different concentrations of humic substances because of its radical initiating, promoting, and inhibiting effects. 相似文献
997.
998.
999.
Fenton试剂法处理甘氨酸废水中COD的研究 总被引:6,自引:0,他引:6
通过正交试验的方法用Fenton试剂对甘氨酸生产中的工业废水进行了试验研究,分析了各因素影响程度及各影响因子的作用机理,得出了最佳的操作条件为:H2O2:COD=1.8,[Fe^2+]=40mmol/L,反应温度40℃,pH值为3,反应时间为80min,最终的COD去除率为68%左右。 相似文献
1000.
γ-射线辐照法改善城市污水厂剩余污泥厌氧消化特性的研究 总被引:2,自引:0,他引:2
采用γ-射线辐照法对城市污水厂剩余污泥进行预处理,从固体组分、可溶性组分及厌氧产气量等角度来探讨γ-射线辐照法改善城市污水厂剩余污泥厌氧消化特性的可行性。结果表明,经γ-射线辐照处理后,污泥的平均粒径减小,在辐照剂量为6.51-30.75kGy范围内,粒径的减小率达30%-50%;可溶性有机组分随着辐照剂量升高而增加,当辐照剂量为19.4kGy时,SCOD增加率达552.5%;与未辐照相比,污泥经2.48、6.51、11.24kGy辐照处理后,厌氧消化累计产气量分别增加8.89%、19.74%和35.81%。γ-射线辐照法是一种有效的改善污泥厌氧消化特性的方法,11.24kGy左右的剂量可作为污泥预处理的最佳剂量。 相似文献