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961.
高氯离子废水COD的吸收测定方法研究   总被引:5,自引:0,他引:5  
本法基于可定星测定K2Cr2O7和Cl-的反应产物Cl2这一原理,在用吸收装置吸收Cl2后.用碘量法测定余氯,从而消除氯离子的干扰。本法具有较高的准确度和精密度。  相似文献   
962.
在乙二胺 (en)介质中 (p H1 1 .5~ 1 2 .3 ) ,Zn(en) 2 +3在单扫描示波极谱仪上于 -1 .42 V(vs.SCE)处产生一灵敏的络合物吸附波 ,锌含量在 0 .0 0 6~ 0 .3 5 μg/ml范围内 ,浓度与峰电流呈线性关系。检测限为 0 .0 0 3 μg/ml。加标回收率为92 %~ 1 0 3 % ,相对标准偏差小于 4.1 %。该方法准确、简便、选择性好 ,可用于 TSP中微量锌的测定。  相似文献   
963.
Nitrated polycyclic aromatic hydrocarbons (NPAHs) have toxic potentials that are higher than those of their corresponding parent polycyclic aromatic hydrocarbons (PAHs) and thus have received increasing attention in recent years. In this study, the occurrence, distribution, source, and human health risk assessment of 15 NPAHs and 16 PAHs were investigated in the surface water from 20 sampling sites of Lake Taihu during the dry, normal, and flood seasons of 2018. The ΣPAH concentrations ranged from 255 to 7298 ng/L and the ΣNPAH concentrations ranged from not-detected (ND) to 212 ng/L. Among the target analytes, 2-nitrofluorene (2-nFlu) was the predominant NPAH, with a detection frequency ranging from 85% to 90% and a maximum concentration of 56.2 ng/L. The three-ringed and four-ringed NPAHs and PAHs comprised the majority of the detected compounds. In terms of seasonal variation, the highest levels of the ΣNPAHs and ΣPAHs were in the dry season and flood season, respectively. Diagnostic ratio analysis indicated that the prime source of NPAHs was direct combustion, whereas in the case of PAHs the contribution was predominantly from a mixed pattern including pollution from unburned petroleum and petroleum combustion. The human health risk of NPAHs and PAHs was evaluated using a lifetime carcinogenic risk assessment model. The carcinogenic risk level of the targets ranged from 2.09 × 10?7 to 5.75 × 10?5 and some surface water samples posed a potential health risk.  相似文献   
964.
The emissions of NO2 and HONO from the KNO3 photolysis in the presence of TiO2 were measured using a round-shape reactor coupled to a NOx analyzer. TiO2 played important roles in the emission flux density of NO2 (RNO2) and HONO (RHONO), depending on crystal structures and mass ratios of TiO2. RNO2 and RHONO significantly decreased with increasing the rutile and anatase mass ratios from 0 to 8 and 0.5 wt.%, respectively. Nevertheless, with further increasing the anatase mass ratio to 8 wt.%, there was an increase in RNO2 and RHONO. RNO2 on KNO3/TiO2/SiO2 had positive correlation with the KNO3 mass (1–20 wt.%), irradiation intensity (80–400 W/m2) and temperature (278–308 K), while it had the maximum value at the relative humidity (RH) of 55%. RHONO on KNO3/TiO2/SiO2 slightly varied with the KNO3 mass and temperature, whereas it increased with the irradiation intensity and RH. In addition, the mechanism for NO2 and HONO emissions from the nitrates photolysis and atmospheric implications were discussed.  相似文献   
965.
Assessment of the health risks resulting from exposure to ambient polycyclic aromatic hydrocarbons (PAHs) is limited by the lack of environmental exposure data among different subpopulations. To assess the exposure cancer risk of particulate carcinogenic polycyclic aromatic hydrocarbon pollution for the elderly, this study conducted a personal exposure measurement campaign for particulate PAHs in a community of Tianjin, a city in northern China. Personal exposure samples were collected from the elderly in non-heating (August–September, 2009) and heating periods (November–December, 2009), and 12 PAHs individuals were analyzed for risk estimation. Questionnaire and time-activity log were also recorded for each person. The probabilistic risk assessment model was integrated with Toxic Equivalent Factors (TEFs). Considering that the estimation of the applied dose for a given air pollutant is dependent on the inhalation rate, the inhalation rate from both EPA exposure factor book was applied to calculate the carcinogenic risk in this study. Monte Carlo simulation was used as a probabilistic risk assessment model, and risk simulation results indicated that the inhalation-ILCR values for both male and female subjects followed a lognormal distribution with a mean of 4.81?×?10?6 and 4.57?×?10?6, respectively. Furthermore, the 95 % probability lung cancer risks were greater than the USEPA acceptable level of 10?6 for both men and women through the inhalation route, revealing that exposure to PAHs posed an unacceptable potential cancer risk for the elderly in this study. As a result, some measures should be taken to reduce PAHs pollution and the exposure level to decrease the cancer risk for the general population, especially for the elderly.  相似文献   
966.
967.
根据中国主要农业区——黄淮海地区的自然和社会经济条件,分析了该区小麦、玉米、大豆、棉花等在气候-土壤生态适应性的基础上,采用逐级生产力估算方法,计算出四大作物的商品量,论证了该地区建设为全国性四大作物商品基地的可能性。  相似文献   
968.
利用红山数字地震台记录到的,自2001年3月到2006年7月近震波形资料,采用从i的尾波单次散射模型计算了该台站周围50 km内的尾波Qc值;该范围代表了邢台震区的地下介质的特征,经多地震拟合后得出尾波与频率的衰减关系.并给出震区的尾波Qc值随时间的变化结果,发现在邢台2002年4月22日的M5.0级地震前后尾波Qc值由低升高然后再降低.  相似文献   
969.
新装修居室空气中甲醛浓度分析   总被引:1,自引:0,他引:1  
目的 探讨装修后居室室内空气中甲醛浓度随时间的变化规律。方法 于2004年3-8月选择装修材料不同的2套新装修住宅,采用盐酸副玫瑰苯胺比色法,跟踪分析呼和浩特市2套居民新装修房屋室内空气甲醛含量。结果 铺复合木地板的A房空气中甲醛浓度比铺耐磨砖地板的B房空气中甲醛浓度约高17%;从装修完毕起,至少要经过6个月,室内空气中甲醛浓度才基本降至符合国家标准的水平;在连续监测过程中也发现,若室温升高,室内空气中甲醛浓度也会略有上升。结论 复合木地板释放的甲醛不容忽视;装修后6个月,室内空气中甲醛浓度才能降到容许范围。  相似文献   
970.
成都电厂电子束烟气脱硫示范工程处理该厂200MW机组锅炉的30万Nm^2/h烟气。其脱硫率及脱硝率均超过80%及10%设计值,处理过程为干法,无废水废渣,副产品硫铵可用作化肥,过程对烟气SO2浓度及烟气量的变化有较好的适应性和负荷跟踪性。  相似文献   
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