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201.
A novel biphenyl-degrading bacterial strain LA-4 was isolated from activated sludge. It was identified as Dyella ginsengisoli according to phylogenetic similarity of 16S rRNA gene sequence. This isolate could utilize biphenyl as sole source of carbon and energy, which degraded over 95 mg/L biphenyl within 36 h. The major metabolites formed from biphenyl, such as 2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid (HOPDA) and benzoic acid, were identified by LC-MS. The crude cell extract of strain LA-4 exhibited the activity of 2,3-dihydroxybiphenyl 1,2-dioxygenase (2,3-DHBD) and the kinetic parameters were Km= 26.48 μmol/L and Vmax= 8.12 μmol/mg protein. A conserved region of the biphenyl dioxygenase gene bphA1 of strain LA-4 was amplified by PCR and confirmed by DNA sequencing. 相似文献
202.
Liangliang Wei Kun Wang Qingliang Zhao Junqiu Jiang Chunmei Xie Wei Qiu 《环境科学学报(英文版)》2010,22(5):641-647
In order to characterize the organic properties of waste activated sludge in a wastewater treatment plant,organic matter within sludge was extracted with NH 3 ·H 2 O preferentially,and subsequently fractionated into five fractions using XAD-8/XAD-4 resins.Up to a 63.8%-71.1% of organic matter within the sludge could be efficiently extracted by NH 3 ·H 2 O.Fractionation results showed that hydrophobic acid and hydrophilic fraction were two main components among the sludge organic matter (accounting for 32.2% and 48.0% of the bulk organic matter,respectively),whereas transphilic acid,hydrophobic neutral and transphilic neutral were quite low (accounting for 9.2%,5.8% and 4.8%,respectively).Despite that the extractant of NH 3 ·H 2 O showed a relatively higher extraction efficiency of the aromatic components,the relatively low aromaticity of the organic fractions implied that those non-aromatic components could also be effectively extracted,especially for neutral and hydrophilic fractions.In addition,acidic fractions contained more aromatic humic-like components,whereas the neutral fractions had a greater content of aromatic proteins and soluble microbial byproduct-like components.Extraction of sludge organics with NH 3 ·H 2 O and subsequential fractionation using XAD resins could be a novel method for further characterization of sludge organics. 相似文献
203.
Heavy metal (Pb,Zn) uptake and chemical changes in rhizosphere soils of four wetland plants with different radial oxygen loss 总被引:4,自引:0,他引:4
Lead and Zn uptake and chemical changes in rhizosphere soils of four emergent-rooted wetland plants; Aneilema bracteatum,
Cyperus alternifolius, Ludwigia hyssopifolia and Veronica serpyllifolia were investigated by two experiments: (1) rhizobag filled with
“clean” or metal-contaminated soil for analysis of Pb and Zn in plants and rhizosphere soils; and (2) applied deoxygenated solution for
analyzing their rates of radial oxygen loss (ROL). The results showed that the wetland plants with di erent ROL rates had significant
e ects on the mobility and chemical forms of Pb and Zn in rhizosphere under flooded conditions. These e ects were varied with
di erent metal elements and metal concentrations in the soils. Lead mobility in rhizosphere of the four plants both in the “clean”
and contaminated soils was decreased, while Zn mobility was increased in the rhizosphere of the “clean” soil, but decreased in the
contaminated soil. Among the four plants, V. serpyllifolia, with the highest ROL, formed the highest degree of Fe plaque on the root
surface, immobilized more Zn in Fe plaque, and has the highest e ects on the changes of Zn form (EXC-Zn) in rhizosphere under both
“clean” and contaminated soil conditions. These results suggested that ROL of wetland plants could play an important role in Fe plaque
formation and mobility and chemical changes of metals in rhizosphere soil under flood conditions. 相似文献
204.
Natural zeolite was modified by loading cetylpyridinium bromide (CPB) to create more e cient sites for humic acid (HA) adsorption.
The natural and CPB modified zeolites were characterized with X-ray di raction, field emission scanning electron microscopy, Fourier
transform infrared spectroscopy and elemental analysis. The e ects of various experimental parameters such as contact time, initial HA
concentration, solution pH and coexistent Ca2+, upon HA adsorption onto CPB modified zeolites were evaluated. The results showed
that natural zeolite had negligible a nity for HA in aqueous solutions, but CPB modified zeolites exhibited high adsorption e ciency
for HA. A higher CPB loading on natural zeolites exhibited a larger HA adsorption capacity. Acidic pH and coexistent Ca2+ were
proved to be favorable for HA adsorption onto CPB modified zeolite. The kinetic process was well described by pseudo second-order
model. The experimental isotherm data fitted well to Langmuir and Sips models. The maximum monolayer adsorption capacity of CPB
modified zeolite with surfactant bilayer coverage was found to be 92.0 mg/g. 相似文献
205.
206.
完善广东省环境应急管理机制研究 总被引:1,自引:0,他引:1
通过对多起北江污染事件(2005年北江镉污染、2010年北江铊污染、2011年武江河锑污染)的案例分析,探究突发环境污染事件的共同特征(由企业违法排污重金属污染物或EPA重点控制优先污染物造成)和演变趋势(影响范围逐渐扩大致应急管理要求逐渐提高),提出重点防控环境优先污染物、整治重污染行业、加强环境承载能力预警、实行强制环境责任保险制度等环境应急管理对策,完善广东省环境应急管理机制. 相似文献
207.
山东省汽车喷涂行业VOCs排放特征研究 总被引:3,自引:1,他引:2
采用气袋采样-气相色谱/质谱法,采集并分析了山东省内小型通用车、货车、电动商务车以及半挂车4类典型汽车喷涂企业挥发性有机物(VOCs)的排放特征。结果表明:山东省汽车喷涂企业中VOCs排放总量以及检出数量排序为:半挂车喷涂企业电动商务车喷涂企业货车喷涂企业小型通用车喷涂企业。各类汽车喷涂企业喷漆以及烘干车间排放的VOCs大多以苯类物质为主(小型通用车面漆烘干车间除外),在小型通用车以及半挂车涂装企业废气中烷烃类物质占比较大。不同企业以及各企业不同工序之间特征VOCs排放浓度有较大差别,喷漆车间特征VOCs浓度要远高于烘干车间。 相似文献
208.
为识别阿什河流域地下水易污区,基于DRASTIC模型,结合研究区水文地质特点和地下水源地特质,舍弃土壤类型和水力传导系数指标,新增抽水井群影响范围评价指标,得到适用于阿什河流域的DRATIE脆弱性评价体系.借助OpenGeoSys(OGS)软件,模拟研究区抽水与不抽水时的地下水流场,圈划出抽水时流场的变化区域,划分抽水井群影响范围.运用DRATIE模型对研究区进行脆弱性评价,绘制研究区地下水脆弱性分区图,并根据用水趋势进行脆弱性情景分析.结果表明:研究区地下水脆弱性主要为较低、中、较高3个级别;河漫滩和阶地区域较易受到污染,抽水井群影响范围内脆弱性为中等,1号井群每口井抽水量不宜超过3.23×10-2 m3/s,2号井群每口井抽水量不宜超过4.00×10-2 m3/s;其余地区较不易受到污染.研究显示,应严格控制水源地抽水量,以防阿什河水体倒灌;合理分配1、2号井群抽水量,可减小水源地脆弱性范围和等级. 相似文献
209.
210.
Yanhui Zhan Jianwei Lin Yanling Qiu Naiyun Gao Zhiliang Zhu 《Frontiers of Environmental Science & Engineering in China》2011,5(1):65-75
Surfactant-modified natural zeolites (SMNZ) with different coverage types were prepared by loading hexadecyltrimethyl ammonium
bromide (HTAB) onto the surface of a natural zeolite. The adsorption behavior of humic acid (HA) on SMNZ was investigated.
Results indicate that the adsorbent SMNZ exhibited a higher affinity toward HA than the natural zeolite. HA removal efficiency
by SMNZ increased with HTAB loading. Coexisting Ca2+ in solution favored HA adsorption onto SMNZ. Adsorption capacity decreased with an increasing solution pH. For typical SMNZ
with bilayer HTAB coverage, HA adsorption process is well described by a pseudo-second-order kinetic model. The experimental
isotherm data fitted well with the Langmuir model. Calculated maximum HA adsorption capacities for SMNZ with bilayer HTAB
coverage at pH 5.5 and 7.5 were 63 and 41 mg·g−1, respectively. E2/E3 (absorbance at 250 nm to that at 365 nm) and E4/E6 (absorbance at 465 nm to that at 665 nm) ratios of
the residual HA in solution were lower than that of the original HA solution. This indicates that the HA fractions with high
polar functional groups, low molecular weight (MW), and aromaticity had a stronger tendency for adsorption onto SMNZ with
bilayer HTAB coverage. Results show that HTAB-modified natural zeolite is a promising adsorbent for removal of HA from aqueous
solution. 相似文献