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71.
微电解-Fenton联合工艺预处理煤层气井压裂废水 总被引:1,自引:0,他引:1
利用Fenton强化微电解工艺对煤层气井压裂废水展开预处理研究,以COD去除率和可生化性(B/C)为考察指标,单独工艺正交实验结果表明pH为3、反应时间为90 min、铁碳体积比为1.5∶1和pH为4、反应时间为80 min、H2O2投加量为4 mL/L分别是微电解与Fenton反应的最优条件,各可获得48.1%和44.9%的COD去除率。在最优条件下进行微电解-Fenton联合运行实验,连续61 h内COD去除率均稳定在65%以上,B/C由0.158上升到0.3以上,有利于后续生化处理的运行。 相似文献
72.
Zhou J Wang Y Yue T Li Y Wai KM Wang W 《Environmental science and pollution research international》2012,19(8):3389-3399
Introduction
During a 2009 investigation of the transport and deposition of trace elements in southern China, 37 event-based precipitation samples were collected at an observatory on Mount Heng, China (1,269?m asl).Methods
Concentrations of trace elements were analyzed using inductively coupled plasma?Cmass spectrometry and the wet deposition fluxes were established. A combination of techniques including enrichment factor analysis, principal component analysis, and back trajectory models were used to identify pollutant sources.Results
Trace element concentrations at Mount Heng were among the highest with respect to measured values reported elsewhere. All elements were of non-marine origin. The elements Pb, As, Cu, Se, and Cd were anthropogenic, while Fe, Cr, V, Ba, Mn, and Ni were of mixed crustal/anthropogenic origin. The crustal and anthropogenic contributions of trace elements were 12.8 % (0.9?~?17.4 %) and 87.2 % (82.6?~?99.1 %), with the maximum crustal fraction being 17.4 % for Fe. Coal combustion, soil and road dust, metallurgical processes, and industrial activities contributed to the element composition.Conclusions
Summit precipitation events were primarily distant in origin. Medium- to long-range transport of trace elements from the Yangtze River Delta and northern China played an important role in wet deposition at Mount Heng, while air masses from south or southeast of the station were generally low in trace element concentrations. 相似文献73.
微波诱导AC/Cu、AC/Fe催化非均相Fenton 反应催化降解垃圾渗滤液 总被引:1,自引:0,他引:1
采用活性炭载体负载Cu、Fe为催化剂,在微波诱导作用下,对垃圾渗滤液污染物进行降解。实验结果表明,活性炭负载金属前经适当浓度硝酸浸泡处理后,催化剂对COD去除率提高可超过15%,过高硝酸盐浓度对COD去除有不利影响;催化剂对COD去除率随Cu、Fe金属负载量增加呈先增加后降低的趋势,催化剂对Cu、Fe的最佳负载量分别为质量百分比2.11%和1.12%。对于AC-Cu体系,在初始pH=3,H2O2投加量为4.98×103mg/L,催化剂用量为5.0×103mg/L,420 W功率下微波辐射10 min时,垃圾渗滤液COD去除率可达到84.13%;对于AC-Fe体系,当H2O2投加量为0.33×103mg/L,催化剂AC-Fe用量为2.0×104mg/L,420 W功率下微波作用10 min时,垃圾渗滤液COD去除率为60.16%。分析2种催化剂对COD去除差异的原因,可能是催化剂AC-Cu表面单分子分布的阈值比AC-Fe高。降解液的pH值对AC-Cu体系、AC-Fe体系COD去除影响存在拐点,最高COD去除率点对应的降解液pH值为3。微波辐射功率较低时,体系COD去除率随辐射功率增加而增加;辐射功率较高时,高温下垃圾渗滤液中有机硫化物分解成小分子硫化物,对催化剂活性存在一定抑制作用。 相似文献
74.
SO2 remains a common air pollutant, almost half of the world’s population uses coal and biomass fuels for domestic energy. Limited evidence suggests that exposure to SO2 may be associated with neurotoxicity and increased risk of hospitalization and mortality of many brain disorders. However, our understanding of the mechanisms by which SO2 causes harmful insults on neurons remains elusive. To explore the molecular mechanism of SO2-induced neurotoxic effects in hippocampal neurons, we evaluated the synaptic plasticity in rat hippocampus after exposure to SO2 at various concentrations (3.5 and 7 mg m−3, 6 h d−1, for 90 d) in vivo, and in primary cultured hippocampal neurons (DIV7 and DIV14) after the treatment of SO2 derivatives in vitro. The results showed that SYP, PSD-95, NR-2B, p-ERK1/2 and p-CREB were consistently inhibited by SO2/SO2 derivatives in more mature hippocampal neurons in vivo and in vitro, while the effects were opposite in young hippocampal neurons. Our results indicated that in young neurons, SO2 exposure produced neuronal insult is similar to ischemic injury; while in more mature neurons, SO2 exposure induced synaptic dysfunctions might participate in cognitive impairment. The results implied that SO2 inhalation could cause different neuronal injury during brain development, and suggested that the molecular mechanisms might be involved in the changes of synaptic plasticity. 相似文献
75.
76.
运用HAZOP技术系统识别了聚丙烯装置存在的工艺危险和可操作性问题,提出了相关改进建议措施;并对HAZOP技术应用过程中经常遇到的典型问题,包括后果如何确定、原因能否用偏差代替、如何确定现有保护措施、如何评估风险度等,进行了探讨。 相似文献
77.
Liu Jingkuang Teng Yue Wang Dong Gong Enqin 《Environmental science and pollution research international》2020,27(30):37260-37277
Environmental Science and Pollution Research - With the acceleration of China’s urbanization process, construction activities have led to a substantial increase in construction waste.... 相似文献
78.
Heber AJ Ni JQ Lim TT Tao PC Schmidt AM Koziel JA Beasley DB Hoff SJ Nicolai RE Jacobson LD Zhang Y 《Journal of the Air & Waste Management Association (1995)》2006,56(10):1472-1483
Comprehensive field studies were initiated in 2002 to measure emissions of ammonia (NH3), hydrogen sulfide (H2S), carbon dioxide (CO2), methane (CH4), nonmethane hydrocarbons (NMHC), particulate matter <10 microm in diameter, and total suspended particulate from swine and poultry production buildings in the United States. This paper focuses on the quasicontinuous gas concentration measurement at multiple locations among paired barns in seven states. Documented principles, used in air pollution monitoring at industrial sources, were applied in developing quality assurance (QA) project plans for these studies. Air was sampled from multiple locations with each gas analyzed with one high quality commercial gas analyzer that was located in an environmentally controlled on-farm instrument shelter. A nominal 4 L/min gas sampling system was designed and constructed with Teflon wetted surfaces, bypass pumping, and sample line flow and pressure sensors. Three-way solenoids were used to automatically switch between multiple gas sampling lines with > or =10 min sampling intervals. Inside and outside gas sampling probes were between 10 and 115 m away from the analyzers. Analyzers used chemiluminescence, fluorescence, photoacoustic infrared, and photoionization detectors for NH3, H2S, CO2, CH4, and NMHC, respectively. Data were collected using personal computer-based data acquisition hardware and software. This paper discusses the methodology of gas concentration measurements and the unique challenges that livestock barns pose for achieving desired accuracy and precision, data representativeness, comparability and completeness, and instrument calibration and maintenance. 相似文献
79.
80.