Study on the denitrification performance of FexLayOz/activated coke for NH3-SCR and the effect of CO escaped from activated coke at mid-high temperature on catalytic activity

Currently, activated coke is widely used in the removal of multiple pollutants from industrial flue gas. In this paper, a series of novel Fe_xLa_yO_z/AC catalysts was prepared by the incipient wetness impregnation for NH₃-SCR denitrification reaction. The introduction of Fe-La bimetal oxides significantly improved the denitrification performance of activated coke at mid-high temperature, and 4% Fe_0.3La_0.7O_1.5/AC exhibited a superior NO_x conversion efficiency of 90.1% at 400 °C. The catalysts were further characterized by BET, SEM, XRD, Raman, EPR, XPS, FTIR, NH₃-TPD, H₂-TPR, et al., whose results showed that the perovskite-type oxide of LaFeO₃ and oxygen vacancies were produced on the catalysts’ surfaces during roasting. Fe-La doping enhanced the amount of acid sites (mainly Lewis and other stronger acid sites) and the content of multifarious oxygen species, which were beneficial for NO_x removal at mid-high temperature. Moreover, it was investigated that the effect of released CO from activated coke at mid-high temperature on the NO_x removal through the lifetime test, in which it was found that a large amount of CO produced by pyrolysis of activated coke could promote the NO_x removal, and long-term escaping of CO on the activated coke carrier did not have a significant negative impact on catalytic performance. The results of the TG-IR test showed that volatile matter is released from the activated coke while TG results showed that the weight loss rate of 4% Fe_0.3La_0.7O_1.5/AC only was 0.0015~0.007%/min at 300–400 °C. Hence, 4% Fe_0.3La_0.7O_1.5/AC had excellent thermal stability and denitrification performance to be continuously used at mid-high temperature. Finally, the mechanisms were proposed on the basis of experiments and characterization results.

     

千岛湖水源水微生物安全性评价

千岛湖作为国家战略水源地,其微生物安全直接关系到千万居民的用水安全.为了研究千岛湖湖水的生物安全性,于2018-2019年采集了金竹牌取水口不同深度的水样,并检测了水样的可生物降解溶解性有机碳(BDOC)、细菌再生长的潜力(BGP)、可培养细菌数、潜在的条件致病菌和细菌群落结构.结果显示,千岛湖水质属地表水Ⅱ～Ⅲ类水,...     

移动床生物膜反应器对垃圾渗滤液短程硝化研究

采用好氧移动床生物膜反应器（MBBR）对经过厌氧脱碳处理的垃圾渗滤液进行了深度短程硝化研究,考察了在中温（25℃）条件下DO浓度、pH值、C/N等因素对氨氮去除效果和短程硝化效果的影响.结果表明,在进水氨氮浓度为400　mg·L^-1,HRT为24 h情况下,当控制DO为2　mg·L^-1、pH值在8左右和C/N小于3时,氨氮去除率能达到70%以上,亚硝酸盐氮的积累率高达90％.间歇试验证明了该生物膜反应器中亚硝化菌的数量和活性要远高于硝化菌.该移动床生物膜工艺可以选择性固定和积累氨氧化细菌,从而实现较高的氨氮去除率和稳定的亚硝酸盐氮积累率.     

重庆市特大旱灾的自然与社会机制分析

文章针对2006年的特大旱灾探讨了2006年的特大旱灾的特征,分析了2006年特大旱灾的形成自然机制和社会机制,并提出了今后重庆市抗御旱灾的策略。认为2006年的特大旱灾是自然因素与社会因素叠加的结果,是人类社会经济系统自身易损性的体现。     

气液相组合生物法净化低浓度甲醛废气研究

对生物膜填料塔 液相生物处理的组合系统净化低浓度甲醛废气进行实验研究,结果表明,组合系统对甲醛废气的净化效果明显优于单独生物膜填料塔净化系统,甲醛净化效率提高35%以上,甲醛生化去除量增大50%以上.动力学研究结果表明,甲醛在生物膜上的生化降解反应为慢速生化反应,需要采取强化甲醛液相生化降解反应、提高反应速率的措施,来提高废气中甲醛的生物净化效果.     

烟气脱硫过程锰催化氧化亚硫酸钙的研究

利用直径280 mm、高320 mm的间歇式搅拌槽,在MnSO4加入浓度为0～0.05 mol/L的情况下,对亚硫酸钙悬浮液进行了催化氧化实验研究.实验结果表明,锰离子的加入会改变亚硫酸钙的氧化机理及氧化过程,表现为终点氧化率和氧化速率的变化.当Mn2 浓度为0.05 mol/L时,亚硫酸钙的终点氧化率比未加入Mn2 时高30%;此外,与非催化反应过程相比,Mn2 的加入能使亚硫酸钙在一个更宽的浓度范围内(0.02～0.073 mol/L)和一个更宽的时间范围内(20～100 min)均保持较高的氧化速率水平.     

风险管理标准化述评

针对近年来三个重要的风险管理国际标准化文件:Guide 73:2002,澳大利亚的风险管理标准AS/NZS 4360:2004和ISO/CD 31000,以及国际减灾理事会的白皮书,评述了国际标准化文件在风险管理过程环节的基本条款和管理框架.Guide 73指引了风险管理领域最基础的术语,对全球的风险管理制定出通用的语言.它强调对于安全领域,风险管理把焦点放在危害的预防和减轻;AS/NZS 4360明确地确定了相关风险管理的定义,解释了风险管理的程序,重点强调要控制风险产生的后果;ISO/CD 31000聚合了大约26个国家的知识和经验,关注组织建立风险管理流程和不断地进行审评的重要性;IRGC强调群体感知是风险管理的前提,只有当群体认知到可能存在风险时,才会有利于用自己的判断经验去进行风险识别、划分和评价风险,进行风险评估.最后述评了中国风险管理标准化的工作以及在国际风险管理标准化中的贡献.     

敏捷网络集成方法在区域应急预案编制中的应用

为解决区域性突发事件应急管理预案的一致性及时效性问题,提出了区域应急组织分层网络集成重构的分级动态预案编制管理方法.结合区域性生物恐怖袭击事件应急管理案例分析,试图提高应急预案编制的实际可操作性.     

煤矿危险源风险预警与控制的研究

根据现代安全管理的理论与方法,结合煤矿人-机-环境特点和不同煤矿事故的发生机理,对煤矿危险源风险预警和控制的基本理论和方法进行了探讨,提出了基于危险源的煤矿风险预警与控制的一般流程,给出煤矿危险源辨识、风险评价、监控和预警的方法,为煤矿安全管理信息系统提供理论基础。     

Spatial distribution of aerosol pollution based on MODIS data over Beijing, China

With the help of regression analysis,the relationships were detected between aerosol's contribution to apparent reflectance(ACR) derived from Moderate Resolution Imaging Spectroradiometer(MODIS)on board Terra and hourly PM_(10)mass concentration measured at 30 ground-based locations in Beijing for the August of 2003 and 2004.It was shown that there was a good correlation between the ACR and PM_(10)(linear correlation coefficient,R=0.56).On the basis of this relationship,spatial distribution and possible sources of PM_(10)derived from MODIS were analyzed and two frequently heavily-polluted regions were found,namely downtown of the city and the district near Xishan Mountain.These two regions coincidently are also urban heat island centers.The foundings of this paper will be greatly useful for environmental monitoring and urban planning for Beijing,especially for the 2008 Olympic game to be held in Beijing.