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991.
Y.F. Khalil 《Journal of Loss Prevention in the Process Industries》2013,26(1):96-103
This paper discusses the results of an experimental program carried out to determine dust cloud deflagration parameters of selected solid-state hydrogen storage materials, including complex metal hydrides (sodium alanate and lithium borohydride/magnesium hydride mixture), chemical hydrides (alane and ammonia borane) and activated carbon (Maxsorb, AX-21). The measured parameters include maximum deflagration pressure rise, maximum rate of pressure rise, minimum ignition temperature, minimum ignition energy and minimum explosible concentration. The calculated explosion indexes include volume-normalized maximum rate of pressure rise (KSt), explosion severity (ES) and ignition sensitivity (IS). The deflagration parameters of Pittsburgh seam coal dust and Lycopodium spores (reference materials) are also measured. The results show that activated carbon is the safest hydrogen storage media among the examined materials. Ammonia borane is unsafe to use because of the high explosibility of its dust. The core insights of this contribution are useful for quantifying the risks associated with use of these materials for on-board systems in light-duty fuel cell-powered vehicles and for supporting the development of hydrogen safety codes and standards. These insights are also critical for designing adequate safety features such as explosion relief venting and isolation devices and for supplementing missing data in materials safety data sheets. 相似文献
992.
Experimental and theoretical studies were conducted to investigate the pyrophoricity and water-reactivity risks associated with employing sodium alanate (NaAlH4) complex metal hydride in on-board vehicular hydrogen (H2) storage systems. The ignition and explosivity of NaAlH4 upon exposure to oxidizers in air or water were attributed to the spontaneous formation of stable hydroperoxyl intermediates on the NaAlH4 surface and/or H2 production, as well as the large driving force for NaAlH4 conversion to favorable hydroxide products predicted by atomic and thermodynamic modeling. The major products from NaAlH4 exposure to air: NaAl(OH)4, gibbsite and bayerite Al(OH)3, and Na2CO3 observed by XRD, were identified to be formed by surface-controlled reactions. The reactivity risks were significantly minimized, without compromising de-/re-hydrogenation cyclability, by compacting NaAlH4 powder into wafers to reduce the available surface area. These core findings are of significance to risk mitigation and H2 safety code and standard development for the safe use of NaAlH4 for on-board H2 storage in light-duty vehicles. 相似文献
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为更加科学有效地辨识景区道路网络中的客流关键节点,以节点脆弱性为度量指标,提出1种基于FIM模型的关键节点脆弱性评价方法。以某大型公园为例,首先通过ArcGIS软件将该公园的道路网络信息转换成可编译的文本信息,经过Java枚举可行路径,然后利用嵌入FIM算法的Lingo进行优化,得出网络节点的重要度。最后综合节点容量、流量、吸引度等信息加权得出网络节点的脆弱性。结果表明:该方法能够有效地对道路网络节点进行脆弱性度量并排序,景区可据此制定相应的客流导向方案以提高景区资源的利用率,提高游览的安全性。 相似文献
996.
Tan K Yang MX Radloff SE Hepburn HR Zhang ZY Luo LJ Li H 《Die Naturwissenschaften》2008,95(12):1165-1168
Although the structure of the dance language is very similar among species of honeybees, communication of the distance component
of the message varies both intraspecifically and interspecifically. However, it is not known whether different honeybee species
would attend interspecific waggle dances and, if so, whether they can decipher such dances. Using mixed-species colonies of
Apis cerana and Apis mellifera, we show that, despite internal differences in the structure of the waggle dances of foragers, both species attend, and act
on the information encoded in each other’s waggle dances but with limited accuracy. These observations indicate that direction
and distance communication pre-date speciation in honeybees. 相似文献
997.
Arsenic speciation for the phytoremediation by the Chinese brake fern, Pteris vittata 总被引:1,自引:0,他引:1
Arsenic (As) speciation for the phytoremediation by the Chinese brake fern was studied. In particular, the mechanism of how plants induce compounds containing thiol (SH) and proteins by As exposure in terms of the relationship between As and phosphate uptaken into plant cells was examined. Pteris vittata callus could efficiently reduce As(V) to As(III) by the rapid introduction of reductase and synthesize thiols leading to phytochelatins production. Furthermore, Pteris vittata could control phosphate concentration in the cells corresponding to the concentration of arsenite and arsenate. To our best knowledge, this is the first report to show the mechanisms of such high As tolerance of Pteris vittata using their callus in terms of in vitro approach for the analysis of As speciation and metabolism route. 相似文献
998.
Numerical study on the ozone formation inside street canyons using a
chemistry box model 总被引:1,自引:1,他引:0
Tropospheric ozone is a secondary air pollutant produced in the presence of nitrogen oxides (NO_x),volatile organic compounds (VOCs),and solar radiation.In an urban environment,ground-level vehicular exhaust is the major anthropogenic source of ozone precursors.In the cases of street canyons,pollutant dilution is weakened by the surrounding buildings that creates localized high concentration of NO_x and VOCs,and thus leads to high potential of ozone formation.By considering the major physical and chemica... 相似文献
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