全文获取类型
收费全文 | 20411篇 |
免费 | 8882篇 |
国内免费 | 19286篇 |
专业分类
安全科学 | 1781篇 |
废物处理 | 970篇 |
环保管理 | 1688篇 |
综合类 | 29453篇 |
基础理论 | 4133篇 |
环境理论 | 1篇 |
污染及防治 | 7661篇 |
评价与监测 | 1581篇 |
社会与环境 | 575篇 |
灾害及防治 | 736篇 |
出版年
2024年 | 171篇 |
2023年 | 392篇 |
2022年 | 792篇 |
2021年 | 631篇 |
2020年 | 973篇 |
2019年 | 1897篇 |
2018年 | 2095篇 |
2017年 | 2232篇 |
2016年 | 2174篇 |
2015年 | 2565篇 |
2014年 | 2967篇 |
2013年 | 3450篇 |
2012年 | 3076篇 |
2011年 | 2844篇 |
2010年 | 2448篇 |
2009年 | 2503篇 |
2008年 | 2300篇 |
2007年 | 2161篇 |
2006年 | 1796篇 |
2005年 | 1315篇 |
2004年 | 1099篇 |
2003年 | 963篇 |
2002年 | 814篇 |
2001年 | 766篇 |
2000年 | 871篇 |
1999年 | 809篇 |
1998年 | 634篇 |
1997年 | 579篇 |
1996年 | 600篇 |
1995年 | 509篇 |
1994年 | 353篇 |
1993年 | 295篇 |
1992年 | 312篇 |
1991年 | 268篇 |
1990年 | 213篇 |
1989年 | 182篇 |
1988年 | 150篇 |
1987年 | 83篇 |
1986年 | 74篇 |
1985年 | 48篇 |
1984年 | 46篇 |
1983年 | 37篇 |
1982年 | 31篇 |
1981年 | 29篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1972年 | 3篇 |
1971年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
381.
A shift in outcomes of predator-prey interactions in plankton community may occur at sublethal dissolved oxygen concentrations that commonly occur in coastal waters. Laboratory experiments were conducted to investigate how a decline in dissolved oxygen concentration alters the predation rate on fish larvae by two estuarine predators. Behavior and consumption of larval fish by moon jellyfish Aurelia aurita (103.1±12.4 mm in bell diameter) and by a juvenile piscivore, Spanish mackerel Scomberomorus niphonius (30.1±2.1 mm in standard length: SL), were observed under four oxygen concentration treatments (1, 2 and 4 mg l–1 and air-saturated: 5.8 mg l–1). Larvae of a coastal marine fish species, red sea bream Pagrus major (7.21±0.52 mm SL), were used as prey for the experiment. Bell contraction rate of the jellyfish did not vary among the oxygen concentrations tested, indicating a tolerance to low oxygen concentration. Gill ventilation rate of the Spanish mackerel increased and swimming speed decreased as the oxygen concentration decreased, indicating that oxygen concentrations 4 mg l–1 are physiologically stressful for this species. The number of larvae consumed in 15 min. by jellyfish increased whereas those consumed by Spanish mackerel decreased with the decrease in oxygen concentration. Low oxygen concentrations that are commonly observed in coastal waters of Japan during summer have the potential to increase the relative importance of jellyfish as predator of fish larvae and to change the importance of alternative trophic pathways in estuarine ecosystems.Communicated by T. Ikeda, Hakodate 相似文献
382.
The science of agroforestry has progressed significantly during the past three decades. This article describes and documents various prominent traditional agroforestry systems. In-depth research on interactive processes of some agrisilvicultural systems have been undertaken and quantified. It has been found that the presence of woody species can enhance nutrient cycling, and can improve soil productivity, soil conservation and soil biotic andfaunal activities. In simultaneous systems however, their presence can also cause competition with the associated food crops. Most agroforestry systems constitute ecologically and bio-physically sustainable land use systems. Some are highly sustainable and economically viable, in particular the highly complex and specialized types, such as the damar and rubber agroforests in Indonesia. Agroforestry systems have potential uses in stabilization of sloping lands and buffer zones around forest reserves, for recovering degraded lands, and for improving the productivity of the bush fallow system. Despite rapid progress in biophysical research, field application of the science of agroforestry is still minimal. This article examines the possibilities of exploring the multiple contributions of trees to food security, rural income generation, diversity of products and ecosystem conservation within sustainable agroforestry contexts. Research efforts in the new millennium need to focus more on practical research and also on socio-economic and policy factors that can enhance beneficial application of the science in the near future to smallholder farmers in the tropics. 相似文献
383.
依靠科学进步,促进防灾减灾 总被引:2,自引:0,他引:2
以科学技术工作为主线 ,系统地总结了陕西省减灾协会 10年来 ,从事自然灾害综合预测、防灾减灾科学研究、学术交流和科普宣传教育等方面的做法、经验和所取得的初步成效 ,以及如何建设好减灾科技社团的体会 相似文献
384.
Sequential removal of heavy metals ions and organic pollutants using an algal-bacterial consortium 总被引:1,自引:0,他引:1
The residual algal-bacterial biomass from photosynthetically supported, organic pollutant biodegradation processes, in enclosed photobioreactors, was tested for its ability to accumulate Cu(II), Ni(II), Cd(II), and Zn(II). Salicylate was chosen as a model contaminant. The algal-bacterial biomass combined the high adsorption capacity of microalgae with the low cost of the residual biomass, which makes it an attractive biosorbent for environmental applications. Cu(II) was preferentially taken-up from the medium when the metals were present both separately and in combination. There was no observed competition for adsorption sites, which suggested that Cu(II), Ni(II), Cd(II), and Zn(II) bind to different sites and that active Ni(II), Cd(II) and Zn(II) binding groups were present at very low concentrations. Therefore, special focus was given to Cu(II) biosorption. Cu(II) biosorption by the algal-bacterial biomass was characterized by an initial fast cell surface adsorption followed by a slower metabolically driven uptake. pH, Cu(II), and algal-bacterial concentration significantly affected the biosorption capacity for Cu(II). Maximum Cu(II) adsorption capacities of 8.5+/-0.4 mg g-1 were achieved at an initial Cu(II) concentration of 20 mg l-1 and at pH 5 for the tested algal-bacterial biomass. These are consistent with values reported for other microbial sorbents under similar conditions. The desorption of Cu(II) from saturated biomass was feasible by elution with a 0.0125 M HCl solution. Simultaneous Cu(II) and salicylate removal in a continuous stirred tank photobioreactor was not feasible due to the high toxicity of Cu(II) towards the microbial culture. The introduction of an adsorption column, packed with the algal-bacterial biomass, prior to the photobioreactor reduced Cu(II) concentration, thereby allowing the subsequent salicylate biodegradation in the photobioreactor. 相似文献
385.
Study on the kinetics of cerium(III) adsorption-desorption on different soils of China 总被引:1,自引:0,他引:1
The kinetics of Ce(III) adsorption-desorption on four typical soils in China has been studied by using the batch method with the radioactive nuclide 141Ce. Results indicated that Ce(III) adsorption was rapid and nearly finished in less than 0.5 min. Desorption procedure was about completed in 1-30 min in the tested soils. Ce(III) desorption equilibrium times vary with different soils. The amounts of Ce(III) desorption on different soils in the same time were different. The Elovich equation proved to be the best models for fitting the data of Ce(III) desorption reactions in fluvo-aquic soil and black soil; and the parabolic-diffusion equation was the best model in red earth and loess soil. 相似文献
386.
Analysis of chemical compositions contributable to chemical oxygen demand (COD) of oilfield produced water 总被引:1,自引:0,他引:1
This work was to give a comprehensive estimation for the chemical compositions contributable to COD of the produced water treatment system. For this purpose, the wastewater samples were collected from an onshore wastewater treatment plant. The chemical compositions of the wastewater were investigated, and the COD contributed by each component was estimated. The results showed that the COD levels of O&G and SS presented decreasing trends during the whole process and achieved total removal percentages of 95.1% and 62.3%, respectively. The final COD of organic acids and low-molecular-weight carbonyl compounds were respectively lowered to nearly 64% and 35% of their initial levels, and no regular trends were found for the COD of these chemicals during the whole treatment process. The COD of inorganic components presented minor variations at all sampling spots. The majority of COD was originated from O&G in raw wastewater. The COD contributed by O&G decreased greatly with continuous treatment and finally was lower than 17% of measured COD. At each sampling spot, the ratios of COD contributed by SS did not exceed 7.6% of measured COD. Other measured chemicals, including organic acids, carbonyl compounds, volatile phenols, reductive anions, metals and TDP were not the main sources of COD during the whole treatment process, and the ratio of COD was below 9% at each sampling spot. Most of the soluble components contributable to residual COD were still unknown after biological treatment, and the COD contributed by these components was greater than 57% of measured COD. 相似文献
387.
Influence of sediment on the fate and toxicity of a polyethoxylated tallowamine surfactant system (MON 0818) in aquatic microcosms 总被引:1,自引:0,他引:1
Wang N Besser JM Buckler DR Honegger JL Ingersoll CG Johnson BT Kurtzweil ML Macgregor J McKee MJ 《Chemosphere》2005,59(4):545-551
The fate and toxicity of a polyethoxylated tallowamine (POEA) surfactant system, MON 0818, was evaluated in water-sediment microcosms during a 4-d laboratory study. A surfactant solution of 8 mg l(-1) nominal concentration was added to each of nine 72-l aquaria with or without a 3-cm layer of one of two natural sediments (total organic carbon (TOC) 1.5% or 3.0%). Control well water was added to each of nine additional 72-l aquaria with or without sediment. Water samples were collected from the microcosms after 2, 6, 24, 48, 72, and 96 h of aging to conduct 48-h toxicity tests with Daphnia magna and to determine surfactant concentrations. Elevated mortality of D. magna (43-83%) was observed in overlying water sampled from water-only microcosms throughout the 96-h aging period, whereas elevated mortality (23-97%) was only observed in overlying water sampled from water-sediment microcosms during the first 24h of aging. Measured concentrations of MON 0818 in water-only microcosms remained relatively constant (4-6 mg l(-1)) during the 96-h period, whereas the concentrations in overlying water from microcosms containing either of the two types of sediment dissipated rapidly, with half-lives of 13 h in the 3.0% TOC sediment and 18 h in the 1.5% TOC sediment. Both toxicity and the concentration of MON 0818 in overlying water decreased more rapidly in microcosms containing sediment with the higher percent TOC and clay and with a higher microbial biomass. Mortality of D. magna was significantly correlated with surfactant concentrations in the overlying water. These results indicate that the toxicity of the POEA surfactant in water rapidly declines in the presence of sediment due to a reduction in the surfactant concentration in the overlying water above the sediment. 相似文献
388.
To understand the dechlorination ability of chlorobenzenes (CBs) and polychlorinated biphenyls (PCBs) by untamed microorganisms under anaerobic condition and to correlate gas chromatographic properties with the occurrence of reductive dechlorination, introduction of CBs and PCBs in the culture medium inoculated with microorganisms from sludge and sediment, respectively, were performed. Three kinds of culture media preparing from sludge, river water and a synthetic medium were used in the experiments. HCB was degraded to 1,3,5-trichlorobenzene (1,3,5-TCB) and 1,3-dichlorobenzene (1,3-DCB) in both sludge medium and synthetic medium with inoculated microorganisms. Three PCB congeners including 2,3,4-, 3,4,5- and 2,3,4,5-CBp (chlorinated biphenyl) were not found to be dechlorinated in the river water medium with inoculation culture but to be dechlorinated in the synthetic medium. MNDO methodology was used to compute theoretical dechlorination reaction heats and GC-ECD techniques were used to estimate chromatographic data of CB and PCB congeners. Both CB and PCB congeners showed that dechlorination by untamed microorganisms under anaerobic mixed cultures were more likely to occur when larger amounts of energy were released and greater deltaln RRT value between the parent congener and the daughter product was observed. Deltaln RRT provided a more precise information on the singularity of PCBs ortho-dechlorination in an aspect of thermodynamic favorable rule. 相似文献
389.
390.
Wang S Beasley HL Sumpter SR Kennedy IR 《Journal of environmental science and health. Part. B》2003,38(3):281-291
An enzyme-linked immunosorbent assay (ELISA) for pyrithiobac-sodium (Staple) produced by DuPont was validated in Australian soils. This pyrithiobac-sodium ELISA was shown to be highly sensitive with the limit of detection of 4-5 ppt. Soil samples were extracted either in PBS buffer by shaking or by accelerated solvent extraction (ASE). While pyrithiobac sodium can be analyzed directly by ELISA after ASE extraction with 1/10 or more dilutions, the analysis of PBS extract required filtration and dilution 1/20 or more depending on the concentration. Immunoassay results compared favorably with GC-MS results for both ASE and PBS extract of incurred residue of pyrithiobac sodium in soil samples, indicating that this ELISA can be an inexpensive and reliable alternative to conventional residue analysis methods for quantification of pyrithiobac-sodium. This validation provided the basis for applying the ELISA to a field study of pyrithiobac-sodium. 相似文献