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11.
X. Fu J. Tabata T. Takanashi S. Ohno S. Tatsuki Y. Ishikawa Y. Huang H. Honda 《Chemoecology》2004,14(3-4):175-180
Summary. The sex pheromone of Ostrinia orientalis
(Lepidoptera: Crambidae) was analyzed by gas chromatography–electroantennographic detection (GC–EAD), GC–mass spectrometry and a series of bioassays. Three EAD-active
compounds were detected in the female sex pheromone
gland extract, and identified as tetradecyl acetate (14:OAc),
(Z)-11-tetradecenyl acetate (Z11-14:OAc) and (E)-11-tetradecenyl acetate (E11-14:OAc). The titers (ratio) of 14:OAc, Z11-14:OAc and
E11-14:OAc in 3-day-old virgin
females were 0.49 ng (10), 4.86 ng (98) and 0.10 ng (2),
respectively. In a wind-tunnel bioassay, the 98:2 blend of
Z11- and E11-14:OAc, but not Z11-14:OAc alone, elicited
the same male behavioral responses as virgin females and
crude gland extracts. 14:OAc was inactive by itself, and did
not show any synergistic effect on the binary blend.
Field trapping experiments also confirmed the attractiveness
of the binary blend to O. orientalis
males. Based on
these results, we concluded that the sex pheromone of
O. orientalis
is a 98:2 mixture of Z11-14:OAc and
E11-14:OAc. This sex pheromone is very similar to that of the Z-type European corn borer,
O. nubilalis. The present
finding raises the question of whether O. orientalis
, which is indistinguishable from O. nubilalis
based on external morphology,
is a biologically distinct species independent from
O. nubilalis. 相似文献
12.
A badge-type personal sampler was developed for measuring personal exposure to nitrogen dioxide (NO2). An absorbent sheet containing triethanolamine (TEA) solution absorbed NO2 which diffused through five layers of hydrophobic fiber filter. Wind effects on absorption rate were suppressed by these filter layers. NO2 was measured by the sampler with a sensitivity of 124.8 μg h/m3 (66 ppb h) and an accuracy of within ± 20%. It could be used for measuring personal exposure to NO2 without interfering with the wearer's daily activities. Nitric oxide (NO) could be measured after a small modification to the sampler provided oxidation ability to the layers of diffusion filter. Three layers of hydrophobic fiber filter were replaced by 12 layers of glass fiber filter containing chromium trioxide solution. NO was oxidized to NO2 in the oxidation layers and absorbed by the absorbent sheet together with the coexisting NO2. Sensitivity and accuracy of the sampler for NO were nearly equal to that for NO2. 相似文献
13.
Air pollution and young children's inhalation exposure to organophosphorus pesticide in an agricultural community in Japan 总被引:1,自引:0,他引:1
Kawahara J Horikoshi R Yamaguchi T Kumagai K Yanagisawa Y 《Environment international》2005,31(8):1123-1132
Assessment of airborne organophosphorus pesticides in houses of young children (1-6 years old) and childcare facilities was conducted following pesticide applications in an agricultural community in Japan. Trichlorfon and fenitrothion, applied in two separate periods, were frequently detected from outdoor and indoor air. Dichlorvos, the primary degradation product of trichlorfon, was also detected after the application of trichlorfon. Both the outdoors and indoor concentration of applied pesticide were shown to increase with decreasing distance from the pesticide-applied farm. Indoor concentration of these pesticides significantly correlated with outdoor concentration (p=0.001 for trichlorfon and p=0.001 for fenitrothion), indicating infiltration of applied pesticide inside. Ratio of indoor to outdoor concentration (I/O ratio) of fenitrothion was higher for houses with windows open during the application than those with closed windows (median value: 0.74 vs. 0.16, p=0.003). However, a similar trend was not observed for trichlorfon as well as dichlorvos in the first period. Dichlorvos was found to have a higher I/O ratio than trichlorfon during the period, and clear correlation between indoor concentrations of dichlorvos and those of trichlorfon suggested increased decomposition of trichlorfon in the indoor environment. Daily inhalation exposure estimated by using the fixed measurement data and time-activity questionnaire ranged from 0 to 35 ng/kg/day for trichlorfon, from 0 to 26 ng/kg/day for dichlorvos, and from 0 to 44 ng/kg/day for fenitrothion. Median inhalation exposure from indoor air accounted for 74%, 86.3%, and 45% of the daily inhalation exposure, respectively. For kindergarteners or nursery school children, inhalation exposure at childcare facilities was comparable with or more than that at home, indicating that pollution level at childcare facilities had potential of high impact on children's exposure. Estimated daily inhalation exposures were inversely correlated to the proximity of their activity location to the pesticide-applied farm. 相似文献
14.
15.
Akiko Matsumoto-Oda Miya Hamai Hitosige Hayaki Kazuhiko Hosaka Kevin D. Hunt Eiiti Kasuya Kenji Kawanaka John C. Mitani Hiroyuki Takasaki Yukio Takahata 《Behavioral ecology and sociobiology》2007,61(5):661-668
Although estrous synchrony has been reported in a number of mammalian species, most often among primates, methodological and
analytical problems make it difficult to interpret these results. We developed a novel estrous synchrony index and employed
a randomization procedure to analyze long-term observations of female chimpanzee (Pan troglodytes schweinfurthii) estrous cycles at the Mahale Mountains National Park, Tanzania. Our results revealed that female chimpanzees at Mahale avoid
synchronizing their estrous periods with each other. We also found that birthrates decreased as the breeding sex ratio increased.
We suggest that estrous asynchrony decreases female–female competition for mates. Asynchrony may also reduce the potential
for male sexual coercion by nonpreferred mating partners. 相似文献
16.
DNA damage is an important step in carcinogenesis. The Ames assay is a short-term screening of carcinogens that induce DNA damage. Most carcinogens require enzymatic activation through oxidation by cytochrome P450 (CYP450) in the presence of S9 mix. A combination of iron (Fe)(III) porphyrin and an oxidant is also able to oxidize compounds as an alternative metabolic pathway to CYP450. Previously it was reported that a chemical model containing a water-soluble 5,10,15,20-tetrakis(1-methylpyridinium4-yl)porphyrinatoiron(III) chloride (4-MPy) and tert-butyl hydroperoxide (t-BuOOH) activated aromatic amines and amides. In this study, a chemical model composed of an Fe porphyrin, water-insoluble 5,10,15,20-tetrakis(pentafluorophenyl)porphyrinatoiron(III) chloride (F5P) or water-soluble 4-MPy was optimized with an oxidant – t-BuOOH, magnesium monoperoxyphthalate (MPPT), or iodosylbenzene (PhIO). Subsequently the mutagenicity of benzo[a]pyrene (B[a]P) and chrysene in Salmonella typhimurium TA strains was compared. B[a]P was activated by a combination of F5P or 4-MPy plus MPPT or PhIO in S. typhimurium TA1538. The B[a]P-induced mutagenicity with F5P plus oxidant was higher than 4-MPy plus oxidant. Mutagenicity of chrysene, a tetracyclic aromatic hydrocarbon, was not detected in the presence of F5P/PhIO in S. typhimurium TA98, but was activated in the presence of F5P/MPPT. The F5P/MPPT activated other polyaromatic hydrocarbons (PAH) in the S. typhimurium TA98 assay including dibenz[a,c]anthracene, dibenz[a,h]anthracene, 3-methylcholanthrene, and benzo[a]anthracene. The results indicated that the F5P/MPPT was the most efficient model for detecting PAH-induced mutagenicity in the Ames assay. 相似文献
17.
Yukio Noma Sayuri Yamane Akiko Kida 《Journal of Material Cycles and Waste Management》2001,3(2):126-134
Adsorbable organic halides (AOX) and AOX formation potential (AOXFP) were investigated in 46 landfill lea-chates as potentially
toxic parameters. AOX in landfill leachate was within the range <10–2200 μg Cl/l, and AOXFP was within 51–15 000 μg Cl/l.
AOX and AOXFP correlated with chemical oxygen demand (COD). AOX discharge from closed landfills was generally lower than that
from operating landfills. The molar ratio of AOXFP/total organic carbon (TOC) suggested that organic compounds in a leachate
have a double bond every 15–190 carbons under the supposition that one chlorine would add to one double bond. The five landfills
discharging high-level AOXFP (>4000 μg Cl/l) were all landfills where sludge had been dumped. The removal efficiencies of
three parameters through leachate treatment processes were as follows: polychlorinated dibenzo-dioxins/dibenzo-furans (PCDDs/DFs)
> TOC > AOX. PCDDs/DFs were substantially removed at p.p.t. levels, while AOX was hardly removed at relatively low levels.
Received: February 14, 2000 / Accepted: January 9, 2001 相似文献
18.
19.
Use of a seeder reactor to manage crystal growth in the fluidized bed reactor for phosphorus recovery. 总被引:1,自引:0,他引:1
Kazuaki Shimamura Hideyuki Ishikawa Toshihiro Tanaka Izumi Hirasawa 《Water environment research》2007,79(4):406-413
The authors have been engaged in the development of a phosphorus recovery system capable of maintaining high recovery efficiencies, with the chemical cost suppressed. This time, they conducted demonstration tests of a fluidized bed magnesium ammonium phosphate reactor provided with a seeder reactor for the supernatant from anaerobic digestion using a pilot experimental plant with a wastewater treatment capacity of 20 m3/d. For the digestion supernatant with a phosphorus concentration of approximately 300 mg/L, the treated water phosphorus concentration was 10 to 25 mg/L, and the phosphorus recovery efficiency was more than 90%. Relative to the chemical cost in the case of magnesium chloride, the chemical cost in the case of magnesium hydroxide is approximately 40%. Thus, with the new system, it was possible to reduce the running cost while maintaining high recovery efficiencies. 相似文献
20.
A collecting method to prepare a fractional determination of ambient forms of mercury in air is proposed. Particulate mercury is collected by a glass fiber filter. Sequential trap tubes consist of four long and slender quartz tubes, in which the Chromosorb W treated with HC gas for Hg(II), the Chromosorb W treated with 0.1 M NaOH for methylmercury, the silver-wire tip for metallic mercury and the gold plate tip for dimethylmercury are packed. The collection efficiency for these trap tubes was in the range of about 85 ~ 100% at the μg or ng concentration level. With this method, the air was collected by suction at the rate of 1.5 /min. for about five hours, the detection limit being 0.2 ng Hg/m3. The results indicate that the regional distribution of total mercury in air was considerably greater in the volcanic and hot spring regions. Mercury species was found to be mostly Hg(II), followed by metallic mercury, methylmercury, dimethylmercury and particulate mercury in this order. 相似文献