全文获取类型
收费全文 | 424篇 |
免费 | 16篇 |
国内免费 | 135篇 |
专业分类
安全科学 | 32篇 |
废物处理 | 24篇 |
环保管理 | 58篇 |
综合类 | 198篇 |
基础理论 | 76篇 |
污染及防治 | 136篇 |
评价与监测 | 22篇 |
社会与环境 | 13篇 |
灾害及防治 | 16篇 |
出版年
2023年 | 6篇 |
2022年 | 30篇 |
2021年 | 20篇 |
2020年 | 10篇 |
2019年 | 18篇 |
2018年 | 14篇 |
2017年 | 21篇 |
2016年 | 20篇 |
2015年 | 23篇 |
2014年 | 28篇 |
2013年 | 46篇 |
2012年 | 45篇 |
2011年 | 41篇 |
2010年 | 29篇 |
2009年 | 20篇 |
2008年 | 25篇 |
2007年 | 21篇 |
2006年 | 40篇 |
2005年 | 7篇 |
2004年 | 14篇 |
2003年 | 9篇 |
2002年 | 11篇 |
2001年 | 8篇 |
2000年 | 13篇 |
1999年 | 8篇 |
1998年 | 5篇 |
1997年 | 8篇 |
1996年 | 10篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有575条查询结果,搜索用时 15 毫秒
541.
542.
Julia Martínez-Blanco Pere Muñoz Assumpció Antón Joan Rieradevall 《Journal of Cleaner Production》2011,19(9-10):985-997
This study presents detailed and comprehensive inventories on the horticultural production of tomato using compost (CM) or mineral fertilizers (M), in both open-fields (OF) and greenhouses (GH), providing information on the environmental impacts and assessing the agronomic viability of the four cultivation options. Life cycle assessment (LCA) was used to calculate the potential environmental impacts of the tomato production cycle per ton of product. The stages in the assessment included: mineral and organic fertilizers production, fertilizers transport, cultivation stage and greenhouse stage. The data were obtained experimentally in pilot fields and in an industrial composting facility using municipal organic waste, both located in the Mediterranean area. The results indicate that replacing a fraction of the mineral fertilizers dosage with compost is a good option, as this did not alter yield or fruit size parameters. Greenhouse protection increased infrastructure materials requirements but enhanced harvest by almost 50% and reduced the water and pesticides requirement. Compost production and greenhouse stages were the most impacting stages. Without subtracting the avoided burdens by composting and not dumping organic waste, the cultivation option OF_M had the lowest and OF_CM the highest impact. When avoided burdens were taken into consideration, the environmental impacts of the four cultivation options varied, depending on the impact category, with bigger differences due to fertilization as a variable rather than the production system. 相似文献
543.
Joan Solé Albert Sans Magí Riba Gloria Rosell Esmeralda Rosa Lourdes Muñoz Maria Pilar Bosch Angel Guerrero 《Chemoecology》2008,18(2):99-108
Summary. The differing antagonist activity of (Z)-13-hexadecen-2-one (Z11 – 14 :MK, 1) and its 1,1,1-trifluoro derivative (Z11 –14 :TFMK, 2), two closely related analogues of the European corn borer pheromone Ostrinia nubilalis (Z strain), and their rationale is reported. Both chemicals exhibited some electrophysiological activity, and topical application
of 10 pg of pheromone analogue on male antennae was sufficient to induce significantly lower depolarization responses to the
pheromone versus untreated insects. In a wind tunnel, the number of European corn borer males attracted to sources containing
mixtures of 1 + pheromone in ratios ≥ 1 :1 was significantly lower than the number attracted to a source containing pheromone alone. Source
contact behaviour was dramatically impaired when the 1 + pheromone blend reached a ratio of 10 :1, in which only 2% of males displayed source contact in the presence of antagonist.
When compound 1 was present at the source, males usually flew upwind with occasional downwind reversals; when compound 2 was present at the lure, males performed wider crosswind reversals, with little progress toward the source. In the field,
traps baited with mixtures of both compounds with the pheromone in ratios of 5 :1 and 10 :1 elicited a significantly decreased
number of male catches. In esterase inhibition assays, compound 2 was a potent inhibitor (IC50 = 70 nM), whereas the non-fluorinated compound 1 was not. The different activity of both compounds is presumed to be due to different mechanisms of action; considerations
for using methyl ketone analogues as new behavioural antagonists of the pheromone are outlined. 相似文献
544.
545.
原油毒性主要源于多环芳烃(PAHs),而烷基化多环芳烃是PAHs的主要组分,氧化衍生物是PAHs降解和代谢过程所产生的重要产物。为评估比较烷基PAHs和氧化PAHs与其母体化合物对海洋生物的毒性,本研究以菲、3-甲基菲和菲醌为研究对象,对海洋经济鱼种——红鳍东方鲀(Takifugu rubripes)幼鱼进行了肝损伤评价。结果显示,线粒体、内质网是对上述3种化合物最为敏感的细胞器;3种化合物对肝损伤的表现形式不同:1.菲导致线粒体数量增加形态改变、内质网减少纹理模糊、出现脂滴、细胞空泡化、出血,2.3-甲基菲导致内质网减少、出现脂滴、细胞空泡化、出血,3.菲醌导致线粒体和内质网水肿、出现脂滴及细胞空泡化;随化合物浓度升高,肝损伤程度加重;同一浓度下,不同化合物损伤程度也有差异,总体趋势为菲醌3-甲基菲菲。上述结果表明,PAHs衍生物的毒性可能强于其母体化合物;除浓度外,化合物的结构可能对其毒性有重要影响。 相似文献
546.
Burger JR Chesh AS Muñoz P Fredes F Ebensperger LA Hayes LD 《Behavioral ecology and sociobiology》2012,66(1):57-66
Social animals are susceptible to high infection levels by contact-transmitted parasites due to increased conspecific interaction.
Exotic parasites are known to have adverse consequences on native hosts. We examined the relationship between social group
size and exotic ectoparasite loads, and adult infection levels with per capita fitness and offspring survival in the plural
breeding rodent Octodon degus in central Chile. Degus at our site were almost entirely infected by two exotic ectoparasites: the fleas Leptopsylla segnis and Xenopsylla cheopis. Neither group size nor number of females per group predicted the abundance of either exotic flea species. The per capita
number of pups (per capita fitness) that emerged from burrow systems used by known social groups was negatively correlated
with abundance of L. segnis but not X. cheopis. On adults, X. cheopis abundance was three times greater than L. segnis but was not significantly correlated with per capita fitness. In females, L. segnis abundance was negatively correlated with peak body mass during pregnancy. Adult ectoparasite load was not correlated with
offspring survival. Based on these results, we hypothesize that high infection levels of L. segnis result in decreased reproductive fitness of adult female degus but are not a cost of sociality because parasite loads are
not predicted by social group size. Further work is needed to experimentally test this hypothesis and to determine if L. segnis serves as a vector for a deleterious pathogen. Lastly, the lack of native ectoparasites may explain why a previous study
at our site determined that behavioral adaptations needed to cope with high ectoparasite burdens (e.g., grooming) are not
extensive in degus; they simply have not had the coevolutionary time needed for selection of these behaviors. 相似文献
547.
印染废水生化出水中有机污染物特性及在硫酸镁混凝过程中的去除行为 总被引:3,自引:1,他引:2
以某印染废水二级生化出水为研究对象,考察了生化出水中有机污染物中各组分含量、分子量分布特点等特性,以及各类有机物在硫酸镁混凝处理过程中的去除行为.实验结果表明,该印染废水的生化出水溶解性有机物的主要成分是疏水性物质,以溶解性有机碳(DOC)表征时占总DOC的78%,其中非酸疏水物质约占46%,而以UV254表征时约占总55%,以美国染料生产协会色度值(ADMI7.6)表征时为97%,其中以非酸疏水物质的贡献最大,达到66%,并且非酸疏水物质中不饱和双键或芳香环有机物的含量较高.生化出水中的DOC主要集中在小于1000 D的有机物上,占37%.在硫酸镁的最佳混凝条件下,可以有效地去除由大分子量的非酸疏水物质引起的色度,而对小分子量的有机物也有一定的去除效果. 相似文献
548.
山东省主要城市酸沉降现状及影响因素分析 总被引:1,自引:0,他引:1
根据山东省多年降水观测资料,分析了其17个设区城市的酸雨现状,并研究了济南市和青岛市硫的干、湿沉降及其变化规律.结果表明,近5a(1997~2001年)青岛市降水酸度位列全省17城市之首,是唯一降水pH年均值低于酸雨临界值5.60的城市;山东省主要城市的降水酸度总体上呈下降趋势.济南市和青岛市近年来硫沉降总通量基本稳定或呈下降趋势,仍达10t/(km2·a)左右;在硫沉降总通量中,硫干沉降的贡献率达80%以上,而在硫干沉降通量中,SO2干沉降的贡献率要远远高于SO42-干沉降的贡献率.通过分析酸雨前体物排放强度、土壤酸碱性以及气象条件对酸沉降的影响,揭示了山东省内主要城市酸沉降的影响因子. 相似文献
549.
Alonso-Hernández CM Cartas-Aguila H Díaz-Asencio M Muñoz-Caravaca A Martín-Pérez J Sibello-Hernández R 《Journal of environmental radioactivity》2006,88(2):199-204
Levels of 137Cs in total atmospheric deposition have been measured in the Cienfuegos region (Cuba) between 1994 and 2002. Samples were collected every three months, evaporated to dryness to obtain residual samples, and measured by gamma spectrometry. The 137Cs mean concentration in total deposition was 0.24 Bq m(-2) and data ranged between < 0.05 and 0.62 Bq m(-2). Precipitation rates and raintime have proved to be the most important factors controlling the concentration and depositional flux of 137Cs in the atmosphere over Cienfuegos, showing a high correlation coefficient (R = 0.93). 相似文献
550.
N‐acetyltransferase (NAT) activity was determined in 100 fish (Oreochromis mossambicus) livers using 2‐aminofluorene and p‐aminobenzoic acid as substrates. Overall, the liver NAT activity of the 50 females was higher than the liver NAT activity of the 50 males. The activities (mean ± SD) of NAT from kidney, blood, intestine, and liver of males was 0.42 ± 0.11, 0.12 ± 0.03, 0.12 ± 0.08, and 1.56 ± 0.54 nmol/min/mg protein for the acetylation of 2‐aminofluorene and 0.36 ± 0.09, 0.09 ± 0.01, 0.11 ± 0.04, and 0.46 ± 0.15 nmol/min/mg protein for the acetylation of p‐aminobenzoic acid. In kidney, blood, intestine, and liver from female fish, the activities obtained were 1.60 ± 0.12, 0.35 ± 0.07, 0.15 ± 0.09, and 1.89 ± 0.50 nmol/min/mg protein for 2‐aminofluorene and 0.95 ± 0.11, 0.27 ± 0.03, 0.13 ± 0.09, and 0.57 ± 0.12nmol/min/mg protein for p‐aminobenzoic acid. Kinetic constants for arylamine N‐acetyltransferase activity in kidney, blood, intestine, and liver from fish with rapid, intermediate, and slow acetylator activity were determined. Apparent K m and V max values for 2‐aminofluorene were 5.5 and 7‐fold higher for liver than for the other tissues. Apparent K m and V max values for p‐aminobenzoic acid were 3.5 and 4.7‐fold higher for liver than for the other tissues. Based on the 2‐aminofluorene NAT activity of liver, there appears to be a polymorphism in NAT activity with 16 rapid, 28 intermediate, and 56 slow acetylators among the 100 fish assayed. This is the first demonstration of acetyl CoA: arylamine N‐acetyltransferase activity in fresh water fish and could lead to the development of a fish model for monitoring the effect of pollution of water environments on native species. 相似文献