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751.
菜园土壤铜吸附--解吸特性的研究 总被引:2,自引:0,他引:2
研究了菜园土壤铜的吸附—解吸特性。结果表明 ,3种菜园土壤吸附 Cu2 的量均随平衡液中Cu2 浓度的增加而增大 ,可用 L angmuir方程和 Freundlich方程来描述。由 Langmuir方程求得的菜园土壤对 Cu2 的最大吸附量和最大缓冲容量的大小顺序为 :黄松土 >江涂土 >粉泥土 ,菜园土壤对 Cu2 的解吸量和解吸率均随其吸附量的增加而增加 ,吸附量与解吸量之间呈显著或极显著线性正相关。 相似文献
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Kerrie J. Long Sue Ellen Haupt George S. Young 《Atmospheric environment (Oxford, England : 1994)》2010,44(12):1558-1567
Source term estimation algorithms compute unknown atmospheric transport and dispersion modeling variables from concentration observations made by sensors in the field. Insufficient spatial and temporal resolution in the meteorological data as well as inherent uncertainty in the wind field data make source term estimation and the prediction of subsequent transport and dispersion extremely difficult. This work addresses the question: how many sensors are necessary in order to successfully estimate the source term and meteorological variables required for atmospheric transport and dispersion modeling?The source term estimation system presented here uses a robust optimization technique – a genetic algorithm (GA) – to find the combination of source location, source height, source strength, surface wind direction, surface wind speed, and time of release that produces a concentration field that best matches the sensor observations. The approach is validated using the Gaussian puff as the dispersion model in identical twin numerical experiments. The limits of the system are tested by incorporating additive and multiplicative noise into the synthetic data. The minimum requirements for data quantity and quality are determined by an extensive grid sensitivity analysis. Finally, a metric is developed for quantifying the minimum number of sensors necessary to accurately estimate the source term and to obtain the relevant wind information. 相似文献
753.
Linlin Wang Litao Tang Ran Wang Xiaoya Wang Jinshao Ye Yan Long 《Environmental science and pollution research international》2016,23(6):5166-5178
There is global concern about the effects of decabromodiphenyl ether (BDE209) on environmental and public health. The molecular properties, biosorption, degradation, accumulation, and cellular metabolic effects of BDE209 were investigated in this study to identify the mechanisms involved in the aerobic biodegradation of BDE209. BDE209 is initially absorbed by wall teichoic acid and N-acetylglucosamine side chains in peptidoglycan, and then, BDE209 is transported and debrominated through three pathways, giving tri-, hepta-, octa-, and nona-bromodiphenyl ethers. The C–C bond energies decrease as the number of bromine atoms on the diphenyl decreases. Polybrominated diphenyl ethers (PBDEs) inhibit protein expression or accelerate protein degradation and increase membrane permeability and the release of Cl?, Na+, NH4 +, arabinose, proteins, acetic acid, and oxalic acid. However, PBDEs increase the amounts of K+, Mg2+, PO4 3?, SO4 2?, and NO3 ? assimilated. The biosorption, degradation, accumulation, and removal efficiencies when Brevibacillus brevis (1 g L?1) was exposed to BDE209 (0.5 mg L?1) for 7 days were 7.4, 69.5, 16.3, and 94.6 %, respectively. 相似文献
754.
Long Fu Thompson Nunifu Bonnie Leung 《Journal of the Air & Waste Management Association (1995)》2014,64(10):1195-1203
A method for transforming continuous monitoring (CM) fine particulate matter (aerodynamic diameter <2.5 μm; PM2.5) data (i.e., by tapered element oscillating microbalance [TEOM]) obtained from the Canadian National Air Pollution Surveillance (NAPS) program to meet the data quality objective (DQO) of R2 > 0.8 against the co-located federal reference method (i.e., dichotomous air sampler) is described. By using a two-step linear regression to account for the effect of the ambient temperature, 16 out of the 23 examined sites met the common model adequacy threshold of R2 > 0.8. After the transformation, 20 out of the 23 examined sites met the DQO of R2 > 0.7, as recommended by the U.S. Environmental Protection Agency (EPA). A combined two-step statistical approach was also examined and revealed similar results. The methods described herein show that the CM data can be successfully transformed to meet DQOs for representative sites across Canada using year-round (both summer and winter) data.
Implications:This study provides a transformation approach to correct ambient TEOM data against the federal reference method without dividing the ambient data according to warm and cold seasons. This transformation approach will significantly improve the correlation coefficient between TEOM and dichotomous air sampler data. It is possible that TEOM data at many Canadian locations can be transformed to meet the EPA data quality objective, thus making this transformation approach useful for comparisons of ambient PM data across jurisdictions. 相似文献
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鄱阳湖生态经济区土地生态安全警情研究 总被引:5,自引:0,他引:5
土地生态安全研究是当前土地可持续利用研究的前沿课题。为了确保土地生态安全,就必须对土地生态安全系统预警进行研究。结合预警理论,从压力 状态 社会响应3方面构建了土地生态安全预警指标体系,运用物元模型对鄱阳湖生态经济区2001~ 2008年的土地生态安全的警情进行分析。结果显示:2001年鄱阳湖生态经济区土地生态安全警情为轻警状态;2002~ 2004年处于中警状态;2005~ 2006年下降为重警状态;2007~ 2008年土地生态安全警情状况有所好转,处于中警状态。通过研究表明,利用物元模型进行区域土地生态安全预警研究是可行的,具有计算简便、意义明确、评价精度高等优点,可为土地生态安全预警研究提供了另一种途径 相似文献
759.
兴凯湖是东北亚地区典型湖泊。20世纪末以来人类活动持续增强,该湖营养快速富集,水体生态状况发生转变,但其环境演化历史及营养本底等信息尚知之甚少。本研究基于对该湖多根沉积钻孔年代、元素及沉积硅藻等多指标的分析,重建了兴凯湖百余年来的环境变化历史。结果表明:兴凯湖历史上保持着良好的环境生态条件,21世纪第一个十年以前水体环境变化较小(硅藻种群弦距<0.0005),近20 a来,兴凯湖生态环境逐渐退化,硅藻从以低—中营养Aulacoseira granulata的优势组合逐渐转变为以Cyclostephanos dubius为代表的富营养组合,污染元素(Pb、Zn等)含量及沉积速率快速升高。基于种群相似性的对比发现2000 a前的硅藻种群变化较小,故采用1994—1998年的水体监测均值作为兴凯湖的营养基准,即水体总磷(TP)、总氮(TN)基准分别为35μg·L-1及970μg·L-1;结合参比元素回归分析得到的大、小兴凯湖沉积物TP基准分别为360 mg·kg-1、500 mg·kg-1,可作为该... 相似文献
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