Crosslinking and stabilization of high fractional free volume polymers for gas separation

Crosslinkable poly(4-methyl-2-pentyne) (PMP) membranes were cast from carbon tetrachloride solutions containing PMP and either 4,4′-diazidobenzophenone or 4,4′-(hexafluoroisopropylidene)diphenyl azide. The composite membranes were transparent and homogeneous and were crosslinked by UV irradiation at room temperature or thermal treatment at 180 °C. Low levels of the bis(aryl azide) (1–4.5 wt%) were effective in rendering the membranes insoluble in cyclohexane and carbon tetrachloride, both are good solvents for PMP, thus PMP can easily be converted to mechanically stable membranes with permeabilities and selectivities comparable or higher than those of the well-known poly(dimethylsiloxane) (PDMS). The permeabilities of O₂, N₂, H₂, CH₄ and CO₂ were measured. Compared to pure PMP, the crosslinked membranes containing bis(aryl azide) had lower permeabilities and higher selectivities, consistent with a reduction in free volume.     

一种二氧化碳无线监测系统的设计与实现

设计了一套由下位机检测系统和上位机监控系统组成的一体化的二氧化碳无线实时监测系统。该系统通过无线传输设备将检测的二氧化碳浓度、环境温度、环境湿度、环境风向、环境风速等信息通过 GPRS 网络传输到监控中心。详细设计了下位机检测系统的硬件电路,分析了 GPRS 无线网络的特点和原理,介绍了 TCP/IP传输协议,给出了上位机监控系统的类图。     

长期定位施肥下紫色土土壤微形态特征

通过对紫色土长期定位施肥下不同施肥处理0～20 cm耕层土壤微形态特征的研究,试图说明施肥对紫色土微形态的影响.用单偏光显微镜对不同处理的土壤微形态进行了观察与分析.结果表明:长期不施肥料的CK处理,土壤耕层结构致密,很少有孔隙发育,土壤微结构为结构较差的碎屑聚积状-沙粒聚积状;长期单施化学肥料,土壤颗粒未形成结构体,少孔隙,土壤微结构主要为斑晶胶凝状-细沙粒聚积状结构,土壤结构比CK处理优;长期施用有机肥或有机无机肥料配施的处理,土壤粗颗粒数量显著增加,结构疏松,孔隙量大,动、植物残体丰富,有铁锰结核和腐殖质的形成和微团聚体的发育,土壤微结构类型以MNPK处理最好,为胶凝紧实状-多孔状结构.有机无机肥料配施能显著改良紫色土的结构,培肥土壤,实现土壤可持续发展.     

昆仑山区构造区划初探

青藏高原虽然经过了多次考察,已经基本摸清了高原的构造格架,然而高原西北部的昆仑山—喀喇昆仑山地区的构造区划仍很不明确。经过这次考察,获得了大量新资料;新发现了库地-苏巴什为一条独立的更早阶段的重要构造界线。考察发现麻札-康西瓦-木孜塔格构造带与东面的昆仑山口-玛沁构造带相联,是真正原第四缝合带所指。由以上这两条构造带把昆仑山分成了北带、中带与南带3部分,而南带从构造发育历史看它与可可西里-巴颜喀喇区相联,不属于真正的昆仑构造区。     

潜流人工湿地污染河水处理系统中的填料堵塞问题研究

利用潜流人工湿地系统处理污染河水,水力负荷为0.15 m3/(m2·d).研究了该系统长期运行过程中的填料堵塞问题及其对污染物去除率的影响.构建了潜流人工湿地污染河水处理中试系统,在运行两年后,潜流人工湿地填料存在一定的堵塞现象,填料孔隙率最大减少了2.67%.填料孔隙堵塞现象主要发生在该中试系统的前段(沿水流方向距进水点0～5 m),其填料堵塞物质主要为无机颗粒物.植物对填料堵塞问题的改善作用并不显著.填料的部分堵塞对该中试系统中污染物的去除率有一定的影响,运行第2年氨氮的去除率略有降低,而COD的去除率有增加的趋势.     

Biological detection and analysis of mercury toxicity to alfalfa (Medicago sativa) plants

Mercury has become one of the major causes of toxic metal pollution in agricultural lands. Accumulation of mercury by plants may disrupt many cellular functions and block growth and development. To assess mercury toxicity, we performed an experiment focusing on the responses of alfalfa (Medicago sativa) to Hg(2+)-induced oxidative stress. Alfalfa plants were treated with 0-40microM HgCl(2) for 7d. The concentrations of Hg(2+) were positively correlated with the generation of O2- and H(2)O(2) in leaves. Treatment with Hg(2+) increased the activities of NADH oxidase and lipoxygenase (LOX) and damaged the biomembrane lipids. To understand biochemical responses under Hg stress, activities of several antioxidant enzymes, superoxide dismutase (SOD), peroxidase (POD), catalase (CAT), ascorbate peroxidase (APX) and glutathione reductase (GR) were assayed. Analysis of SOD activity by non-denaturing polyacrylamide gel electrophoresis revealed five isoforms in leaves, but they showed different patterns. Also, eight isoenzymes of APX and seven of POD in leaves were detected. However, only one isoform of CAT was visualized. The total activities of APX, POD and CAT were generally enhanced. We also measured several antioxidative metabolites such as ascorbate and glutathione (GSH), and found that both differentially accumulated in leaves. These results indicate that the increased levels of O2- and H(2)O(2) under Hg stress were closely linked to the improved capacity of antioxidant enzymes. The data not only provide the important information for better understanding of the toxic and tolerance mechanisms, but as well can be used as a bio-indicator for soil contamination by Hg.     

室温Fenton反应过程H2O2有效利用率的影响因素研究

Fenton反应是H2O2在Fe^2＋催化作用下产生氧自由基并氧化污染物的高效方法。但影响Fenton反应过程H2O2分解及其有效利用率的因素是很多的,其中[Fe^2＋]要求控制在3mmol／L以上。酚类体系H2O2的有效利用率不受H2O2浓度变化的影响,但受初始COD的影响,一般表现为随COD的增加,H2O2有效利用率迅速增加。当初始COD一定时,H2O2浓度在600mg／L和1800mg／L时,一元酚与二元酚体系的H2O2有效利用率均出现了两个峰值,前者的峰值分别为11．83gCOD／gH2O2和12．99gCOD／gH2O2,后者的峰值分别为9．01和11．95gCOD／gH2O2。而醇类体系H2O2的有效利用率受H2O2浓度的影响较大,但与初始COD的关系不明显。当H2O2浓度低于300mg／L时,乙醇比对照体系H2O2的分解率高1-3％,而有效利用率仅为0．6gCOD／gH2O2;随H2O2用量的继续增加,其有效利用率趋于0gCOD／gH2O2。而二元醇体系H2O2有效利用率与其浓度间呈“倒U”型规律,H2O2低于300mg／L时,其有效利用率仅为1．25gCOD／gH2O2;H2O2浓度在300mg／L～900mg／L之间时,其有效利用率可达8．96gCOD／gH2O2;其后随着H2O2的增加,有效利用率迅速下降到与乙醇体系相当。在混合体系中,醇羟基和酚羟基所占比例对H2O2有效利用率也有显著的影响,当乙醇比例小于60％时,H2O2有效利用率稳定在13．0gCOD／gH2O2;随乙醇比例的增加,其对H2O2的分解抑制效应表现出剂量依赖关系,H2O2有效利用率也逐渐下降到近于0gCOD／gH2O2,说明这部分H2O2并没有得以有效地分解用于氧化废水中的COD,这在工程实践中应引起高度的重视。     

啤酒废水治理技术进展

简述了近年来啤酒废水处理技术研究及应用现状，这些方法包括：好氧法、厌氧－好氧法、厌氧法；特别介绍了一些新工艺：ＳＢＲ，ＡＢＦ，ＥＧＳＢ，ＩＣ等；并对啤酒废水处理技术的发展前景进行了展望。     

Governmental policies drive the LUCC trajectories in the Jianghan Plain

The prosperity of farmers is closely tied to governmental policies. The Jianghan Plain is an important region for commodity grains, cotton and edible oil for China. The trajectories of land use and land cover change (LUCC) of the study area from 1995 to 2010 were studied based on the LUCC database of the Chinese Academy of Sciences. The LUCC was characterised by a continuous decrease of arable land and continuous increase of waters and construction land. The LUCC was obviously concurrent with the implementation of related national policies. The transition to construction land was ever well controlled by ‘Notice regarding the further strengthening of land management and arable land protection’ promulgated in 1997. However, it flourished again with the ‘Rise of Central China Strategy’ taking effect since 2006. The transition of construction land to others reflects an uncommon trend, which must be strengthened with the strict implementation of the overall plan, which imposes a limited acreage quota of construction land to each district. The policies were quite contradictory to the transition of waters. LUCC related to waters is most active, which was driven by both natural forces and national policies. Just after the devastating flood of 1998, the state council of China put forward the Green Policy to govern the major rivers. As to the study area, it is mainly to ‘push over dykes to let flood through and return farmland to lakes’. In 2004, the Grain Direct Subsidy Policy was implemented, which, along with the surge in the price of rice, resulted in a strengthening trend of conversion of ponds to paddy fields.     

Influences of sediment properties and macrophytes on phosphorous speciation in the intertidal marsh

Phosphorus (P) in wetlands is mainly bound to sediment in various species, which is essential to predict water column P levels. The purpose of this work is to understand the influences of sediment properties and vegetation types on P speciation. Sediments under four vegetation types in the tidal flat and offshore sandbar in Hangzhou Bay of China were collected seasonally. The rank order of P species in sediment based on concentration was exchangeable P (Exch-P)?相似文献