微电解-Fenton联合工艺预处理煤层气井压裂废水

利用Fenton强化微电解工艺对煤层气井压裂废水展开预处理研究,以COD去除率和可生化性(B/C)为考察指标,单独工艺正交实验结果表明pH为3、反应时间为90 min、铁碳体积比为1.5∶1和pH为4、反应时间为80 min、H2O2投加量为4 mL/L分别是微电解与Fenton反应的最优条件,各可获得48.1%和44.9%的COD去除率。在最优条件下进行微电解-Fenton联合运行实验,连续61 h内COD去除率均稳定在65%以上,B/C由0.158上升到0.3以上,有利于后续生化处理的运行。     

改性壳聚糖复合凹凸棒土絮凝油漆废水

将壳聚糖、阳离子淀粉和二甲基二烯丙基氯化铵(DMDAAC)进行三元接枝共聚,制备了三元接枝改性壳聚糖(CTS-DMDAAC-CS),通过红外光谱和扫描电镜对其结构进行了表征。并且将三元接枝改性壳聚糖与凹凸棒土进行优化复配,对油漆废水进行了絮凝实验,得出了当pH=12,沉降时间为20 min,复合絮凝剂投加量为0.2 g,三元接枝共聚物∶凹凸棒土=1∶10时,该复合絮凝剂对油漆去除率最佳能够达到89.3%,并且絮凝效果好,是一种新型绿色环保的有机-无机复合絮凝剂。     

林火烈度评价及其空间异质性研究进展

回顾了林火烈度评价的方法,包括单因素评价、综合评价和遥感技术的应用等;综述了林火烈度空间异质性的最新研究进展;展望了林火烈度及其空间异质性研究的未来发展趋势。     

三峡工程蓄水后荆江河段河势变化及生态护岸研究

三峡工程蓄水以来,进入长江中下游河道的水沙过程发生明显改变,从而导致中下游河道尤其是荆江河段冲刷、崩塌,局部河段河势调整较为剧烈,并导致主流顶冲部位发生变化,可能会引起新的崩岸发生。分析了荆江河段河势变化特点,列举了各种传统护岸方法,分析了传统护岸的特点和适用性,针对传统护岸工程的不足,提出生态护岸理念,在满足整体性、稳定性、适应变形等要求下,采取工程措施与植物措施共同护岸,并为河道与河岸之间水分交换提供条件,建立了水生生态系统和陆地生态系统之间的联系,实现了河流原本完整的结构和作为生态廊道的功能,进而保证整个生态系统的稳定,有利于生态环境的保护和水土保持,实现生态理念,满足生态需要,达到人与自然和谐发展。     

基于投入产出法的中国出口产品隐含碳测算

使用投入产出法,利用1999 -2008年中国海关货物出口商品分类数据,研究和测算了中国出口商品中的隐含碳.研究结果显示,中国是隐含碳的出口大国,出口贸易是中国CO2排放量逐年增长的重要原因.1999 - 2008年,我国出口产品中的隐含碳由1999年的3.8亿t上升至2008年的11.9亿t,在此期间,中国CO2年排放量的12％ -24％是因生产满足国际市场消费的产品而产生的.中国出口产品中的隐含碳主要集中在5大类行业,分别为:纺织业及服装鞋帽制造业、化学医药制造业、黑色及有色金属冶炼和压延加工业、通用及专用机械设备、电气机械及器材制造业.这5大类行业的出口产品中的隐含碳在中国出口产品的隐含碳总量中占到80％左右.中国出口产品隐含碳的主要流向是美国、欧盟和日本.在实证研究结果的基础上,本文认为国际社会应从生产者负责制和消费者负责制相结合的角度界定各国的碳排放责任和减排目标;同时建议我国应提高生产技术,降低产品的能源消耗强度,并限制能源密集型产业产品的出口.     

Removal of 2-chlorophenol from water using rice-straw derived ash

Removal of 2-chlorophenol from water using rice-straw derived ash (RSDA) was evaluated in this study to compare with commercial activated carbon. RSDA was obtained by burning rice-straw at 400 °C and 700 °C for 1 h. This ash can provide a better adsorbent for 2-chlorophenol. The adsorption capacities of RSDA at 400 °C and 700 °C are 37 and 52 mg g?1 at pH 4, respectively, and decrease to 9.0 and 40 mg g?1 at pH 10. Adsorption of either neutral or anionic 2-cholorphenol by the RSDA are shown as L-shaped nonlinear isotherms, suggesting surface adsorption rather than partitioning is occurring. At higher-burning temperatures, the surface area, porosity, point of zero charge and aromaticity of the resultant RSDA increase, but the oxygen content and surface acidity decrease. The combined effects result in a higher 2-chlorophenol adsorption of RSDA at 700 °C, which shows a slight pH effect on the adsorption of 2-chlorophenol, due to the lower content of oxygen-containing functional groups. Oxygen-containing functional groups contribute to surface acidity and H-bonding sites for adsorbed water, which compromises the interaction between 2-chlorophenol and the adsorbents. Thus, it suggests that rice-straw derived carbon (RSDC) can be used as an effective low-cost substitute material for activated carbon for removal of chlorophenols from wastewater.     

pH对生物质同步水解产酸的影响

采用香蒲枯叶作为发酵基质,考察了水生生物质在培养温度为(25.0±0.5)℃、pH为6～12下的水解产酸情况.结果表明:(1)实验末期(30 d),不同pH下香蒲枯叶中半纤维素降解率为28％～60％,比纤维素(19％～42％)和木质素(1％～46％)高.(2)在同一发酵时间内,发酵液总有机碳(TOC)、还原糖浓度总体随...     

鸭绿江口及毗邻浅海沉积物重金属的分布特征与风险评价

采用重金属的富集系数和多金属污染度分析鸭绿江口及毗邻浅海沉积物重金属的分布特征.结果表明:鸭绿江口及毗邻浅海沉积物Cu、Hg和Cd属于重要的污染因子;多金属污染度高强度分布区与高含沙量区存在对应关系,但对重金属富集影响更大的是人类活动.采用潜在生态风险指数法与生物效应阈值浓度法2种评价方法进行研究区的生态风险评价,结果...     

对氯苯酚废水的电化学降解研究

实验利用电沉积法制备的不锈钢基PbO2电极,以对氯苯酚溶液为模型废水,通过静态实验研究外加电压、电解质浓度、曝气量及初始pH值对电化学氧化降解对氯苯酚效果的影响。结果表明,实验制备的PbO2电极具有较高的电催化活性,能够有效降解对氯苯酚;较低的操作电压有助于降低处理成本;随着电解质浓度和曝气量的增加,对氯苯酚去除率均呈...     

Municipal solid waste source-separated collection in China: A comparative analysis

A pilot program focusing on municipal solid waste (MSW) source-separated collection was launched in eight major cities throughout China in 2000. Detailed investigations were carried out and a comprehensive system was constructed to evaluate the effects of the eight-year implementation in those cities. This paper provides an overview of different methods of collection, transportation, and treatment of MSW in the eight cities; as well as making a comparative analysis of MSW source-separated collection in China. Information about the quantity and composition of MSW shows that the characteristics of MSW are similar, which are low calorific value, high moisture content and high proportion of organisms. Differences which exist among the eight cities in municipal solid waste management (MSWM) are presented in this paper. Only Beijing and Shanghai demonstrated a relatively effective result in the implementation of MSW source-separated collection. While the six remaining cities result in poor performance. Considering the current status of MSWM, source-separated collection should be a key priority. Thus, a wider range of cities should participate in this program instead of merely the eight pilot cities. It is evident that an integrated MSWM system is urgently needed. Kitchen waste and recyclables are encouraged to be separated at the source. Stakeholders involved play an important role in MSWM, thus their responsibilities should be clearly identified. Improvement in legislation, coordination mechanisms and public education are problematic issues that need to be addressed.