Enhanced arsenate removal from aqueous solution by Mn-doped MgAl-layered double hydroxides

Environmental Science and Pollution Research - In this study, Mn-doped MgAl-layered double hydroxides (LDHs) were successfully synthesized for efficient removal arsenate from aqueous solution. The...     

三峡库区重庆段土壤保持服务时空分布格局研究

土壤保持是生态系统服务与功能的重要组成,在防止土壤侵蚀、减少径流泥沙与农业面源污染等方面具有至关重要的作用。以对国家生态安全具有重要作用的土壤保持生态功能区——三峡库区重庆段为研究区域,研究得到了2000~2013年时间序列区域土壤保持服务"流量"结果,结果表明:(1)三峡库区重庆段多年平均土壤保持量为604.39 t/hm~2·a,沿长江干流自西向东逐渐增强,区域差异显著;(2)三峡库区的土壤保持服务存在明显的垂直分异特征,随着高程的增加,以300 m与900 m为节点,出现递减-递增-递减的分段规律,与人类活动存在明显的相关关系;(3)增加森林覆被面积是改善区域土壤保持、减少水土流失的重要举措。同时,在三峡库区开展坡改梯工程,减少坡耕地的数量能够有效控制区域水土流失;     

Application of phosphate solubilizing bacteria in immobilization of Pb and Cd in soil

Environmental Science and Pollution Research - In the present study, heavy metal (HM)-tolerant phosphate solubilizing bacteria (PSB) were isolated and their performance during the remediation of Pb...     

湿地生态地球化学研究进展

湿地生态地球化学研究是湿地研究的核心内容之一, 是研究其物理过程、化学过程和生物过程及其相互关系以及这些过程与湿地功能的关系.回顾了近年来国内外湿地生态地球化学方面的研究成果,介绍了它的概念,并评述了湿地的生态功能、元素地球化学、生物地球化学、湿地模型和3S技术等新技术在湿地研究中的应用等方面的研究进展.提出了中国湿地生态地球化学研究的优先领域,应加强湿地基础理论研究及在湿地的演化、生态过程、界面过程、预测与评价、信息系统等方面的研究.     

UniTank工艺流程氨氮浓度的动态特征

利用基于ASM2D的数学模型对上海石洞口污水厂UniTank工艺内氨氮浓度的动态特性进行了仿真研究,发现该流程反应器氨氮浓度具有非稳态特征.反应器内氨氮浓度的变化规律与曝气时间设定及进水时间设定有关.增加曝气强度,能降低边池及中池的氨氮浓度,相应增大边池及中池的硝态氮浓度.     

废旧镍-镉电池中镍镉的回收方法

废旧镍－镉电池中镍和镉的回收主要有火法冶金和湿法冶金两种处理方法，本文对目前研究状况进行了综述。     

超细无碱玻纤复合滤料的过滤性能

袋式除尘是一种高效的除尘技术,对PM2.5具有较高的过滤效率,但是其运行阻力较大,因此,研发高效、低阻过滤材料是解决大气污染问题的关键所在。以耐高温的PPS纤维针刺布为上下层,超细无碱玻纤为中间层,经过超声波粘合或线缝合技术制备了多层复合过滤材料,研究了滤料在容尘状态下的过滤效率、过滤阻力,以及孔径变化。结果表明,该复合滤料的初始阻力低于150 Pa,容尘后对0.2~2 μm的颗粒物的过滤效率达80%以上;随着粉尘的沉积,滤料的过滤效率有了较大提高,对1 μm以上颗粒物的过滤效率可达99.99%以上,对最易透过粒径（MPPS）的过滤效率达95%以上;过滤前后,滤料的孔径分布发生了变化,过滤后滤料出现了1~5 μm的孔径分布。该复合滤料在工业高温粉尘过滤中将会有较好的应用前景。     

Properties of pyrolytic chars and activated carbons derived from pilot-scale pyrolysis of used tires

Used tires were pyrolyzed in a pilot-scale quasi-inert rotary kiln. Influences of variables, such as time, temperature, and agent flow, on the activation of obtained char were subsequently investigated in a laboratory-scale fixed bed. Mesoporous pores are found to be dominant in the pore structures of raw char. Brunauer-Emmett-Teller (BET) surfaces of activated chars increased linearly with carbon burnoff. The carbon burnoff of tire char achieved by carbon dioxide (CO2) under otherwise identical conditions was on average 75% of that achieved by steam, but their BET surfaces are almost the same. The proper activation greatly improved the aqueous adsorption of raw char, especially for small molecular adsorbates, for example, phenol from 6 to 51 mg/g. With increasing burnoff, phenol adsorption exhibited a first-stage linear increase followed by a rapid drop after 30% burnoff. Similarly, iodine adsorption first increased linearly, but it held as the burnoff exceeded 40%, which implied that the reduction of iodine adsorption due to decreasing micropores was partially made up by increasing mesopores. Both raw chars and activated chars showed appreciable adsorption capacity of methylene-blue comparable with that of commercial carbons. Thus, tire-derived activated carbons can be used as an excellent mesoporous adsorbent for larger molecular species.     

RuO2/La2O3/TiO2悬浮体系中直接耐晒黑G的光催化降解

钛酸丁酯为前驱体,采用溶胶-凝胶-浸渍法制备RuO2/La2O3/TiO2复合光催化剂,以紫外灯为光源,研究了催化剂组成、煅烧温度、溶液pH值等因素对直接耐晒黑G(DFBG)光催化降解的影响.结果表明掺杂量w(La2O3)1.39%、w(RuO2)0.12%、煅烧温度500℃(2 h)、溶液pH值7.3时,光催化活性最佳.当通气量为200 mL/min,催化剂投加量为150mg时,50 mg/L的DFBG溶液经60 min降解,其降解率近100%.DFBG的光催化降解服从Langmuir-Hinshelwood动力学模型,测得相应的动力学参数k=7.42×10-3mmol/L·min,K=19.54 L/mmol.